NDLI: Introducing 2-(2-carboxyphenoxy)terephthalic acid as a new versatile building block for design of diverse coordination polymers: synthesis, structural features, luminescence sensing, and magnetism

Please wait, while we are loading the content...

Supramolecular coordination assemblies of a symmetrical octamethyl-substituted cucurbituril with alkali metal ions based on the outer-surface interactions of cucurbit[n]urils

Fabrication of Cu₂MoS₄ hollow nanotubes with rGO sheets for enhanced visible light photocatalytic performance

Formation mechanism and morphology-dependent luminescence of NdF₃ nanoplates with cavities

Synthesis of the homochiral metal–organic framework DUT-129 based on a chiral dicarboxylate linker with 6 stereocenters

Four new zinc(ii) diphosphonates obtained via an ionothermal route: crystal structures and phase transformation behaviour

3D hierarchical macro/mesoporous TiO₂ with nanoporous or nanotubular structures and their core/shell composites achieved by anodization

Diiodomethane as a halogen bond donor toward metal-bound halides

Reorganized, weak C–H⋯O interactions directly modify the mechanical properties and compaction performance of a series of nitrobenzoic acids

Polymorphism, pseudo-polymorphism, and conformerism in the crystal structure of piperazine-N,N′-bis(N,O-diphenyl phosphoramidate)

Synthesis of zeolite-like metal–organic frameworks via a dual-ligand strategy

Czochralski growth and characterization of cerium doped calcium scandate

Syntheses, crystal structures and characterization of three alkaline metal borates

Introducing 2-(2-carboxyphenoxy)terephthalic acid as a new versatile building block for design of diverse coordination polymers: synthesis, structural features, luminescence sensing, and magnetism

Back cover

CrystEngComm Vol - 19 Issue - 9

CrystEngComm Vol - 19 Issue - 8

CrystEngComm Vol - 19 Issue - 7

CrystEngComm Vol - 19 Issue - 6

CrystEngComm Vol - 19 Issue - 5

CrystEngComm Vol - 19 Issue - 4

CrystEngComm Vol - 19 Issue - 3

CrystEngComm Vol - 19 Issue - 2

Introducing 2-(2-carboxyphenoxy)terephthalic acid as a new versatile building block for design of diverse coordination polymers: synthesis, structural features, luminescence sensing, and magnetism

Content Provider	Royal Society of Chemistry (RSC)
Author	Wu, Jiang Liang, Xiao-Xiao Cui, Yan-Hui Shi, Zi-Fa Kirillov, Alexander M. Gu, Jin-Zhong
Copyright Year	2017
Abstract	In this work, an ether-bridged aromatic carboxylic acid, 2-(2-carboxyphenoxy)terephthalic acid (H3cpta), was applied as an unexplored building block for the generation of a novel series of coordination compounds, which represent the first examples of structurally characterized products derived from H3cpta, thus opening up its use as a versatile building block in crystal engineering research. The obtained products were formulated as [Cd(μ-Hcpta)(phen)(H2O)]n (1), [Mn(μ-Hcpta)(phen)(H2O)]n (2), {[Cd3(μ3-Hcpta)(μ4-cpta)(μ-Cl)(H2O)4]·2H2O}n (3), {[Cd3(μ6-cpta)2(py)2]·5H2O}n (4), [Mn3(μ5-cpta)2(2,2′-bipy)2]n (5), [Mn3(μ4-cpta)2(phen)3(H2O)2]n (6), {[Zn3(μ3-cpta)2(phen)3]·3H2O} (7), [Cd2(μ4-cpta)(μ-Cl)(phen)2]n (8), [Cd3(μ5-cpta)2(phen)2(H2O)2]n (9), [Cd3(μ4-cpta)2(phen)3(H2O)2]n (10), [Cd3(μ5-cpta)2(H2biim)2]n (11), [Zn2(μ6-cpta)(μ-Hbiim)]n (12), and [Ni3(μ3-cpta)2(phen)3(py)3(H2O)3]n (13). These compounds were assembled in the presence of an optional N-donor ancillary ligand, which was selected from 1,10-phenanthroline (phen), pyridine (py), 2,2′-bipyridine (2,2′-bipy), or 2,2′-biimidazole (H2biim). The obtained compounds 1–13 were fully characterized, including by IR spectroscopy, elemental analysis, thermogravimetric analysis (TGA), powder (PXRD) and single-crystal X-ray diffraction. The structures of 1–13 vary from a discrete 0D dimer (1) to the 1D (2, 3, 7, and 13) and 2D (5, 6, and 8–11) coordination polymers, as well as to the 3D metal–organic frameworks (MOFs 4 and 12). Such a wide structural diversity of 1–13 is guided by the following factors: a type of metal(II) node and counter anion, a deprotonation degree of the principal H3cpta block, and/or a type of an auxiliary ligand. Topological classification of H-bonded (in 1) and metal–organic (in 2–13) underlying networks was performed, disclosing the following topological types: sql (in 1), 2C1 (in 2 and 7), 3,4,5L45 (in 5, 9, and 11), 3,4L128 (in 6 and 10), 3,3,4L29 (in 8), and SP 1-periodic net (in 13), as well as some topologically unique nets (in 3, 4, and 12). Besides, magnetic properties of 2, 5, 6, and 13 were studied and modeled, revealing antiferromagnetic interactions between adjacent metal(II) centers. In addition, luminescence properties were investigated for 1, 3, 4, and 7–12; MOF 4 can be used as a sensitive material for the detection of Fe3+ ions in aqueous solution through the luminescence quenching effect.
Starting Page	2570
Ending Page	2588
Page Count	19
File Format	HTM / HTML PDF
ISSN	14668033
Volume Number	19
Issue Number	18
Journal	CrystEngComm
DOI	10.1039/c7ce00219j
Language	English
Publisher	Royal Society of Chemistry
Access Restriction	Open
Subject Keyword	Water Antiferromagnetism Crystal engineering Infrared spectroscopy Acid Thermogravimetric analysis Ligand Luminescence Ion Protein dimer Three-dimensional space X-ray crystallography Pyridine Bipyridine Phenanthroline
Content Type	Text
Resource Type	Article
Subject	Chemistry Condensed Matter Physics Materials Science

