NDLI: Thioether-terminated nickel(ii) coordination clusters with {Ni<sub>6</sub>} horseshoe- and {Ni<sub>8</sub>} rollercoaster-shaped cores

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Contents list

Two-dimensional layered nanomaterials for gas-sensing applications

Intercalation in two-dimensional transition metal chalcogenides

A new sodium storage mechanism of TiO₂ for sodium ion batteries

Coupling of terminal iridium nitrido complexes

Alkoxide-intercalated NiFe-layered double hydroxides magnetic nanosheets as efficient water oxidation electrocatalysts

Cu₂O clusters grown on TiO₂ nanoplates as efficient photocatalysts for hydrogen generation

A comparison of two classic Pb²⁺-dependent RNA-cleaving DNAzymes

Sustainable development of a surface-functionalized mesoporous aluminosilicate with ultra-high ion exchange efficiency

Glutathione modified carbon-dots: from aggregation-induced emission enhancement properties to a “turn-on” sensing of temperature/Fe³⁺ ions in cells

Thioether-terminated nickel(ii) coordination clusters with {Ni₆} horseshoe- and {Ni₈} rollercoaster-shaped cores

MoS₂ with an intercalation reaction as a long-life anode material for lithium ion batteries

Dioxygen binding at a four-coordinate cobaltous porphyrin site in a metal–organic framework: structural, EPR, and O₂ adsorption analysis

A new methylviologen-templated zinc gallophosphate zeolite with photo-/thermochromism, fluorescent and photoelectric properties

Carbamide promoted polyol synthesis and transmittance properties of silver nanocubes

Correction: Alkoxide-intercalated NiFe-layered double hydroxides magnetic nanosheets as efficient water oxidation electrocatalysts

Correction: A new methylviologen-templated zinc gallophosphate zeolite with photo-/thermochromism, fluorescent and photoelectric properties

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Inorganic Chemistry Frontiers Vol - 3 Issue - 3

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Inorganic Chemistry Frontiers Vol -2

Inorganic Chemistry Frontiers Vol -1

Thioether-terminated nickel(ii) coordination clusters with {Ni₆} horseshoe- and {Ni₈} rollercoaster-shaped cores

Content Provider	Royal Society of Chemistry (RSC)
Author	Leusen, Jan Schmitz, Sebastian Kögerler, Paul Ellern, Arkady Monakhov, Kirill Yu.
Copyright Year	2016
Abstract	We report two polynuclear nickel(II) compounds whose supramolecular structures are controlled by small inorganic templating anions and π-conjugated Schiff-base ligands (L·SMe3− and HL·SMe2−) with peripheral, structurally exposed methylthioether groups. The central component of the compound [Ni6(L·SMe)3(CO3)(MeOH)6(THF)2]Cl·2MeOH (1, monoclinic space group P2/c) displays a horseshoe-shaped {Ni6} core templated by μ6-CO32− moiety due to the fixation of atmospheric carbon dioxide. According to thermogravimetric analysis, compound 1 retains the structural integrity of its carbonate-bonded metal core [Ni6(L·SMe)3(CO3)]+ up to ca. 390 °C. In the crystal lattice, compound 1 features an one-dimensional hydrogen-bonded chain structure [{CO3 ⊂ Ni6}⋯Cl⋯{CO3 ⊂ Ni6}]∞. The structure of the compound [Ni8(HL·SMe)2(L·SMe)2(OH)4(MeCN)4(H2O)4](NO3)2·11MeCN·2PhCN (2, triclinic space group P) consists of a dicationic crown-like {Ni8} metallamacrocycle hosting two NO3− anions in the upper and lower cavities. The {Ni6} complex is characterised by antiferromagnetic exchange interactions, whereas {Ni8} reveals predominantly ferromagnetic exchange coupling between the spin-1 Ni(II) centres. The presence of terminal thioether anchoring groups at the periphery of complex 1, coupled with high thermal stability and solubility in several common organic solvents, renders this compound an interesting candidate for molecular surface-deposition from solution using electrospray ionisation mass spectrometry approach and, possibly, for supported-transition metal complex heterogeneous catalysis.
Starting Page	523
Ending Page	531
Page Count	9
File Format	HTM / HTML PDF
ISSN	20521553
Volume Number	3
Issue Number	4
Journal	Inorganic Chemistry Frontiers
DOI	10.1039/c5qi00278h
Language	English
Publisher	Royal Society of Chemistry
Access Restriction	Subscribed
Subject Keyword	Nickel Monoclinic crystal system Space group Carbon dioxide Thermogravimetric analysis Crystal structure Water of crystallization Triclinic crystal system Antiferromagnetism Ferromagnetism Thioether Electrospray ionization Mass spectrometry Heterogeneous catalysis
Content Type	Text
Resource Type	Article
Subject	Inorganic Chemistry

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