NDLI: Palladium catalysts supported on carbon–nitrogen composites for aqueous-phase hydrogenation of phenol

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Inside front cover

Solar thermal catalytic reforming of natural gas: a review on chemistry, catalysis and system design

Recent advances in metal free- and late transition metal-catalysed hydroamination of unactivated alkenes

Specific oxyfunctionalisations catalysed by peroxygenases: opportunities, challenges and solutions

Maximizing n-alkane hydroisomerization: the interplay of phase, feed complexity and zeolite catalyst mixing

Exceptional activity of sub-nm Pt clusters on CdS for photocatalytic hydrogen production: a combined experimental and first-principles study

Novel glycosyl pyridyl-triazole@palladium nanoparticles: efficient and recoverable catalysts for C–C cross-coupling reactions

MnNiCoO₄/N-MWCNT nanocomposite catalyst with high selectivity in membraneless direct formate fuel cells and bifunctional activity for oxygen electrochemistry

Multi-scale promoting effects of lead for palladium catalyzed aerobic oxidative coupling of methylacrolein with methanol

(Salicylaldiminato)Ni(ii)-catalysts for hydrosilylation of olefins

Mechanochemical preparation of advanced catalytically active bifunctional Pd-containing nanomaterials for aqueous phase hydrogenation

Ionic liquid-functionalized graphene oxide as an efficient support for the chiral salen Mn(iii) complex in asymmetric epoxidation of unfunctionalized olefins

Sustainable production of dimethyl adipate by non-heme iron(iii) catalysed oxidative cleavage of catechol

Mechanistic insight into the Z–E isomerization catalysis of azobenzenes mediated by bare and core–shell gold nanoparticles

Cu–Mo doped zeolite ZSM-5 catalyzed conversion of lignin to alkyl phenols with high selectivity

High specific surface area YSZ powders from a supercritical CO₂ process as catalytic supports for NO_x storage–reduction reaction

The mechanism of the effect of H₂O on the low temperature selective catalytic reduction of NO with NH₃ over Mn–Fe spinel

Facile one-pot fabrication of a silica gel-supported chiral phase-transfer catalyst—N-(2-cyanobenzyl)-O(9)-allyl-cinchonidinium salt

Enhanced catalytic activity of Au nanoparticles self-assembled on thiophenol functionalized graphene

Mechanistic insights into hydrogen generation for catalytic hydrolysis and alcoholysis of silanes with high-valent oxorhenium(v) complexes

Palladium nanoparticles supported on graphene as catalysts for the dehydrogenative coupling of hydrosilanes and amines

Simple soluble Bi(iii) salts as efficient catalysts for the oxidation of alkanes with H₂O₂

Promotional effect of doping SnO₂ into TiO₂ over a CeO₂/TiO₂ catalyst for selective catalytic reduction of NO by NH₃

Iron-catalyzed aerobic oxidative functionalization of sp³ C–H bonds: a versatile strategy for the construction of N-heterocycles

Electrochemical activation of an oblique angle deposited Cu catalyst film for H₂ production

In-depth structure–selectivity investigations on asymmetric, copper-catalyzed oxidative biaryl coupling in the presence of 5-cis-substituted prolinamines

Ozone catalytic oxidation for ammonia removal from simulated air at room temperature

Synthesis of ethyl hexyl ether over acidic ion-exchange resins for cleaner diesel fuel

Promoting effect of Nd on the reduction of NO with NH₃ over CeO₂ supported by activated semi-coke: an in situ DRIFTS study

Enhanced performance in NO_x reduction by NH₃ over a mesoporous Ce–Ti–MoO_x catalyst stabilized by a carbon template

High surface area La₂Sn₂O₇ pyrochlore as a novel, active and stable support for Pd for CO oxidation

Influence of structural and electronic properties of organomolybdenum(ii) complexes of the type [CpMo(CO)₃R] and [CpMo(O₂)(O)R] (R = Cl, CH₃, CF₃) on the catalytic olefin epoxidation

DRIFTS study of a Ce–W mixed oxide catalyst for the selective catalytic reduction of NO_x with NH₃

Palladium catalysts supported on carbon–nitrogen composites for aqueous-phase hydrogenation of phenol

