NDLI: Preparation of a molecularly imprinted fluorescent chemosensor using quinoline modified vinyl-β-cyclodextrin and acrylamide as monomers for the selective recognition of spermidine

Content Provider	Royal Society of Chemistry (RSC)
Author	Dong, Xiangchao Cheng, Yang
Copyright Year	2016
Abstract	A new molecularly imprinted fluorescent chemosensor with selectivity for spermidine has been developed using quinoline modified vinyl-β-cyclodextrin as a reporter and major functional monomer. Acrylamide that provided synergetic monomer/template interactions was also used in the imprinting. The imprinted receptor of the chemosensor was created by the inclusion and hydrogen-bonding interactions between functional monomers and spermidine. The chemosensor has shown higher sensitivity and imprinting performance than that synthesized using only β-cyclodextrin. The imprinting factor of the imprinted membrane for spermidine is 3.87. This suggests that the imprinted chemosensor has good imprinted binding affinity. The selectivity (α), evaluated by the ratio of sensitivity for spermidine to that for its analogs, was ≧2.0, indicating the suitable recognition properties of the chemosensor. The fluorescence of the imprinted membrane exhibited a “Turn-on” response mode. A linear relationship between the negative logarithm of spermidine concentration and the fluorescence intensity of the chemosensor at Cspermidine of 5 × 10−7 to 1 × 10−4 mol L−1 has been obtained. The results demonstrated that the use of vinyl-β-cyclodextrin and radical polymerization for this chemosensor preparation has obvious advantages. The imprinted fluorescent chemosensor has application potential for spermidine determination in complex samples.
Starting Page	5838
Ending Page	5842
Page Count	5
File Format	HTM / HTML PDF
ISSN	17599660
Volume Number	8
Issue Number	29
Journal	Analytical Methods
DOI	10.1039/c6ay00984k
Language	English
Publisher	Royal Society of Chemistry
Access Restriction	Open
Subject Keyword	Acrylamide Reporter gene Spermidine Logarithm Mol L Radical polymerization Quinoline Fluorescence Monomer Chemoreceptor
Content Type	Text
Resource Type	Article
Subject	Analytical Chemistry Engineering Chemical Engineering

Sl.	Authority	Responsibilities	Communication Details
1	Ministry of Education (GoI), Department of Higher Education	Sanctioning Authority	https://www.education.gov.in/ict-initiatives
2	Indian Institute of Technology Kharagpur	Host Institute of the Project: The host institute of the project is responsible for providing infrastructure support and hosting the project	https://www.iitkgp.ac.in
3	National Digital Library of India Office, Indian Institute of Technology Kharagpur	The administrative and infrastructural headquarters of the project	Dr. B. Sutradhar bsutra@ndl.gov.in
4	Project PI / Joint PI	Principal Investigator and Joint Principal Investigators of the project	Dr. B. Sutradhar bsutra@ndl.gov.in Prof. Saswat Chakrabarti will be added soon
5	Website/Portal (Helpdesk)	Queries regarding NDLI and its services	support@ndl.gov.in
6	Contents and Copyright Issues	Queries related to content curation and copyright issues	content@ndl.gov.in
7	National Digital Library of India Club (NDLI Club)	Queries related to NDLI Club formation, support, user awareness program, seminar/symposium, collaboration, social media, promotion, and outreach	clubsupport@ndl.gov.in
8	Digital Preservation Centre (DPC)	Assistance with digitizing and archiving copyright-free printed books	dpc@ndl.gov.in
9	IDR Setup or Support	Queries related to establishment and support of Institutional Digital Repository (IDR) and IDR workshops	idr@ndl.gov.in

Molecularly imprinted fluorescent chemosensor synthesized using quinoline-modified-β-cyclodextrin as monomer for spermidine recognition

Novel surface modified molecularly imprinted polymer using acryloyl-beta-cyclodextrin and acrylamide as monomers for selective recognition of lysozyme in aqueous solution.

Protein imprinted polymer using acryloyl-β-cyclodextrin and acrylamide as monomers

novel fluorescent multi-functional monomer for preparation of ilver ion-imprinted fluorescent on – off chemosensor

Preparation and evaluation of vanillin molecularly imprinted polymer microspheres by reversible addition–fragmentation chain transfer precipitation polymerization

Fluorescent Sensing of Chlorophenols in Water Using an Azo Dye Modified β-Cyclodextrin Polymer

A Hg²⁺ selective fluorescent chemosensor based on rhodamine B thiohydrazide and its application in bioimaging

Effects of RAFT Agent on the Selective Approach of Molecularly Imprinted Polymers

Synergetic Effect of Dual Functional Monomers in Molecularly Imprinted Polymer Preparation for Selective Solid Phase Extraction of Ciprofloxacin

Preparation of a molecularly imprinted fluorescent chemosensor using quinoline modified vinyl-β-cyclodextrin and acrylamide as monomers for the selective recognition of spermidine

Similar Documents

Molecularly imprinted fluorescent chemosensor synthesized using quinoline-modified-β-cyclodextrin as monomer for spermidine recognition

Novel surface modified molecularly imprinted polymer using acryloyl-beta-cyclodextrin and acrylamide as monomers for selective recognition of lysozyme in aqueous solution.

Protein imprinted polymer using acryloyl-β-cyclodextrin and acrylamide as monomers

novel fluorescent multi-functional monomer for preparation of ilver ion-imprinted fluorescent on – off chemosensor

Preparation and evaluation of vanillin molecularly imprinted polymer microspheres by reversible addition–fragmentation chain transfer precipitation polymerization

Fluorescent Sensing of Chlorophenols in Water Using an Azo Dye Modified β-Cyclodextrin Polymer

A Hg2+ selective fluorescent chemosensor based on rhodamine B thiohydrazide and its application in bioimaging

Effects of RAFT Agent on the Selective Approach of Molecularly Imprinted Polymers

Synergetic Effect of Dual Functional Monomers in Molecularly Imprinted Polymer Preparation for Selective Solid Phase Extraction of Ciprofloxacin

Preparation of a molecularly imprinted fluorescent chemosensor using quinoline modified vinyl-β-cyclodextrin and acrylamide as monomers for the selective recognition of spermidine

A Hg²⁺ selective fluorescent chemosensor based on rhodamine B thiohydrazide and its application in bioimaging