NDLI: Synthesis and characterization of layered metal sulfates containing MII3(μ<sub>3</sub>-OH/F)<sub>2</sub>(M = Mg, Co) diamond chains

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Dalton Transactions Vol - 46 Issue - 3

Dalton Transactions Vol - 46 Issue - 2

Dalton Transactions Vol -39

Dalton Transactions Vol -0

Synthesis and characterization of layered metal sulfates containing MII3(μ₃-OH/F)₂(M = Mg, Co) diamond chains

Content Provider	Royal Society of Chemistry (RSC)
Author	Mahana, Sudipta Marri, Subba R. Behera, J. N. Topwal, Dinesh
Copyright Year	2017
Abstract	Cobalt and magnesium sulfates of the compositions, [C4N2H12]2[Co3F2(SO4)3(H2O)2], (1) and [NH4]2[Mg3(OH)2(SO4)3(H2O)2], (2), respectively, have been synthesized under hydro/solvothermal conditions, and are characterized by IR spectra, elemental analysis, powder X-ray diffraction (PXRD), energy-dispersive X-ray spectroscopy (EDX), thermogravimetric analysis (TGA), and X-ray single-crystal diffraction. 1 and 2 crystallized in the orthorhombic space groups Pnma and Cmc2 respectively. While 1 is templated by the organic piperazinium cation, 2 is obtained in the presence of ammonium ions. The layered structures are formed by the diamond chains comprising of M3(μ3-OH/F)2 units (M = Co: 1, Mg: 2). Magnetic studies of 1 reveal its ferromagnetic nature with a transition at 10.8 K and show it does not exhibit spin-glass freezing. Isothermal magnetization shows a hysteresis loop at 2.5 K with a coercive field of 1200 Oe and remnant magnetization of 0.1μB. A sharp λ-like anomaly is also seen in the heat capacity curve, favoring long range magnetic ordering below Tc.
Starting Page	1105
Ending Page	1111
Page Count	7
File Format	HTM / HTML PDF
ISSN	14779226
Volume Number	46
Issue Number	4
Journal	Dalton Transactions
DOI	10.1039/c6dt04142f
Language	English
Publisher	Royal Society of Chemistry
Access Restriction	Open
Subject Keyword	Pnma Magnesium Water of crystallization Rheinmetall MG 3 X-ray crystallography Energy-dispersive X-ray spectroscopy Thermogravimetric analysis Neutron diffraction Orthorhombic crystal system Ion Ammonium BMW M3 Ferromagnetism Hysteresis Coercivity Properties of water
Content Type	Text
Resource Type	Article
Subject	Inorganic Chemistry

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