Sl.	Authority	Responsibilities	Communication Details
1	Ministry of Education (GoI), Department of Higher Education	Sanctioning Authority	https://www.education.gov.in/ict-initiatives
2	Indian Institute of Technology Kharagpur	Host Institute of the Project: The host institute of the project is responsible for providing infrastructure support and hosting the project	https://www.iitkgp.ac.in
3	National Digital Library of India Office, Indian Institute of Technology Kharagpur	The administrative and infrastructural headquarters of the project	Dr. B. Sutradhar bsutra@ndl.gov.in
4	Project PI / Joint PI	Principal Investigator and Joint Principal Investigators of the project	Dr. B. Sutradhar bsutra@ndl.gov.in Prof. Saswat Chakrabarti will be added soon
5	Website/Portal (Helpdesk)	Queries regarding NDLI and its services	support@ndl.gov.in
6	Contents and Copyright Issues	Queries related to content curation and copyright issues	content@ndl.gov.in
7	National Digital Library of India Club (NDLI Club)	Queries related to NDLI Club formation, support, user awareness program, seminar/symposium, collaboration, social media, promotion, and outreach	clubsupport@ndl.gov.in
8	Digital Preservation Centre (DPC)	Assistance with digitizing and archiving copyright-free printed books	dpc@ndl.gov.in
9	IDR Setup or Support	Queries related to establishment and support of Institutional Digital Repository (IDR) and IDR workshops	idr@ndl.gov.in

Introducing 2-(2-carboxyphenoxy)terephthalic acid as a new versatile building block for design of diverse coordination polymers: synthesis, structural features, luminescence sensing, and magnetism

Two coordination polymers constructed by 5-[(4-carboxyphenoxy)methyl]benzene-1,3-dicarboxylic acid and 2,2'-bipyridine: syntheses, structures and luminescence properties.

Synthesis, Crystal Structure, Luminescence and Magnetism of Three Novel Coordination Polymers Based on Flexible Multicarboxylate Zwitterionic Ligand

Crystal Structure, Synthesis and Luminescence Sensing of a Zn(II) Coordination Polymer with 2,5-Dihydroxy-1,4-Terephthalic Acid and 2,2′-Bipyridine as Ligands

Synthesis, Crystal Structure, and Luminescent Properties of a New Holmium(III) Coordination Polymer Involving 2,5-Dihydroxy-1,4-terephthalic Acid Dianion as Ligand

Structural and Luminescent Properties of Heterobimetallic Zinc(II)-Europium(III) Dimer Constructed from N2O2-Type Bisoxime and Terephthalic Acid

New Topologically Unique Metal-Organic Architectures Driven by a Pyridine-Tricarboxylate Building Block

Syntheses, characterization, and magnetic properties of novel divalent Co/Ni coordination polymers based on a V-shaped pyridine ligand and dicarboxylate acids

Two uranyl heterocyclic carboxyl compounds with fluorescent properties as high sensitivity and selectivity optical detectors for nitroaromatics

Introducing 2-(2-carboxyphenoxy)terephthalic acid as a new versatile building block for design of diverse coordination polymers: synthesis, structural features, luminescence sensing, and magnetism

Similar Documents

Introducing 2-(2-carboxyphenoxy)terephthalic acid as a new versatile building block for design of diverse coordination polymers: synthesis, structural features, luminescence sensing, and magnetism

Two coordination polymers constructed by 5-[(4-carboxyphenoxy)methyl]benzene-1,3-dicarboxylic acid and 2,2'-bipyridine: syntheses, structures and luminescence properties.

Synthesis, Crystal Structure, Luminescence and Magnetism of Three Novel Coordination Polymers Based on Flexible Multicarboxylate Zwitterionic Ligand

Crystal Structure, Synthesis and Luminescence Sensing of a Zn(II) Coordination Polymer with 2,5-Dihydroxy-1,4-Terephthalic Acid and 2,2′-Bipyridine as Ligands

Synthesis, Crystal Structure, and Luminescent Properties of a New Holmium(III) Coordination Polymer Involving 2,5-Dihydroxy-1,4-terephthalic Acid Dianion as Ligand

Structural and Luminescent Properties of Heterobimetallic Zinc(II)-Europium(III) Dimer Constructed from N2O2-Type Bisoxime and Terephthalic Acid

New Topologically Unique Metal-Organic Architectures Driven by a Pyridine-Tricarboxylate Building Block

Syntheses, characterization, and magnetic properties of novel divalent Co/Ni coordination polymers based on a V-shaped pyridine ligand and dicarboxylate acids

Two uranyl heterocyclic carboxyl compounds with fluorescent properties as high sensitivity and selectivity optical detectors for nitroaromatics

Introducing 2-(2-carboxyphenoxy)terephthalic acid as a new versatile building block for design of diverse coordination polymers: synthesis, structural features, luminescence sensing, and magnetism