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Energy & Environmental Science Vol - 5 Issue - 3

Energy & Environmental Science Vol - 5 Issue - 2

Energy & Environmental Science Vol -4

Energy & Environmental Science Vol -3

Energy & Environmental Science Vol -2

Energy & Environmental Science Vol -1

Highly durable SiOC composite anode prepared by electrodeposition for lithium secondary batteries

Content Provider	Royal Society of Chemistry (RSC)
Author	Yokoshima, Tokihiko Momma, Toshiyuki Osaka, Tetsuya Nara, Hiroki
Copyright Year	2012
Abstract	A highly durable SiOC composite anode was prepared for use in lithium secondary batteries. The SiOC composite was synthesized by electrodeposition of SiCl4. The composite anode delivered a discharge capacity of 1045 mA h per gram of Si at the 2000th cycle and 842 mA h per gram of Si even at the 7200th cycle. The reason for the excellent cyclability was investigated by methods including field emission scanning electron microscopy (FESEM), scanning transmission electron microscopy with an energy dispersive X-ray analyser (STEM-EDX), and X-ray photoelectron spectroscopy (XPS). The results revealed that the excellent cyclability was achieved by the homogeneous dispersion of SiOx and organic/inorganic compounds at the nanometre scale. The structural uniformity of the SiOC composite is believed to have suppressed the crack formation attributable to the stress resulting from the reaction of silicon with lithium during charge–discharge cycles.
Starting Page	6500
Ending Page	6505
Page Count	6
File Format	HTM / HTML PDF
ISSN	17545692
Volume Number	5
Issue Number	4
Journal	Energy & Environmental Science
DOI	10.1039/c2ee03278c
Language	English
Publisher	Royal Society of Chemistry
Access Restriction	Open
Subject Keyword	Anode Lithium Electroplating Gram Scanning electron microscope Scanning transmission electron microscopy X-ray X-ray photoelectron spectroscopy Photoemission spectroscopy Dispersion relation Nanometre
Content Type	Text
Resource Type	Article
Subject	Environmental Chemistry Pollution Renewable Energy, Sustainability and the Environment Nuclear Energy and Engineering

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