NDLI: Aluminium triisopropoxide: An inexpensive and easy-to-handle catalyst of the copolymerisation of cyclohexene oxide with CO<sub>2</sub>

Please wait, while we are loading the content...

Diversity in electrochemical oxidation of dihydroxybenzoic acids in the presence of acetylacetone. A green method for synthesis of new benzofuran derivatives

Selection process of new solvents in temperature-dependent multi-component solvent systems and its application in isomerising hydroformylation

Poly(ethyleneglycol)(PEG): a versatile reaction medium in gaining access to 4′-(pyridyl)-terpyridines

A novel room temperature ionic liquid sol–gel matrix for amperometric biosensor application

Aluminium triisopropoxide: An inexpensive and easy-to-handle catalyst of the copolymerisation of cyclohexene oxide with CO₂

Metal-coated nanoscale TiO₂ catalysts for enhanced CO₂ photoreduction

Stability and activity of immobilised penicillin G amidase in ionic liquids at controlled a_w

ZrOCl₂·8H₂O catalysts for the esterification of long chain aliphatic carboxylic acids and alcohols. The enhancement of catalytic performance by supporting on ordered mesoporous silica

A solvent-free synthesis of α,α′-bis(substituted benzylidene) cycloalkanones catalyzed by lanthanide amides [(Me₃Si)₂N]₃Ln(µ-Cl)Li(THF)₃ under microwave irradiation

Back cover

Green Chemistry Vol - 7 Issue - 8

Green Chemistry Vol - 7 Issue - 7

Green Chemistry Vol - 7 Issue - 6

Green Chemistry Vol - 7 Issue - 5

Green Chemistry Vol - 7 Issue - 4

Green Chemistry Vol - 7 Issue - 3

Green Chemistry Vol - 7 Issue - 2

Green Chemistry Vol -6

Green Chemistry Vol -5

Green Chemistry Vol -4

Green Chemistry Vol -3

Green Chemistry Vol -2

Aluminium triisopropoxide: An inexpensive and easy-to-handle catalyst of the copolymerisation of cyclohexene oxide with CO₂

Content Provider	Royal Society of Chemistry (RSC)
Author	Janssen, Annette Sypien, Jakub Dinjus, Eckhard Zevaco, Thomas A.
Copyright Year	2005
Abstract	Aluminium triisopropoxide, a versatile and cheap oligomeric Lewis acid catalyst, easily reacts with carbon dioxide to build complex oligomeric aluminium alkoxo-alkylcarbonato compounds. A first series of experiments with cyclohexene oxide and CO2 showed that the catalyst is highly active in the copolymerisation with carbon dioxide and that a satisfactory carbon dioxide insertion takes place when the reaction is run at temperatures between 50 and 80 °C and pressures around 100 bar CO2. High yields of polyether-carbonates can be obtained (up to 1000 g of copolymer per g aluminium) with molecular weight up to 11 000 g mol−1 and a better selectivity of the CO2-insertion than other aluminium trialkoxides (carbonate to ether linkages ratio: 1 to 3). On the basis of 27Al-NMR spectra it can be seen that the high reactivity of the catalyst is due to a rearrangement of the stable tetrameric aluminium isopropoxide in a more reactive oligomer and, most likely, during the copolymerisation, to a further fragmentation into reactive monomeric species.
Starting Page	659
Ending Page	666
Page Count	8
File Format	HTM / HTML PDF
ISSN	14639262
Volume Number	7
Issue Number	9
Journal	Green Chemistry
DOI	10.1039/b504798f
Language	English
Publisher	Royal Society of Chemistry
Access Restriction	Subscribed
Subject Keyword	Lewis Carboxylic acid Carbon dioxide Aluminium Cyclohexene oxide Copolymer Ether Aluminium isopropoxide Oligomer
Content Type	Text
Resource Type	Article
Subject	Environmental Chemistry Pollution

