NDLI: Crystalline triphenylamine substituted arenes: solid state packing and luminescence properties

Please wait, while we are loading the content...

Novel 3-D interpenetrated metal–organometallic networks based on self-assembled Zn(ii)/Cu(ii) from 1,1′-ferrocenedicarboxylic acid and 4,4′-bipyridine

Chiral separation of dl-glutamic acid by ultrasonic field

Optical quality tetragonal phase single-crystal fiber of potassium di-hydrogen phosphate with efficient second-harmonic generation

Enhanced photoelectrochemical activity of nanostructured ZnFe₂O₄ thin films prepared by the electrospray technique

A view on systematic truncation of tetrahedral ligands for coordination polymers

Ligand-dependent assembly of dinuclear, linear tetranuclear and one-dimensional Zn(ii) complexes with an aroylhydrazone Schiff base

Doping marker layers for ex situ growth characterisation of HVPE gallium nitride

Role of substrate surface morphology on the epitaxial growth behavior of cerium oxide films prepared by chemical solution deposition

Reversible water uptake by a porous molecular crystal from metal complex of gemini surfactant

Crystal structure and magnetic properties of two manganese(ii) homometallic coordination polymers

Crystalline triphenylamine substituted arenes: solid state packing and luminescence properties

Crystal structure landscape of ethenzamide: a physicochemical property study

Syntheses, structural characterization and photophysical properties of two series of rare-earth-isonicotinic-acid containing Waugh-type manganomolybdates

Synthesis and investigations of In₂S₃:Ho³⁺ quantum dots on doping induced changes

An investigation of the effects of varying pH on protein crystallization screening

Improvement of bond strength between ZnO nanorods and carbon fibers using magnetron sputtered ZnO films as the interphase

Non-classical growth of water-redispersible spheroidal gold nanoparticles assisted by leonardite humate

Back cover

CrystEngComm Vol - 19 Issue - 4

CrystEngComm Vol - 19 Issue - 3

CrystEngComm Vol - 19 Issue - 2

Crystalline triphenylamine substituted arenes: solid state packing and luminescence properties

Content Provider	Royal Society of Chemistry (RSC)
Author	Niyas, M. A. Mallia, Ajith R. Ramakrishnan, Remya Hariharan, Mahesh
Copyright Year	2017
Abstract	The crystal packing and solid state photophysical properties of twisted propeller-shaped triphenylamine (T) incorporated aromatic hydrocarbons [ArT where Ar = benzene (Ph), naphthalene (N), anthracene (A), phenanthrene (Phe), pyrene (Py) and perylene (Pe)] are investigated. The qualitative crystal structure and quantum theory of atoms-in-molecules (QTAIM) analyses revealed the dominant role of intermolecular C–H⋯C interactions in governing the three-dimensional arrangement in ArT crystals. Hirshfeld surface analyses revealed that the triphenylamine-substituted arene (ArT) crystals possess a herringbone motif with ρ (%C–H⋯C/%C⋯C) values varying from 10.4 in PeT to 101.2 in AT. A blue shift of ca. 10–28 nm in the emission maxima for PhT, NT, AT, PheT and PyT is observed in the solid state in comparison to that in dichloromethane while the solid state emission maxima is red shifted (ca. 25–71 nm) compared to that in hexane. A 2.40-fold enhancement in the quantum yield of AT is observed in the solid state relative to the solution state (dichloromethane). Solvent polarity dependent absorption and emission measurements of ArT derivatives along with Lippert–Mataga analyses evidenced the presence of charge transfer interactions between Ar and T units. A precise and systematic understanding of the influence of the crystal structure on the photophysical properties is quintessential to achieve highly efficient organic light emitting diodes and other optoelectronic devices in the near future.
Starting Page	817
Ending Page	825
Page Count	9
File Format	HTM / HTML PDF
ISSN	14668033
Volume Number	19
Issue Number	5
Journal	CrystEngComm
DOI	10.1039/c6ce02321e
Language	English
Publisher	Royal Society of Chemistry
Access Restriction	Open
Subject Keyword	Anthracene Phenanthrene Optoelectronics Mataga Cyclone Phet Lippert Pyrene Quantum Naphthalene Blueshift Benzene Dichloromethane Hexane Hirshfeld Perylene Triphenylamine
Content Type	Text
Resource Type	Article
Subject	Chemistry Condensed Matter Physics Materials Science

