NDLI: Two coordination polymers constructed by 5-[(4-carboxyphenoxy)methyl]benzene-1,3-dicarboxylic acid and 2,2'-bipyridine: syntheses, structures and luminescence properties.

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Two coordination polymers constructed by 5-[(4-carboxyphenoxy)methyl]benzene-1,3-dicarboxylic acid and 2,2'-bipyridine: syntheses, structures and luminescence properties.

Content Provider	Semantic Scholar
Author	He, Yuan Xiao, Li Yuan Yuan, Zi Han Zhang, Jie Wang, Yan
Copyright Year	2019
Abstract	Coordination polymers (CPs) have attracted increasing interest in recent years. In this work, two new CPs, namely poly[[aquabis(2,2'-bipyridine-κ2N,N'){μ3-5-[(4-carboxylatophenoxy)methyl]benzene-1,3-dicarboxylato-κ4O1,O1':O3:O5}(μ-formato-κ3O:O,O')dicadmium(II)] monohydrate], {[Cd2(C16H9O7)(HCO2)(C10H8N2)2(H2O)]·H2O}n (1), and poly[[(2,2'-bipyridine-κ2N,N'){μ3-5-[(4-carboxylphenoxy)methyl]benzene-1,3-dicarboxylato-κ4O1,O1':O3:O5}manganese(II)] sesquihydrate], {[Mn(C16H10O7)(C10H8N2)]·1.5H2O}n (2), have been prepared using the tricarboxylic acid 5-[(4-carboxyphenoxy)methyl]benzene-1,3-dicarboxylic acid and 2,2'-bipyridine under hydrothermal conditions. CP 1 displays a two-dimensional layer structure which is further extended into a three-dimensional (3D) supramolecular structure via intermolecular π-π interactions, while CP 2 shows a different 3D supramolecular structure extended from one-dimensional ladder chains by intermolecular π-π interactions. In addition, the solid-state luminescence spectra of 1 and 2 were studied at room temperature.
Starting Page	1562
Ending Page	1568
Page Count	7
File Format	PDF HTM / HTML
DOI	10.1107/s2053229619014633
PubMed reference number	31802745
Journal	Medline
Volume Number	75
Part	12
Alternate Webpage(s)	http://journals.iucr.org/c/issues/2019/12/00/qf3036/qf3036.pdf
Alternate Webpage(s)	https://doi.org/10.1107/s2053229619014633
Journal	Acta crystallographica. Section C, Structural chemistry
Language	English
Access Restriction	Open
Content Type	Text
Resource Type	Article

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