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| Content Provider | Royal Society of Chemistry (RSC) |
|---|---|
| Author | Kirkpatrick, Douglas C. Martin, R. Scott Antwi, Christiana |
| Copyright Year | 2010 |
| Abstract | This work demonstrates that recordable compact discs (CDs) that contain gold as a reflective layer can be used as an electrode substrate for microchip-based analysis systems. A fabrication procedure that enables the reproducible patterning of multiple electrodes has been developed. It is shown that the microelectrodes can be integrated within a PDMS-based fluidic network and used for amperometric detection of electroactive analytes at both single and dual microelectrodes. A detailed comparison is made between the CD-based patterned electrodes and electrodes made by the traditional method of sputtering gold and titanium adhesion layers onto a glass substrate. It is also shown that mercury can be electrodeposited onto a CD-based microelectrode and the amalgam electrode used to selectively detect thiols. Finally, it is demonstrated that a decoupler for microchip-based electrophoresis can be made by electrodepositing palladium onto a gold electrode and a separate downstream gold working electrode can be used for amperometric detection. These CD-based patterned electrodes are attractive alternatives for situations where device cost is of a concern or sputtering facilities are unavailable. |
| Starting Page | 811 |
| Ending Page | 816 |
| Page Count | 6 |
| File Format | HTM / HTML PDF |
| ISSN | 17599660 |
| Volume Number | 2 |
| Issue Number | 7 |
| Journal | Analytical Methods |
| DOI | 10.1039/c0ay00294a |
| Language | English |
| Publisher | Royal Society of Chemistry |
| Access Restriction | Open |
| Subject Keyword | Electrode Titanium Mercury-vapor lamp Electrophoresis Electroplating Working electrode Sputtering |
| Content Type | Text |
| Resource Type | Article |
| Subject | Analytical Chemistry Engineering Chemical Engineering |
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