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Intercalation of n-alkylamines into misfit layer sulfides

Content Provider	Royal Society of Chemistry (RSC)
Author	Sánchez, Luis Lavela, Pedro Morales, JuliáN Hernán, Lourdes Tirado, José L.
Copyright Year	1996
Abstract	Novel intercalation complexes of (PbS)1.18( TiS2)2 and (PbS)1.14(TaS2)2 two representative compounds of misfit layer sulfides, have been prepared by direct reaction with n-alkylamines (CnH2n+ 1 NH2)(n= 1–9). From the observed amine stoichiometry and lattice expansions, the most likely configuration for the intercalated amine molecules is one in which the latter are located at the van der Waals gap between two adjacent TS2 slabs as a monolayer with the alkyl chain oriented parallel to the layers. Thermal deintercalation of the new phases occurred at temperatures below 250 °C and in the case of Ti intercalates, H2S was released simultaneously with the amine deintercalation process. The intercalation process was confirmed to be reversible. Thus, the product obtained from the thermal treatment recovered the main features of the original host structure and, when mixed with the amine, yielded an intercalate of similar structural characteristics to those found using the original sulfide.
Starting Page	861
Ending Page	866
Page Count	6
File Format	PDF
ISSN	09599428
Volume Number	6
Issue Number	5
Journal	Journal of Materials Chemistry
DOI	10.1039/JM9960600861
Language	English
Publisher	Royal Society of Chemistry
Access Restriction	Open
Subject Keyword	Stoichiometry Crystal structure Van der Waals force Intercalation (chemistry) Hydrogen sulfide Sulfide
Content Type	Text
Resource Type	Article
Subject	Chemistry Materials Chemistry

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