NDLI: Ag containing porous Au structures as highly selective catalysts for glycolate and formate

Please wait, while we are loading the content...

Elucidating and exploiting the chemistry of Keggin heteropolyacids in the methanol-to-DME conversion: enabling the bulk reaction thanks to operando Raman

Electrocatalytic hydrogenation of pyridinium enabled by surface proton transfer reactions

Macroporous SmMn₂O₅ mullite for NO_x-assisted soot combustion

Mechanistic insights for the photoredox organocatalytic fluorination of aliphatic carbons by anthraquinone using time-resolved and DFT studies

Acidity and accessibility studies of desilicated ZSM-5 zeolites in terms of their effectiveness as catalysts in acid-catalyzed cracking processes

Ag containing porous Au structures as highly selective catalysts for glycolate and formate

Petal-like hierarchical array of ultrathin Ni(OH)₂ nanosheets decorated with Ni(OH)₂ nanoburls: a highly efficient OER electrocatalyst

Unusual deactivation of HZSM-5 zeolite in the methanol to hydrocarbon reaction

Catalytic role of bridging oxygens in TiO₂ liquid phase photocatalytic reactions: analysis of H₂¹⁶O photooxidation on labeled Ti¹⁸O₂

Cleavage mechanism of the aliphatic C–C bond catalyzed by 2,4′-dihydroxyacetophenone dioxygenase from Alcaligenes sp. 4HAP: a QM/MM study

Photocatalytic coupling of formaldehyde to ethylene glycol and glycolaldehyde over bismuth vanadate with controllable facets and cocatalysts

Highly efficient removal of organic contaminants based on peroxymonosulfate activation by iron phthalocyanine: mechanism and the bicarbonate ion enhancement effect

Mechanisms governing selective hydrogenation of acetylene over γ-Mo₂N surfaces

Large improvement of visible-light photocatalytic H₂-evolution based on cocatalyst-free Zn_0.5Cd_0.5S synthesized through a two-step process

Catalysts of 3D ordered macroporous ZrO₂-supported core–shell Pt@CeO_2−x nanoparticles: effect of the optimized Pt–CeO₂ interface on improving the catalytic activity and stability of soot oxidation

Hexagonal Zn_1−xCd_xS (0.2 ≤x≤ 1) solid solution photocatalysts for H₂ generation from water

On the Mn promoted synthesis of higher alcohols over Cu derived ternary catalysts

Hierarchical yolk–shell layered potassium niobate for tuned pH-dependent photocatalytic H₂ evolution

Nanobelt α-CuV₂O₆ with hydrophilic mesoporous poly(ionic liquid): a binary catalyst for synthesis of 2,5-diformylfuran from fructose

Inside back cover

Back cover

Catalysis Science & Technology Vol - 7 Issue - 3

Catalysis Science & Technology Vol - 7 Issue - 2

Catalysis Science & Technology Vol - 7 Issue - 1

Catalysis Science & Technology Vol -6

Catalysis Science & Technology Vol -5

Catalysis Science & Technology Vol -4

Catalysis Science & Technology Vol -3

Catalysis Science & Technology Vol -2

Catalysis Science & Technology Vol -1

Ag containing porous Au structures as highly selective catalysts for glycolate and formate

Content Provider	Royal Society of Chemistry (RSC)
Author	Kim, Donghwan Wang, Xin Xie, Mingshi Thia, Larissa
Copyright Year	2017
Abstract	Formic acid and its salts are important chemical intermediates. Industrial production of formic acid involves liquid phase carbonylation of methanol to methyl formate followed by hydrolysis to formic acid. Alternatively, formic acid can be generated during glycerol electro-oxidation when glycerol undergoes C–C bond cleavage. Silver based catalysts such as carbon supported silver–gold alloys significantly improve selectivity to formic acid during glycerol electro-oxidation. However, these catalysts tend to suffer from poor electro-chemical activity. Herein, we examined the ability of Ag containing, porous Au structures to tune the glycerol oxidation pathway towards formate and glycolate whilst maintaining high electro-catalytic activity. Our catalyst consisted of an Au rich porous framework that possessed residual amounts of Ag within its pores. When tested for glycerol electro-oxidation, the Ag containing porous Au catalyst exhibited both high selectivity towards formate and high electrochemical activity.
Starting Page	874
Ending Page	881
Page Count	8
File Format	HTM / HTML PDF
ISSN	20444753
Volume Number	7
Issue Number	4
Journal	Catalysis Science & Technology
DOI	10.1039/c6cy02580c
Language	English
Publisher	Royal Society of Chemistry
Access Restriction	Open
Subject Keyword	Hydrolysis Carbonylation Carboxylic acid Methyl formate Chemical bond Formic acid Glycolic acid Glycerol Electrochemistry Carbon Methanol
Content Type	Text
Resource Type	Article
Subject	Catalysis

