NDLI: UV-curable semi-interpenetrating polymer network-integrated, highly bendable plastic crystal composite electrolytes for shape-conformable all-solid-state lithium ion batteries

Please wait, while we are loading the content...

One-pot catalytic hydrocracking of raw woody biomass into chemicals over supported carbide catalysts: simultaneous conversion of cellulose, hemicellulose and lignin

The electrocapacitive properties of graphene oxide reduced by urea

Photocatalytic oxidation of thiophene on BiVO₄ with dual co-catalysts Pt and RuO₂ under visible light irradiation using molecular oxygen as oxidant

Replacing fossil based PET with biobased PEF; process analysis, energy and GHG balance

Energy and environmental nanotechnology in conductive paper and textiles

Polymer fuel cells based on polybenzimidazole/H₃PO₄

Impact of a possible future global hydrogen economy on Arctic stratospheric ozone loss

Graphene oxide derived carbons (GODCs): synthesis and gas adsorption properties

Enhanced photovoltaic performance with co-sensitization of porphyrin and an organic dye in dye-sensitized solar cells

CO₂ capture and conversion using Mg-MOF-74 prepared by a sonochemical method

Effect of pore size and its dispersity on the energy storage in nanoporous supercapacitors

Formate oxidation viaβ-deprotonation in [Ni(P^R₂N^R′₂)₂(CH₃CN)]²⁺ complexes

UV-curable semi-interpenetrating polymer network-integrated, highly bendable plastic crystal composite electrolytes for shape-conformable all-solid-state lithium ion batteries

Highly durable SiOC composite anode prepared by electrodeposition for lithium secondary batteries

Optimization of photoelectrochemical water splitting performance on hierarchical TiO₂ nanotube arrays

How should you measure your excitonic solar cells?

Investigation of the degradation mechanisms of a variety of organic photovoltaic devices by combination of imaging techniques—the ISOS-3 inter-laboratory collaboration

Photogalvanic cells based on lyotropic nanosystems: towards the use of liquid nanotechnology for personalised energy sources

Dynamics of photogenerated charges in the phosphate modified TiO₂ and the enhanced activity for photoelectrochemical water splitting

Seed-assisted synthesis of highly ordered TiO₂@α-Fe₂O₃ core/shell arrays on carbon textiles for lithium-ion battery applications

Back cover

Energy & Environmental Science Vol - 5 Issue - 3

Energy & Environmental Science Vol - 5 Issue - 2

Energy & Environmental Science Vol -4

Energy & Environmental Science Vol -3

Energy & Environmental Science Vol -2

Energy & Environmental Science Vol -1

UV-curable semi-interpenetrating polymer network-integrated, highly bendable plastic crystal composite electrolytes for shape-conformable all-solid-state lithium ion batteries

Content Provider	Royal Society of Chemistry (RSC)
Author	Ha, Hyo-Jeong Kil, Eun-Hye Kim, Je Young Kwon, Yo Han Lee, Sang-Young Lee, Chang Kee
Copyright Year	2012
Abstract	A facile approach to fabricate a highly bendable plastic crystal composite electrolyte (PCCE) for use in shape conformable all-solid-state lithium-ion batteries is demonstrated. This strategy is based on integration of a semi-interpenetrating polymer network (semi-IPN) matrix with a plastic crystal electrolyte (PCE, 1 M lithium bis-trifluoromethanesulfonimide in succinonitrile). In comparison to conventional carbonate-based electrolytes, salient benefits of the PCE are the thermal stability and nonflammability, which show promising potential as a safer electrolyte. The semi-IPN matrix in the PCCE is composed of a UV (ultraviolet)-crosslinked ethoxylated trimethylolpropane triacrylate polymer network and polyvinylidene fluoride-co-hexafluoropropylene (as a linear polymer). Solid electrolyte properties of the PCCE are investigated in terms of plastic crystal behavior, mechanical bendability, and ionic transport. Owing to the presence of the anomalous semi-IPN matrix, the PCCE exhibits unprecedented improvement in bendability, along with affording high ionic conductivity. Based on this understanding of the PCCE characteristics, feasibility of applying the PCCE to solid electrolytes for lithium-ion batteries is explored. The facile ionic transport of the PCCE, in conjunction with suppressed growth of cell impedance during cycling, plays a crucial role in providing excellence in cell performance. These advantageous features of the PCCE are further discussed with an in-depth consideration of the semi-IPN matrix architecture and its specific interaction with the PCE.
Starting Page	6491
Ending Page	6499
Page Count	9
File Format	HTM / HTML PDF
ISSN	17545692
Volume Number	5
Issue Number	4
Journal	Energy & Environmental Science
DOI	10.1039/c2ee03025j
Language	English
Publisher	Royal Society of Chemistry
Access Restriction	Open
Subject Keyword	PCE PCCE Plastic crystal Electrolyte Lithium-ion battery Polymer Composite material Lithium Succinonitrile Ultraviolet Trimethylolpropane Electrical impedance
Content Type	Text
Resource Type	Article
Subject	Environmental Chemistry Pollution Renewable Energy, Sustainability and the Environment Nuclear Energy and Engineering

