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Journal of Materials Chemistry A Vol - 1 Issue - 8

Journal of Materials Chemistry A Vol - 1 Issue - 7

Journal of Materials Chemistry A Vol - 1 Issue - 6

Journal of Materials Chemistry A Vol - 1 Issue - 5

Robust and efficient charge storage by uniform grafting of TEMPO radical polymer around multi-walled carbon nanotubes

Content Provider	Royal Society of Chemistry (RSC)
Author	Oyaizu, Kenichi Geckeler, Kurt E. Endo, Shogo Nishide, Hiroyuki Choi, Wonsung
Copyright Year	2013
Abstract	The radical polymer of redox-active nitroxide was first terminally modified and then grafted onto multi-walled carbon nanotubes (MWNTs) by a facile terminating reaction. The radical polymer-grafted MWNTs allowed a high dispersibility in organic solvents and fadeless redox ability of nitroxide. The TEM images revealed that the radical polymer was successfully wrapped around a MWNT with nanometre thickness showing a core–shell nanotube structure homogeneously over the whole MWNTs. The radical polymer wrapping around the MWNT exhibited quantitative and high-rate redox properties of nitroxide suitable for a cathode-active material, which was prominent when compared with a radical polymer-grafted MWNT via a “grafting from” method. These results demonstrate that nano-scale homogeneous wrapping prevented the aggregation of the radical polymer and allowed the rapid counterion accommodation leading to quantitative and rapid charge propagation.
Starting Page	2999
Ending Page	3003
Page Count	5
File Format	HTM / HTML PDF
ISSN	20507488
Volume Number	1
Issue Number	9
Journal	Journal of Materials Chemistry A
DOI	10.1039/c3ta01588b
Language	English
Publisher	Royal Society of Chemistry
Access Restriction	Open
Subject Keyword	Polymer Aminoxyl group Carbon nanotube Redox Transmission electron microscopy Nanometre Grafting Counterion
Content Type	Text
Resource Type	Article
Subject	Chemistry Renewable Energy, Sustainability and the Environment Materials Science

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