Catalytic oxidation of formaldehyde over manganese oxides with different crystal structures

Quaternary ammonium hydroxide as a metal-free and halogen-free catalyst for the synthesis of cyclic carbonates from epoxides and carbon dioxide

Continuous synthesis of diethyl carbonate from ethanol and CO₂ over Ce–Zr–O catalysts

Photocatalytic hydrogen evolution from a cobalt/nickel complex with dithiolene ligands under irradiation with visible light

Catalytic asymmetric [3,3]-rearrangements of allylic acetimidates

Direct synthesis of dimethyl ether from CO₂ hydrogenation over Cu–ZnO–ZrO₂/SO₄²⁻–ZrO₂ hybrid catalysts: effects of sulfur-to-zirconia ratios

Size-dependent CO and propylene oxidation activities of platinum nanoparticles on the monolithic Pt/TiO₂–YO_x diesel oxidation catalyst under simulative diesel exhaust conditions

Enhanced catalytic activity of hierarchically macro-/mesoporous Pt/TiO₂ toward room-temperature decomposition of formaldehyde

Soluble polymer-supported hindered phosphine ligands for palladium-catalyzed aryl amination

Electrocatalytic stereoselective transformation of aldehydes and two molecules of pyrazolin-5-one into (R*,R*)-bis(spiro-2,4-dihydro-3H-pyrazol-3-one)cyclopropanes

Room temperature Suzuki coupling of aryl iodides, bromides, and chlorides using a heterogeneous carbon nanotube-palladium nanohybrid catalyst

Catalytic oxidation of cellobiose over TiO₂ supported gold-based bimetallic nanoparticles

Iron catalyzed halogenation of benzylic aldehydes and ketones

Reversibility of asymmetric catalyzed C–C bond formation by benzoylformate decarboxylase

Synthesis of aluminium triflate-grafted MCM-41 as a water-tolerant acid catalyst for the ketalization of glycerol with acetone

Hydrogenation of succinic acid over supported rhenium catalysts prepared by the microwave-assisted thermolytic method

Triphenylphosphine: a ligand for heterogeneous catalysis too? Selectivity enhancement in acetylene hydrogenation over modified Pd/TiO₂ catalyst

Asymmetric 1,3-dipolar cycloaddition reactions between enals and nitrones catalysed by half-sandwich rhodium or iridium diphosphane complexes

Copper oxide as efficient catalyst for oxidative dehydrogenation of alcohols with air

Experimental and DFT studies on Sr-doped LaMnO₃ catalysts for NO_x storage and reduction

The preparation of Fe/wood-based activated carbon catalyst for phenol hydroxylation from Fe²⁺ and Fe³⁺ precursors

A heteropoly acid ionic crystal containing Cr as an active catalyst for dehydration of monosaccharides to produce 5-HMF in water

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Palladium catalysts supported on carbon–nitrogen composites for aqueous-phase hydrogenation of phenol

Content Provider	Royal Society of Chemistry (RSC)
Author	Chen, Ping Lou, Hui Feng, Gang
Copyright Year	2015
Abstract	Phenol is an important component of pyrolysis bio-oil, especially from lignin, and the conversion of phenol is crucial for the production of biofuel. A cost-effective and efficient catalyst is worth developing in the hydrogenation of phenol. Herein we report that supported palladium nanoparticles on carbon–nitrogen composites with high surface area are highly active for aqueous-phase hydrogenation of phenol. The conversion of phenol was 91.7% within 1 h at 80 °C. Higher activity was achieved at higher temperature. The synergy between palladium nanoparticles and the carbon–nitrogen composite support accelerated the hydrogenation of phenol, which clarified the crucial role played by the support. The hydrogenation of phenol highlights the potential of these catalysts for upgrading bio-oil.
Starting Page	2300
Ending Page	2304
Page Count	5
File Format	HTM / HTML PDF
ISSN	20444753
Volume Number	5
Issue Number	4
Journal	Catalysis Science & Technology
DOI	10.1039/c4cy01647e
Language	English
Publisher	Royal Society of Chemistry
Access Restriction	Open
Subject Keyword	Pyrolysis Lignin Phenol Pyrolysis oil Biofuel Hydrogenation
Content Type	Text
Resource Type	Article
Subject	Catalysis

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