NDLI: Two-dimensional crystal engineering using halogen and hydrogen bonds: towards structural landscapes

Content Provider	Royal Society of Chemistry (RSC)
Author	Mukherjee, Arijit Feyter, Steven De Hennrich, Gunther Teyssandier, Joan Mali, Kunal S.
Copyright Year	2017
Abstract	Two-dimensional (2D) crystallization on solid surfaces is governed by a subtle balance of supramolecular and interfacial interactions. However, these subtle interactions often make the prediction of supramolecular structure from the molecular structure impossible. As a consequence, surface-based 2D crystallization has often been studied on a case-by-case basis, which hinders the identification of structure-determining relationships between different self-assembling systems. Here we begin the discussion on such structure-determining relationships by comparing the 2D crystallization of two identical building blocks based on a 1,3,5-tris(pyridine-4-ylethynyl)benzene unit at the solution–solid interface. The concepts of supramolecular synthons and structural landscapes are introduced in the context of 2D crystallization on surfaces to identify common structural elements. The systems are characterized using scanning tunneling microscopy (STM). This strategy involves carrying out minor structural modifications on the parent compound to access supramolecular patterns that are otherwise not obtained. We demonstrate that this chemical perturbation strategy translates equally well for 2D co-crystallization experiments with halogen bond donors yielding porous bi-component networks. The holistic approach described here represents a stepping stone towards gaining predictive power over the 2D crystallization of molecules on solid surfaces.
Starting Page	3759
Ending Page	3769
Page Count	11
File Format	HTM / HTML PDF
ISSN	20416520
Volume Number	8
Issue Number	5
Journal	Chemical Science
DOI	10.1039/c7sc00129k
Language	English
Publisher	Royal Society of Chemistry
Access Restriction	Subscribed
Subject Keyword	Pyridine Benzene Halogen Covalent bond Scanning tunneling microscope Synthon
Content Type	Text
Resource Type	Article
Subject	Chemistry

Sl.	Authority	Responsibilities	Communication Details
1	Ministry of Education (GoI), Department of Higher Education	Sanctioning Authority	https://www.education.gov.in/ict-initiatives
2	Indian Institute of Technology Kharagpur	Host Institute of the Project: The host institute of the project is responsible for providing infrastructure support and hosting the project	https://www.iitkgp.ac.in
3	National Digital Library of India Office, Indian Institute of Technology Kharagpur	The administrative and infrastructural headquarters of the project	Dr. B. Sutradhar bsutra@ndl.gov.in
4	Project PI / Joint PI	Principal Investigator and Joint Principal Investigators of the project	Dr. B. Sutradhar bsutra@ndl.gov.in Prof. Saswat Chakrabarti will be added soon
5	Website/Portal (Helpdesk)	Queries regarding NDLI and its services	support@ndl.gov.in
6	Contents and Copyright Issues	Queries related to content curation and copyright issues	content@ndl.gov.in
7	National Digital Library of India Club (NDLI Club)	Queries related to NDLI Club formation, support, user awareness program, seminar/symposium, collaboration, social media, promotion, and outreach	clubsupport@ndl.gov.in
8	Digital Preservation Centre (DPC)	Assistance with digitizing and archiving copyright-free printed books	dpc@ndl.gov.in
9	IDR Setup or Support	Queries related to establishment and support of Institutional Digital Repository (IDR) and IDR workshops	idr@ndl.gov.in

l crystal engineering using halogen and hydrogen bonds : towards structural landscapes †

Crystal engineering with hydrogen bonds and halogen bonds

Two-dimensional supramolecular chemistry on surfaces

Halogen bonded two-dimensional supramolecular assemblies studied by high resolution scanning tunneling microscopy

Two-Dimensional Crystal Growth Process of n-Alkane Molecules Observed Using Scanning Tunneling Microscope

Molecular templates and nano-reactors: two-dimensional hydrogen bonded supramolecular networks on solid/liquid interfaces

Halogen bonds in 2D supramolecular self-assembly of organic semiconductors

Obtaining Synthon Modularity In Ternary Cocrystals With Hydrogen Bonds And Halogen Bonds

The Impact of Halogen Substituents on the Synthesis and Structure of Co-Crystals of Pyridine Amides

Two-dimensional crystal engineering using halogen and hydrogen bonds: towards structural landscapes

Similar Documents

l crystal engineering using halogen and hydrogen bonds : towards structural landscapes †

Crystal engineering with hydrogen bonds and halogen bonds

Two-dimensional supramolecular chemistry on surfaces

Halogen bonded two-dimensional supramolecular assemblies studied by high resolution scanning tunneling microscopy

Two-Dimensional Crystal Growth Process of n-Alkane Molecules Observed Using Scanning Tunneling Microscope

Molecular templates and nano-reactors: two-dimensional hydrogen bonded supramolecular networks on solid/liquid interfaces

Halogen bonds in 2D supramolecular self-assembly of organic semiconductors

Obtaining Synthon Modularity In Ternary Cocrystals With Hydrogen Bonds And Halogen Bonds

The Impact of Halogen Substituents on the Synthesis and Structure of Co-Crystals of Pyridine Amides

Two-dimensional crystal engineering using halogen and hydrogen bonds: towards structural landscapes