NDLI: [M3(μ3-O)(O2CR)6] and related trigonal prisms: versatile molecular building blocks for crystal engineering of metal

Please wait, while we are loading the content...

Solid-state structural transformation doubly triggered by reaction temperature and time in 3D metal-organic frameworks: great enhancement of stability and gas adsorption

Non-close-packed pore arrays through one-step breath figure self-assembly and reversal

Insight into aggregation-induced emission characteristics of red-emissive quinoline-malononitrile by cell tracking and real-time trypsin detection

Three-electron two-centred bonds and the stabilisation of cationic sulfur radicals

High-capacity Li₂S–graphene oxide composite cathodes with stable cycling performance

A tripodal peptide ligand for asymmetric Rh(ii) catalysis highlights unique features of on-bead catalyst development

Atomic properties and chemical bonding in the pyrite and marcasite polymorphs of FeS₂: a combined experimental and theoretical electron density study

Photoscopy: spectroscopic information from camera snapshots?

Hydrogen atom abstraction reactions independent of C–H bond dissociation energies of organic substrates in water: significance of oxidant–substrate adduct formation

A peptide-free, liposome-based oligosaccharide vaccine, adjuvanted with a natural killer T cell antigen, generates robust antibody responses in vivo

Highly enantioselective S–H bond insertion cooperatively catalyzed by dirhodium complexes and chiral spiro phosphoric acids

Probing the mobility of catenane rings in single molecules

Theoretical study of the magnetic anisotropy and magnetic tunnelling in mononuclear Ni(ii) complexes with potential molecular magnet behavior

Highly efficient cycloreversion of photochromic dithienylethene compounds using visible light-driven photoredox catalysis

A light-induced reversible phase separation and its coupling to a dynamic library of imines

Nanoscale self-assembled multivalent (SAMul) heparin binders in highly competitive, biologically relevant, aqueous media

Computational prediction and experimental confirmation of B-site doping in YBa₂Fe₃O₈

Observation of the rare chrysene excimer

BiVO₄–Ru/SrTiO₃:Rh composite Z-scheme photocatalyst for solar water splitting

Tristable [n]rotaxanes: from molecular shuttle to molecular cable car

Iron-mediated intermolecular N-group transfer chemistry with olefinic substrates

Utilizing the bioorthogonal base-pairing system of l-DNA to design ideal DNA nanocarriers for enhanced delivery of nucleic acid cargos

NIR electrochemical fluorescence switching from polymethine dyes

Sodium phosphaethynolate, Na(OCP), as a “P” transfer reagent for the synthesis of N-heterocyclic carbene supported P₃ and PAsP radicals

Predicting pathways for terpene formation from first principles – routes to known and new sesquiterpenes

Evaluating atomic components in fluorene wires

Hierarchically tetramodal-porous zeolite ZSM-5 monoliths with template-free-derived intracrystalline mesopores

Palladium-catalyzed benzo[d]isoxazole synthesis by C–H activation/[4 + 1] annulation

Gold(iii) complexes inhibit growth of cisplatin-resistant ovarian cancer in association with upregulation of proapoptotic PMS2 gene

Catalytic enantioselective synthesis of 2-(2-hydroxyethyl)indole scaffolds via consecutive intramolecular amido-cupration of allenes and asymmetric addition of carbonyl compounds

Selective and reversible photochemical derivatization of cysteine residues in peptides and proteins

Engineered spatial inversion symmetry breaking in an oxide heterostructure built from isosymmetric room-temperature magnetically ordered components

Glycopolymers with secondary binding motifs mimic glycan branching and display bacterial lectin selectivity in addition to affinity

A series of C₃-symmetric heterobimetallic Cr–M (M = Fe, Co and Cu) complexes

Remarkable influence of secondary catalyst site on enantioselective desymmetrization of cyclopentenedione

A quantitative and site-specific chemoenzymatic glycosylation approach for PEGylated MUC1 peptides

Inhibition of the 4Fe–4S proteins IspG and IspH: an EPR, ENDOR and HYSCORE investigation

Modifying the properties of 4f single-ion magnets by peripheral ligand functionalisation

Inside back cover

Back cover

Chemical Science Vol - 5 Issue - 3

Chemical Science Vol - 5 Issue - 2

Chemical Science Vol -4

Chemical Science Vol -3

Chemical Science Vol -2

Chemical Science Vol -1

[M₃(μ₃-O)(O₂CR)₆] and related trigonal prisms: versatile molecular building blocks for crystal engineering of metal–organic material platforms

Content Provider	Royal Society of Chemistry (RSC)
Author	Schoedel, Alexander Zaworotko, Michael J.
Copyright Year	2014
Abstract	This review details the emergence of metal–organic materials (MOMs) sustained by high symmetry trigonal prismatic molecular building blocks (MBBs). MOMs have attracted general attention over the past two decades as judicious selection of MBBs allows crystal engineers to exert exquisite control over MOM structure, which, when combined with their modularity, diverse composition and fine-tuneable structural features, makes their properties controllable in a manner uncommon in materials science. In this context, tetrahedral and octahedral MBBs, which readily afford diamondoid (dia) or primitive cubic (pcu) nets, respectively, are the most commonly studied MBBs. However, trigonal prismatic MBBs have also captured the imagination of crystal engineers since they can sustain stable, high symmetry, extra-large surface area nets with new topologies and exhibit excellent gas sorption performance. Nets formed by linking [M3(μ3-O)(O2CR)6] MBBs are of particular interest and are discussed from a crystal engineering perspective. These MBBs can form discrete (0-D) polyhedra, 2-D grids and 3-D nets that represent families or “platforms” that enable systematic studies of structure–property relationships. The development of decorated [M3(μ3-O)(O2CR)6] MBBs that facilitate a 2-step strategy for generation of novel MOM platforms from simple, low cost MBBs, is also discussed.
Starting Page	1269
Ending Page	1282
Page Count	14
File Format	HTM / HTML PDF
ISSN	20416520
Volume Number	5
Issue Number	4
Journal	Chemical Science
DOI	10.1039/c4sc00171k
Language	English
Publisher	Royal Society of Chemistry
Access Restriction	Open
Subject Keyword	Sorption Crystal engineering Diamondoid Materials science BMW M3 2-step garage
Content Type	Text
Resource Type	Article
Subject	Chemistry

