NDLI: Synthesis of cyclic carbonates from CO<sub>2</sub> and epoxides using ionic liquids and related catalysts including choline chloride

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Catalysis Science & Technology Vol - 4 Issue - 5

Catalysis Science & Technology Vol - 4 Issue - 4

Catalysis Science & Technology Vol - 4 Issue - 3

Catalysis Science & Technology Vol - 4 Issue - 2

Catalysis Science & Technology Vol -3

Catalysis Science & Technology Vol -2

Catalysis Science & Technology Vol -1

Synthesis of cyclic carbonates from CO₂ and epoxides using ionic liquids and related catalysts including choline chloride–metal halide mixtures

Content Provider	Royal Society of Chemistry (RSC)
Author	Tompkins, Lindsay E. Kitselman, Kayla A. O'Brien, Jeremy W. He, Qing Curtis, Gregory C. T. Kerton, Francesca M.
Copyright Year	2014
Abstract	In this mini-review, progress made in the use of ionic liquid catalysts and related systems for cycloaddition reactions of carbon dioxide with epoxides is described with the primary focus on results from the past eight years. Catalysts described range from simple onium species including tetrabutylammonium bromide, functionalized and simple imidazolium ionic liquids, to a plethora of supported ionic liquid systems. A range of supports including alumina, silica, carbon nanotubes, magnetic nanoparticles, poly(ethyleneglycol), polystyrene, cellulose and chitosan have been used with a variety of ionic groups. These include ammonium, phosphonium and both functionalized and unfunctionalized imidazolium salts. Results have been tabulated to summarize reaction conditions and TONs for styrene oxide, propylene oxide and cyclohexene oxide conversions. It is clear that metal ions used in combination with ionic liquids, particularly ZnBr2, can enhance conversions, and hydroxyl, carboxyl and other functional groups capable of hydrogen-bonding can be incorporated to improve catalysis. Some recent results using flow reactors are highlighted. Examples of ionic catalysts used in the related processes of oxidative carboxylation of alkenes, which also yields cyclic carbonate products, and carbon dioxide–aziridine coupling reactions, which yield oxazolidinone products are described. New data on catalytic styrene carbonate production using choline chloride-transition metal chloride mixtures are presented. For 3d metals, the catalytic activity of these mixtures is Cr > Co ≈ Fe ≈ Ni > Mn ≫ Cu.
Starting Page	1513
Ending Page	1528
Page Count	16
File Format	HTM / HTML PDF
ISSN	20444753
Volume Number	4
Issue Number	6
Journal	Catalysis Science & Technology
DOI	10.1039/c3cy00998j
Language	English
Publisher	Royal Society of Chemistry
Access Restriction	Open
Subject Keyword	Aluminium oxide Quaternary ammonium cation Ethylene glycol Tetra-n-butylammonium bromide Carbon dioxide Cellulose Cyclohexene oxide Polystyrene Phosphonium Carbon Silicon dioxide Ionic liquid Styrene oxide Carbon nanotube Propylene oxide Cycloaddition Chloride 2-Oxazolidone Choline Styrene Carboxylation Chitosan Hydroxide
Content Type	Text
Resource Type	Article
Subject	Catalysis

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Quaternary ammonium hydroxide as a metal-free and halogen-free catalyst for the synthesis of cyclic carbonates from epoxides and carbon dioxide

A single centre aluminium(iii) catalyst and TBAB as an ionic organo-catalyst for the homogeneous catalytic synthesis of styrene carbonate

Cycloaddition Reaction of Carbon Dioxide to Epoxides Catalyzed by Polymer-Supported Quaternary Phosphonium Salts

Titanate nanotube-promoted chemical fixation of carbon dioxide to cyclic carbonate: a combined experimental and computational study

Recovery and reuse of ionic liquids and palladium catalyst for Suzuki reactions using organic solvent nanofiltration

Cycloaddition Reaction of Carbon Dioxide to Epoxides Catalyzed by Polymer-Supported Quaternary Phosphonium Salts

Efficient synthesis of dimethyl carbonate from methanol, propylene oxide and CO₂ catalyzed by recyclable inorganic base/phosphonium halide-functionalized polyethylene glycol

Quaternary ammonium hydroxide as a metal-free and halogen-free catalyst for the synthesis of cyclic carbonates from epoxides and carbon dioxide

Effective synthesis of propylene carbonate from propylene glycol and carbon dioxide by alkali carbonates

Synthesis of cyclic carbonates from CO₂ and epoxides using ionic liquids and related catalysts including choline chloride–metal halide mixtures

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