NDLI: Luminescent ternary inorganic-organic mesoporous hybrids Eu(TTASi-SBA-15)phen: covalent linkage in TTA directly functionalized SBA-15

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Front cover

Contents

Boroxine chemistry and applications: A perspective

Tetrapodal pentadentate ligands: Single site reactivity and bond activation in iron(II) complexes

Mixed template effect adjusted by amine concentration in ionothermal synthesis of molecular sieves

IPr* an easily accessible highly hindered N-heterocyclic carbene

Single-crystal to single-crystal transformations in discrete hydrated dimeric copper complexes

Extension of the charge separated-state lifetime by supramolecular association of a tetrathiafulvalene electron donor to a zinc/gold bisporphyrin

P–C dichotomy: divergent iron(−I)-mediated alkyne and phosphaalkyne cycloligomerisations

Regiocontrolled [2 + 2] photodimerization of Cd^II metal complexes in both solution and solid state

Metal complexes of thiobiurets and dithiobiurets: Novel single source precursors for metal sulfide thin film nanostructures

‘Super-reduced’ iron under physiologically-relevant conditions

Dimorphic (Ba[GaCl₄]₂)₃·2C₆H₆: a case of coordination extremes

Recoverable and recyclable magnetic nanoparticle supported aluminium isopropoxide for ring-opening polymerization of ε-caprolactone

Syntheses and crystal structures of four new silver(i) iodates with d⁰-transition metal cations

Luminescent ternary inorganic-organic mesoporous hybrids Eu(TTASi-SBA-15)phen: covalent linkage in TTA directly functionalized SBA-15

Organic–inorganic composite photocatalyst of g-C₃N₄ and TaON with improved visible light photocatalytic activities

Bimetallic Ru–Cu tellurido complexes: controlled synthesis and electrochemical studies of copper halide–TeRu₅ and Te₂Ru₄ clusters

Combining oximes with azides to create a novel 1-D [NaCo^III₂] system: synthesis, structure and solid-state NMR

S–S bond reactivity in metal-perthiocarboxylato compounds

Manisyl-substituted polypyridine coordination compounds: Metallo-supramolecular networks of interdigitated double helices assembled via CH⋯π and π–π interactions

Sensitized near-IR luminescence of lanthanide complexes based on push-pull diketone derivatives

Tetranuclear copper(ii)–Schiff-base complexes as active catalysts for oxidation of cyclohexane and toluene

Lone electron-pair enhancement of SHG responses in eulytite-type compounds: A^II₃M^III(PO₄)₃ (A = Pb, M = Bi; A = Ba, M = Bi, La)

Nanoporous lanthanide-carboxylate frameworks based on 5-nitroisophthalic acid

Speciation in solution, solid state spectroscopy and vapochromism of [Pt(trpy)(NCS)]SbF₆ where trpy = 2,2′:6′,2′′-terpyridine

Monoorganooxotin cage, diorganotin ladders, diorganotin double chain and triorganotin single chain formed with phosphonate and arsonate ligands

Nitrite reduction by copper complexes

Efficient electrogenerated chemiluminescence from osmium(ii) polypyridine systems containing tetraphenylarsine or diphenylphosphine ligands

Palladium complexes of 6-aminofulvene-2-aldiminate (AFA) ligands

Synthesis and structural diversity of oligosilanylzinc compounds

In vitro studies of 3-hydroxy-4-pyridinones and their glycosylated derivatives as potential agents for Alzheimer's disease

Hypovalent titanium and Ti(ii)–Ti(iii) interconversions

Ligand substitution behavior of Ru₆(μ₆-C)(CO)₁₇ with unsaturated diphosphines: facile capping of a polyhedral face and photochemically promoted P–C bond cleavage in the cluster Ru₆(μ₆-C)(CO)₁₄(μ₃-bpcd)

Activation of dioxygen by a mononuclear non-heme iron complex: characterization of a Fe^III(OOH) intermediate

Coordination of neutral, methylene bridged bis-guanidyls at palladium

Tuning of the charge in octahedral ferric complexes based on pyridoxal-N-substituted thiosemicarbazone ligands

Back matter

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Dalton Transactions Vol - 39 Issue - 5

Dalton Transactions Vol -0

Luminescent ternary inorganic-organic mesoporous hybrids Eu(TTASi-SBA-15)phen: covalent linkage in TTA directly functionalized SBA-15

Content Provider	Royal Society of Chemistry (RSC)
Author	Li, Ying Yan, Bing
Copyright Year	2010
Abstract	A novel kind of luminescent ternary organic–inorganic mesoporous hybrid Eu(TTASi-SBA-15)3phen (phen = 1,10-phenanthroline) has been assembled by the Eu3+ complex covalently attached to the TTA directly Functionalized ordered mesoporous SBA-15, which is characterized to have high surface area, uniformity in the mesostructure and crystallinity. The efficient intramolecular energy transfer in mesoporous material Eu(TTASi-SBA-15)3phen mainly occurs between the modified ligand TTASi and the central Eu3+ ion. Furthermore, compared with the binary mesoporous material Eu(TTASi-SBA-15)3, the ternary mesoporous material Eu(TTASi-SBA-15)3phen exhibits the characteristic emission of the Eu3+ ion with a higher luminescence quantum efficiency intensity and a longer lifetime, suggesting that the introduction of ligand phen into the mesoporous matrix is of benefit for the sentisization of Eu3+luminescence, by replacing H2O groups that can quench the luminescence of Eu3+ ions.
Starting Page	1480
Ending Page	1487
Page Count	8
File Format	HTM / HTML PDF
ISSN	14779226
Volume Number	39
Issue Number	6
Journal	Dalton Transactions
DOI	10.1039/b914586a
Language	English
Publisher	Royal Society of Chemistry
Access Restriction	Open
Subject Keyword	TTA Mesoporous material Phenanthroline Ligand Ion Luminescence Quantum tunnelling Extracellular matrix Water
Content Type	Text
Resource Type	Article
Subject	Inorganic Chemistry

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