Sl.	Authority	Responsibilities	Communication Details
1	Ministry of Education (GoI), Department of Higher Education	Sanctioning Authority	https://www.education.gov.in/ict-initiatives
2	Indian Institute of Technology Kharagpur	Host Institute of the Project: The host institute of the project is responsible for providing infrastructure support and hosting the project	https://www.iitkgp.ac.in
3	National Digital Library of India Office, Indian Institute of Technology Kharagpur	The administrative and infrastructural headquarters of the project	Dr. B. Sutradhar bsutra@ndl.gov.in
4	Project PI / Joint PI	Principal Investigator and Joint Principal Investigators of the project	Dr. B. Sutradhar bsutra@ndl.gov.in Prof. Saswat Chakrabarti will be added soon
5	Website/Portal (Helpdesk)	Queries regarding NDLI and its services	support@ndl.gov.in
6	Contents and Copyright Issues	Queries related to content curation and copyright issues	content@ndl.gov.in
7	National Digital Library of India Club (NDLI Club)	Queries related to NDLI Club formation, support, user awareness program, seminar/symposium, collaboration, social media, promotion, and outreach	clubsupport@ndl.gov.in
8	Digital Preservation Centre (DPC)	Assistance with digitizing and archiving copyright-free printed books	dpc@ndl.gov.in
9	IDR Setup or Support	Queries related to establishment and support of Institutional Digital Repository (IDR) and IDR workshops	idr@ndl.gov.in

Crystalline triphenylamine substituted arenes: solid state packing and luminescence properties

Highly Soluble Monoamino-Substituted Perylene Tetracarboxylic Dianhydrides: Synthesis, Optical and Electrochemical Properties

Photochemically-assisted synthesis and photophysical properties of difluoroboronated β-diketones with fused four-benzene-ring chromophores, chrysene and pyrene

1,6- and 1,7-Regioisomers of Highly Soluble Amino-Substituted Perylene Tetracarboxylic Dianhydrides: Synthesis, Optical and Electrochemical Properties

Determination of lead, naphthalene, phenanthrene, anthracene and pyrene in street dust

Determination of the absolute quantum efficiency of the luminescence of crystalline anthracene and of meso–dimeso derivatives using photoacoustic spectroscopy

Green Perylene Bisimide Dyes: Synthesis, Photophysical and Electrochemical Properties

The photosensitised oxidation of amines. Part IV. The use of aromatic hydrocarbons as sensitisers

Handed Mirror Symmetry Breaking at the Photo-Excited State of π-Conjugated Rotamers in Solutions

Crystalline triphenylamine substituted arenes: solid state packing and luminescence properties

Similar Documents

Crystalline triphenylamine substituted arenes: solid state packing and luminescence properties

Highly Soluble Monoamino-Substituted Perylene Tetracarboxylic Dianhydrides: Synthesis, Optical and Electrochemical Properties

Photochemically-assisted synthesis and photophysical properties of difluoroboronated β-diketones with fused four-benzene-ring chromophores, chrysene and pyrene

1,6- and 1,7-Regioisomers of Highly Soluble Amino-Substituted Perylene Tetracarboxylic Dianhydrides: Synthesis, Optical and Electrochemical Properties

Determination of lead, naphthalene, phenanthrene, anthracene and pyrene in street dust

Determination of the absolute quantum efficiency of the luminescence of crystalline anthracene and of meso–dimeso derivatives using photoacoustic spectroscopy

Green Perylene Bisimide Dyes: Synthesis, Photophysical and Electrochemical Properties

The photosensitised oxidation of amines. Part IV. The use of aromatic hydrocarbons as sensitisers

Handed Mirror Symmetry Breaking at the Photo-Excited State of π-Conjugated Rotamers in Solutions

Crystalline triphenylamine substituted arenes: solid state packing and luminescence properties