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Cobalt-zinc oxide absorbents for low temperature gas desulfurisation

Content Provider	Royal Society of Chemistry (RSC)
Author	Baird, Thomas Campbell, Kenneth C. Holliman, Peter J. Morris, Michael Hoyle, Robert W. Stirling, Diane Huxam, Max Williams, B. Peter
Copyright Year	1999
Abstract	The hydrogen sulfide absorption capacity of a series of cobalt-zinc oxides with nominal Co/Zn atomic ratios of 0/100, 10/90, 20/80, 30/70, 40/60, 50/50, 70/30, 90/10 and 100/0 was determined using a continuous flow absorption apparatus. The reaction of the mixed oxides with H 2 S amounted to ca. 3 monolayers, and is therefore largely confined to the surface of the oxides. The sulfur uptake was found to be proportional to the surface area of the oxides with a Co/Zn ratio ≤40/60, indicating that lattice diffusion played a major role in the rate determining step, and that the main function of the cobalt was to increase the surface area. At high cobalt concentrations, the sulfur uptake increased more than proportionately with surface area and the reaction was virtually stoichiometric for the oxide with a Co/Zn ratio of 100/0. This was associated with a change in the oxide structure from a bulk biphasic ZnO and Co 3 O 4 absorbent with a ZnCo 2 O 4 surface spinel at Co/Zn ratios ≤30 to a monophasic zincian or pure Co 3 O 4 structure at higher cobalt loadings. Analysis of the sulfided mixed oxides showed that microcrystalline membraneous sheets containing cobalt, zinc and sulfur developed on sulfiding. XPS studies of the sulfided oxides indicated that H 2 S reduced the surface spinel found at Co/Zn ratios ≤30/70 and the zincian/pure Co 3 O 4 found at higher cobalt concentrations to CoO and ZnO prior to the formation of their sulfides. The results are interpreted in terms of a surface reconstruction occurring during sulfiding.
Starting Page	599
Ending Page	605
Page Count	7
File Format	PDF
ISSN	09599428
Volume Number	9
Issue Number	2
Journal	Journal of Materials Chemistry
DOI	10.1039/a806909c
Language	English
Publisher	Royal Society of Chemistry
Access Restriction	Open
Subject Keyword	Hydrogen sulfide Sulfur Crystal structure Diffusion Cobalt Stoichiometry Spinel Zinc
Content Type	Text
Resource Type	Article
Subject	Chemistry Materials Chemistry

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