NDLI: Toward the rational design of non-precious transition metal oxides for oxygen electrocatalysis

Content Provider	Royal Society of Chemistry (RSC)
Author	Risch, Marcel Hong, Wesley T. Suntivich, Jin Shao-Horn, Yang Stoerzinger, Kelsey A. Grimaud, Alexis
Copyright Year	2015
Abstract	In this Review, we discuss the state-of-the-art understanding of non-precious transition metal oxides that catalyze the oxygen reduction and evolution reactions. Understanding and mastering the kinetics of oxygen electrocatalysis is instrumental to making use of photosynthesis, advancing solar fuels, fuel cells, electrolyzers, and metal–air batteries. We first present key insights, assumptions and limitations of well-known activity descriptors and reaction mechanisms in the past four decades. The turnover frequency of crystalline oxides as promising catalysts is also put into perspective with amorphous oxides and photosystem II. Particular attention is paid to electronic structure parameters that can potentially govern the adsorbate binding strength and thus provide simple rationales and design principles to predict new catalyst chemistries with enhanced activity. We share new perspective synthesizing mechanism and electronic descriptors developed from both molecular orbital and solid state band structure principles. We conclude with an outlook on the opportunities in future research within this rapidly developing field.
Starting Page	1404
Ending Page	1427
Page Count	24
File Format	HTM / HTML PDF
ISSN	17545692
Volume Number	8
Issue Number	5
Journal	Energy & Environmental Science
DOI	10.1039/c4ee03869j
Language	English
Publisher	Royal Society of Chemistry
Access Restriction	Open
Subject Keyword	Transition metal Oxygen Photosynthesis Photosystem II Molecular orbital Electronic band structure
Content Type	Text
Resource Type	Article
Subject	Environmental Chemistry Pollution Renewable Energy, Sustainability and the Environment Nuclear Energy and Engineering

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