Sl.	Authority	Responsibilities	Communication Details
1	Ministry of Education (GoI), Department of Higher Education	Sanctioning Authority	https://www.education.gov.in/ict-initiatives
2	Indian Institute of Technology Kharagpur	Host Institute of the Project: The host institute of the project is responsible for providing infrastructure support and hosting the project	https://www.iitkgp.ac.in
3	National Digital Library of India Office, Indian Institute of Technology Kharagpur	The administrative and infrastructural headquarters of the project	Dr. B. Sutradhar bsutra@ndl.gov.in
4	Project PI / Joint PI	Principal Investigator and Joint Principal Investigators of the project	Dr. B. Sutradhar bsutra@ndl.gov.in Prof. Saswat Chakrabarti will be added soon
5	Website/Portal (Helpdesk)	Queries regarding NDLI and its services	support@ndl.gov.in
6	Contents and Copyright Issues	Queries related to content curation and copyright issues	content@ndl.gov.in
7	National Digital Library of India Club (NDLI Club)	Queries related to NDLI Club formation, support, user awareness program, seminar/symposium, collaboration, social media, promotion, and outreach	clubsupport@ndl.gov.in
8	Digital Preservation Centre (DPC)	Assistance with digitizing and archiving copyright-free printed books	dpc@ndl.gov.in
9	IDR Setup or Support	Queries related to establishment and support of Institutional Digital Repository (IDR) and IDR workshops	idr@ndl.gov.in

Anion effect controlling the selectivity in the zinc-catalysed copolymerisation of CO2 and cyclohexene oxide

Differences in Reactivity of Epoxides in the Copolymerisation with Carbon Dioxide by Zinc-Based Catalysts: Propylene Oxide versus Cyclohexene Oxide

Effect of modifiers on the activity of a Cr₂O₃/Al₂O₃ catalyst in the dehydrogenation of ethylbenzene with CO₂

A Rational Investigation of the Lewis Acid-Promoted Coupling of Carbon Dioxide with Cyclohexene Oxide: Towards CO2-Sourced Polycyclohexene Carbonate under Solvent- and Cocatalyst-Free Conditions

Polypyrrole Nanofibers Supported Cr(III)(salen)Cl Catalyst: A Novel Polymer Supported Catalyst for Alternating Copolymerization of Cyclohexene Oxide with Carbon dioxide

Continuous esterification or dehydration in supercritical carbon dioxide

Solid acid catalyzed biodiesel production by simultaneous esterification and transesterification

A Lewis acid β-diiminato-zinc-complex as all-rounder for co- and terpolymerisation of various epoxides with carbon dioxide

Polymerization of cyclohexene oxide using yttrium isopropoxide and a bimetallic yttrium-aluminium isopropoxide as initiators

Aluminium triisopropoxide: An inexpensive and easy-to-handle catalyst of the copolymerisation of cyclohexene oxide with CO₂

Similar Documents

Anion effect controlling the selectivity in the zinc-catalysed copolymerisation of CO2 and cyclohexene oxide

Differences in Reactivity of Epoxides in the Copolymerisation with Carbon Dioxide by Zinc-Based Catalysts: Propylene Oxide versus Cyclohexene Oxide

Effect of modifiers on the activity of a Cr2O3/Al2O3 catalyst in the dehydrogenation of ethylbenzene with CO2

A Rational Investigation of the Lewis Acid-Promoted Coupling of Carbon Dioxide with Cyclohexene Oxide: Towards CO2-Sourced Polycyclohexene Carbonate under Solvent- and Cocatalyst-Free Conditions

Polypyrrole Nanofibers Supported Cr(III)(salen)Cl Catalyst: A Novel Polymer Supported Catalyst for Alternating Copolymerization of Cyclohexene Oxide with Carbon dioxide

Continuous esterification or dehydration in supercritical carbon dioxide

Solid acid catalyzed biodiesel production by simultaneous esterification and transesterification

A Lewis acid β-diiminato-zinc-complex as all-rounder for co- and terpolymerisation of various epoxides with carbon dioxide

Polymerization of cyclohexene oxide using yttrium isopropoxide and a bimetallic yttrium-aluminium isopropoxide as initiators

Aluminium triisopropoxide: An inexpensive and easy-to-handle catalyst of the copolymerisation of cyclohexene oxide with CO2

Effect of modifiers on the activity of a Cr₂O₃/Al₂O₃ catalyst in the dehydrogenation of ethylbenzene with CO₂

Aluminium triisopropoxide: An inexpensive and easy-to-handle catalyst of the copolymerisation of cyclohexene oxide with CO₂