Sl.	Authority	Responsibilities	Communication Details
1	Ministry of Education (GoI), Department of Higher Education	Sanctioning Authority	https://www.education.gov.in/ict-initiatives
2	Indian Institute of Technology Kharagpur	Host Institute of the Project: The host institute of the project is responsible for providing infrastructure support and hosting the project	https://www.iitkgp.ac.in
3	National Digital Library of India Office, Indian Institute of Technology Kharagpur	The administrative and infrastructural headquarters of the project	Dr. B. Sutradhar bsutra@ndl.gov.in
4	Project PI / Joint PI	Principal Investigator and Joint Principal Investigators of the project	Dr. B. Sutradhar bsutra@ndl.gov.in Prof. Saswat Chakrabarti will be added soon
5	Website/Portal (Helpdesk)	Queries regarding NDLI and its services	support@ndl.gov.in
6	Contents and Copyright Issues	Queries related to content curation and copyright issues	content@ndl.gov.in
7	National Digital Library of India Club (NDLI Club)	Queries related to NDLI Club formation, support, user awareness program, seminar/symposium, collaboration, social media, promotion, and outreach	clubsupport@ndl.gov.in
8	Digital Preservation Centre (DPC)	Assistance with digitizing and archiving copyright-free printed books	dpc@ndl.gov.in
9	IDR Setup or Support	Queries related to establishment and support of Institutional Digital Repository (IDR) and IDR workshops	idr@ndl.gov.in

Infiltrated and Isostatic Laminated NCM and LTO Electrodes with Plastic Crystal Electrolyte Based on Succinonitrile for Lithium-Ion Solid State Batteries

Composite Electrolyte & Electrode Membranes for Electrochemical Energy Storage & Conversion Devices

Highly porous CMC-Li aerogel frameworks supported polymer solid electrolytes for lithium metal batteries

Advanced Gel Polymer Electrolyte for Lithium-Ion Polymer Batteries

An All-Solid-State Lithium Metal Battery Based on Electrodes-Compatible Plastic Crystal Electrolyte

Block copolymer electrolytes for lithium batteries

Polymer electrolytes for lithium/sulfur batteries.

Polyacrylonitrile (PAN)-Based Polymer Electrolyte for Lithium-Ion Batteries

Polymer Electrolytes for Lithium/Sulfur Batteries

UV-curable semi-interpenetrating polymer network-integrated, highly bendable plastic crystal composite electrolytes for shape-conformable all-solid-state lithium ion batteries

Similar Documents

Infiltrated and Isostatic Laminated NCM and LTO Electrodes with Plastic Crystal Electrolyte Based on Succinonitrile for Lithium-Ion Solid State Batteries

Composite Electrolyte & Electrode Membranes for Electrochemical Energy Storage & Conversion Devices

Highly porous CMC-Li aerogel frameworks supported polymer solid electrolytes for lithium metal batteries

Advanced Gel Polymer Electrolyte for Lithium-Ion Polymer Batteries

An All-Solid-State Lithium Metal Battery Based on Electrodes-Compatible Plastic Crystal Electrolyte

Block copolymer electrolytes for lithium batteries

Polymer electrolytes for lithium/sulfur batteries.

Polyacrylonitrile (PAN)-Based Polymer Electrolyte for Lithium-Ion Batteries

Polymer Electrolytes for Lithium/Sulfur Batteries

UV-curable semi-interpenetrating polymer network-integrated, highly bendable plastic crystal composite electrolytes for shape-conformable all-solid-state lithium ion batteries