Sl.	Authority	Responsibilities	Communication Details
1	Ministry of Education (GoI), Department of Higher Education	Sanctioning Authority	https://www.education.gov.in/ict-initiatives
2	Indian Institute of Technology Kharagpur	Host Institute of the Project: The host institute of the project is responsible for providing infrastructure support and hosting the project	https://www.iitkgp.ac.in
3	National Digital Library of India Office, Indian Institute of Technology Kharagpur	The administrative and infrastructural headquarters of the project	Dr. B. Sutradhar bsutra@ndl.gov.in
4	Project PI / Joint PI	Principal Investigator and Joint Principal Investigators of the project	Dr. B. Sutradhar bsutra@ndl.gov.in Prof. Saswat Chakrabarti will be added soon
5	Website/Portal (Helpdesk)	Queries regarding NDLI and its services	support@ndl.gov.in
6	Contents and Copyright Issues	Queries related to content curation and copyright issues	content@ndl.gov.in
7	National Digital Library of India Club (NDLI Club)	Queries related to NDLI Club formation, support, user awareness program, seminar/symposium, collaboration, social media, promotion, and outreach	clubsupport@ndl.gov.in
8	Digital Preservation Centre (DPC)	Assistance with digitizing and archiving copyright-free printed books	dpc@ndl.gov.in
9	IDR Setup or Support	Queries related to establishment and support of Institutional Digital Repository (IDR) and IDR workshops	idr@ndl.gov.in

Oxidative esterification of ethylene glycol in methanol to form methyl glycolate over supported Au catalysts

Conversion of Green Methanol to Methyl Formate

Formic Acid Oxidation over Hierarchical Porous Carbon Containing PtPd Catalysts

Methanol Selective Oxidation to Methyl Formate over ReOx/CeO2 Catalysts

Selective oxidation of methanol to methyl formate on catalysts of Au–Ag alloy nanoparticles supported on titania under UV irradiation

Photocatalytically Reducing CO2 to Methyl Formate in Methanol Over Ag Loaded SrTiO3 Nanocrystal Catalysts

Reaction Kinetics of Methanol Carbonylation to Methyl Formate Catalyzed by CH3O− Exchange Resin

Progress in inorganic cathode catalysts for electrochemical conversion of carbon dioxide into formate or formic acid

Catalytic Disproportionation of Formic Acid to Methanol using Recyclable Silylformates

Ag containing porous Au structures as highly selective catalysts for glycolate and formate

Similar Documents

Oxidative esterification of ethylene glycol in methanol to form methyl glycolate over supported Au catalysts

Conversion of Green Methanol to Methyl Formate

Formic Acid Oxidation over Hierarchical Porous Carbon Containing PtPd Catalysts

Methanol Selective Oxidation to Methyl Formate over ReOx/CeO2 Catalysts

Selective oxidation of methanol to methyl formate on catalysts of Au–Ag alloy nanoparticles supported on titania under UV irradiation

Photocatalytically Reducing CO2 to Methyl Formate in Methanol Over Ag Loaded SrTiO3 Nanocrystal Catalysts

Reaction Kinetics of Methanol Carbonylation to Methyl Formate Catalyzed by CH3O− Exchange Resin

Progress in inorganic cathode catalysts for electrochemical conversion of carbon dioxide into formate or formic acid

Catalytic Disproportionation of Formic Acid to Methanol using Recyclable Silylformates

Ag containing porous Au structures as highly selective catalysts for glycolate and formate