NDLI: Carbamide promoted polyol synthesis and transmittance properties of silver nanocubes

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Two-dimensional layered nanomaterials for gas-sensing applications

Intercalation in two-dimensional transition metal chalcogenides

A new sodium storage mechanism of TiO₂ for sodium ion batteries

Coupling of terminal iridium nitrido complexes

Alkoxide-intercalated NiFe-layered double hydroxides magnetic nanosheets as efficient water oxidation electrocatalysts

Cu₂O clusters grown on TiO₂ nanoplates as efficient photocatalysts for hydrogen generation

A comparison of two classic Pb²⁺-dependent RNA-cleaving DNAzymes

Sustainable development of a surface-functionalized mesoporous aluminosilicate with ultra-high ion exchange efficiency

Glutathione modified carbon-dots: from aggregation-induced emission enhancement properties to a “turn-on” sensing of temperature/Fe³⁺ ions in cells

Thioether-terminated nickel(ii) coordination clusters with {Ni₆} horseshoe- and {Ni₈} rollercoaster-shaped cores

MoS₂ with an intercalation reaction as a long-life anode material for lithium ion batteries

Dioxygen binding at a four-coordinate cobaltous porphyrin site in a metal–organic framework: structural, EPR, and O₂ adsorption analysis

A new methylviologen-templated zinc gallophosphate zeolite with photo-/thermochromism, fluorescent and photoelectric properties

Carbamide promoted polyol synthesis and transmittance properties of silver nanocubes

Correction: Alkoxide-intercalated NiFe-layered double hydroxides magnetic nanosheets as efficient water oxidation electrocatalysts

Correction: A new methylviologen-templated zinc gallophosphate zeolite with photo-/thermochromism, fluorescent and photoelectric properties

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Inorganic Chemistry Frontiers Vol - 3 Issue - 3

Inorganic Chemistry Frontiers Vol - 3 Issue - 2

Inorganic Chemistry Frontiers Vol -2

Inorganic Chemistry Frontiers Vol -1

Carbamide promoted polyol synthesis and transmittance properties of silver nanocubes

Content Provider	Royal Society of Chemistry (RSC)
Author	Zhang, Jing Wiley, Benjamin J. Zhang, Xiaohui Hu, Changwen Wang, Qiang Li, Chunhong Wang, Jigang Guo, Ming
Copyright Year	2016
Abstract	In this work, silver (Ag) nanocubes with different sizes were rapidly synthesized with a modified HCl-based polyol approach by employing carbamide (CO(NH2)2) as the additive or promoter, which could shorten the reaction time from about 25 h to less than 4 h and the method could be confirmed as facile and robust. In the reaction system, the NH3 molecules play the role of aggregating Ag+ and [Ag(NH3)2]+ could gradually release Ag+, which in turn results in formation of a more homogeneous product in a short time (50 min–4 h). Some factors affecting the synthesis including the concentration, reaction time and agitator speed have also been investigated, which could be adjusted to control the size, morphology, purity and uniformity of the Ag nanocubes. A mechanism for the rapid synthesis of the Ag nanocubes was proposed. To overcome the lower repeatability of reported methods, we have supplied a robust method to synthesize Ag nanocubes and this procedure may provide a useful guide for the future synthesis of Ag or other metal nanoparticles. The transmittance properties of the different Ag nanocubes have also been detected, which demonstrated that the transmittance of the Au film coupled with the Ag nanocubes is very sensitive to not only the size of the Ag nanocubes but also the thickness of the polyelectrolyte molecular spacer layers.
Starting Page	547
Ending Page	555
Page Count	9
File Format	HTM / HTML PDF
ISSN	20521553
Volume Number	3
Issue Number	4
Journal	Inorganic Chemistry Frontiers
DOI	10.1039/c5qi00256g
Language	English
Publisher	Royal Society of Chemistry
Access Restriction	Open
Subject Keyword	Polyol Urea Ammonia Short Time Polyelectrolyte Molecular spacer
Content Type	Text
Resource Type	Article
Subject	Inorganic Chemistry

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Effect of light at different wavelengths on polyol synthesis of silver nanocubes.

Synthesis of Ag Nanocubes 18–32 nm in Edge Length: The Effects of Polyol on Reduction Kinetics, Size Control, and Reproducibility

Study of polyol synthesis reaction parameters controlling high yield of silver nanocubes

Urea synthesis from ammonia in periportal and pericentral regions of the liver lobule. Effect of oxygen

Synthesis and Crystal Structures of Two Metal Urea Nitrates

Polyelectrolyte mediated scalable synthesis of highly stable silver nanocubes in less than a minute using microwave irradiation.

Formation and Growth of Silver Nanocubes upon Nanosecond Pulsed Laser Irradiation: Effects of Laser Intensity and Irradiation Time

Microwave-Promoted and Lewis Acid Catalysed Synthesis of 2,4,6-Triarylpyridines Using Urea as Benign Source of Ammonia

Gamma Radiation Synthesis and Characterization of Starch Based Polyelectrolyte Hydrogels Loaded Silver Nanoparticles

Carbamide promoted polyol synthesis and transmittance properties of silver nanocubes

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Carbamide promoted polyol synthesis and transmittance properties of silver nanocubes