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Dalton Transactions Vol - 39 Issue - 5

Dalton Transactions Vol -0

Syntheses and crystal structures of four new silver(i) iodates with d⁰-transition metal cations

Content Provider	Royal Society of Chemistry (RSC)
Author	Mao, Jiang-Gao Hu, Chun-Li Kong, Fang Sun, Chuan-Fu Yang, Bing-Ping
Copyright Year	2010
Abstract	Systematic explorations of new phases in the AgI-TiIV/VV/MoVI-iodate systems led to four new quaternary silver iodates, namely, Ag2Ti(IO3)6, Ag2(VO2)(IO3)3, Ag2(V2O4)(IO3)4, and Ag2(MoO2)(IO3)4. They represent the first examples of silver iodates containing d0 transition metal cations. Ag2Ti(IO3)6 is isostructural with K2Ti(IO3)6 and its structure features a zero-dimensional (0D) [Ti(IO3)6]2− anionic unit composed of non-distorted TiO6 octahedron corner-sharing with six IO3− groups. Such anions are further bridged by Ag+ ions into a 3D network. In both Ag2(VO2)(IO3)3 and Ag2(V2O4)(IO3)4, each vanadium(V) is octahedrally coordinated by one terminal and two bridging oxo anions as well as three iodate anions in unidentate fashion. Neighboring VO6 octahedra form a 1D vanadium(V) oxide chain via corner-sharing oxo anions, such chains are further decorated by iodate anions in bridging or unidentate fashion. Ag2(VO2)(IO3)3 features a thick triple layer composed of two Ag(2)(VO2)(IO3)2 and one Ag(1)IO3 sheet whereas Ag2(V2O4)(IO3)4 features a 3D network composed of 1D [(V2O4)(IO3)3]− anionic chains along the c-axis that are interconnected by [Ag4(IO3)2]2+ clusters. Ag2(MoO2)(IO3)4 is isostructural with K2(MoO2)(IO3)4 and its structure features a 3D network built from 0D [(MoO2)(IO3)4]2− anions further interconnected by Ag+ ions. Optical and luminescent property measurements as well as band structure calculations based on density functional theory (DFT) methods have also been performed.
Starting Page	1473
Ending Page	1479
Page Count	7
File Format	HTM / HTML PDF
ISSN	14779226
Volume Number	39
Issue Number	6
Journal	Dalton Transactions
DOI	10.1039/b917907k
Language	English
Publisher	Royal Society of Chemistry
Access Restriction	Open
Subject Keyword	Transition metal Octahedron Dimension Vanadium Iodate Denticity Vanadium(V) oxide Potassium Electronic band structure Density functional theory
Content Type	Text
Resource Type	Article
Subject	Inorganic Chemistry

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