Sl.	Authority	Responsibilities	Communication Details
1	Ministry of Education (GoI), Department of Higher Education	Sanctioning Authority	https://www.education.gov.in/ict-initiatives
2	Indian Institute of Technology Kharagpur	Host Institute of the Project: The host institute of the project is responsible for providing infrastructure support and hosting the project	https://www.iitkgp.ac.in
3	National Digital Library of India Office, Indian Institute of Technology Kharagpur	The administrative and infrastructural headquarters of the project	Dr. B. Sutradhar bsutra@ndl.gov.in
4	Project PI / Joint PI	Principal Investigator and Joint Principal Investigators of the project	Dr. B. Sutradhar bsutra@ndl.gov.in Prof. Saswat Chakrabarti will be added soon
5	Website/Portal (Helpdesk)	Queries regarding NDLI and its services	support@ndl.gov.in
6	Contents and Copyright Issues	Queries related to content curation and copyright issues	content@ndl.gov.in
7	National Digital Library of India Club (NDLI Club)	Queries related to NDLI Club formation, support, user awareness program, seminar/symposium, collaboration, social media, promotion, and outreach	clubsupport@ndl.gov.in
8	Digital Preservation Centre (DPC)	Assistance with digitizing and archiving copyright-free printed books	dpc@ndl.gov.in
9	IDR Setup or Support	Queries related to establishment and support of Institutional Digital Repository (IDR) and IDR workshops	idr@ndl.gov.in

[M3(μ3-O)(O2CR)6] and related trigonal prisms: versatile molecular building blocks for crystal engineering of metal–organic material platforms

Network diversity through decoration of trigonal-prismatic nodes: two-step crystal engineering of cationic metal-organic materials.

Theoretical Investigations of CO2 and CH4 Sorption in an Interpenetrated Diamondoid Metal–Organic Material

Synthesis of 2-azido-2-deoxy- and 2-acetamido-2-deoxy-D-manno derivatives as versatile building blocks

3-Chloro-2-aza-2-propeniminium Units as Versatile Building Blocks in Organic Synthesis

Assembly of [Cu2(COO)4] and [M3(μ3-O)(COO)6] (M = Sc, Fe, Ga, and In) building blocks into porous frameworks towards ultra-high C2H2/CO2 and C2H2/CH4 separation performance.

Transition Metal Centered Trigonal Prisms as Building Units in Various Rare Earth–Transition Metal-Indides

Design of supramolecular metal complexing polymers: synthesis, complexation, and polymerization of 5,5"-bisfunctionalized terpyridine building blocks

Rerefinement of poly[diaquabis(μ3-2-methylpropanoato-κ4O:O,O′:O′)bis(μ3-2-methylpropanoato-κ3O:O:O)(μ2-2-methylpropanoato-κ3O:O,O′)(2-methylpropanoato-κ2O,O′)trilead(II)]

[M₃(μ₃-O)(O₂CR)₆] and related trigonal prisms: versatile molecular building blocks for crystal engineering of metal–organic material platforms

Similar Documents

[M3(μ3-O)(O2CR)6] and related trigonal prisms: versatile molecular building blocks for crystal engineering of metal–organic material platforms

Network diversity through decoration of trigonal-prismatic nodes: two-step crystal engineering of cationic metal-organic materials.

Theoretical Investigations of CO2 and CH4 Sorption in an Interpenetrated Diamondoid Metal–Organic Material

Synthesis of 2-azido-2-deoxy- and 2-acetamido-2-deoxy-D-manno derivatives as versatile building blocks

3-Chloro-2-aza-2-propeniminium Units as Versatile Building Blocks in Organic Synthesis

Assembly of [Cu2(COO)4] and [M3(μ3-O)(COO)6] (M = Sc, Fe, Ga, and In) building blocks into porous frameworks towards ultra-high C2H2/CO2 and C2H2/CH4 separation performance.

Transition Metal Centered Trigonal Prisms as Building Units in Various Rare Earth–Transition Metal-Indides

Design of supramolecular metal complexing polymers: synthesis, complexation, and polymerization of 5,5"-bisfunctionalized terpyridine building blocks

Rerefinement of poly[diaquabis(μ3-2-methylpropanoato-κ4O:O,O′:O′)bis(μ3-2-methylpropanoato-κ3O:O:O)(μ2-2-methylpropanoato-κ3O:O,O′)(2-methylpropanoato-κ2O,O′)trilead(II)]

[M3(μ3-O)(O2CR)6] and related trigonal prisms: versatile molecular building blocks for crystal engineering of metal–organic material platforms

[M₃(μ₃-O)(O₂CR)₆] and related trigonal prisms: versatile molecular building blocks for crystal engineering of metal–organic material platforms