NDLI: Microwave assisted extraction of Cr(iii) and Cr(vi) from soil/sediments combined with ion exchange separation and inductively coupled plasma optical emission spectrometry detection

Content Provider	Royal Society of Chemistry (RSC)
Author	Swamy, A. V. N. Sahayam, A. C. Venkateswarlu, G. Mamatha, P.
Copyright Year	2014
Abstract	An analytical methodology has been developed for the speciation of Cr(III) and Cr(VI) in soil/sediments. The species of interest were extracted from samples using a solution containing 0.1 M EDTA, 1% tetrabutyl ammonium bromide (TBAB) and a little HF in a domestic microwave oven. The conditions for the quantitative extraction of the Cr species from sediments were optimized. The separation of anionic Cr(VI) from the sediment extract was carried out using the sulfate form of Dowex-1 at pH 4.5. Though the extract contained the anionic EDTA complex of Cr(III), it was quantitatively eluted. The adsorbed Cr(VI) was eluted with 2 M HNO3. The determination of the separated Cr(VI) and Cr(III) in the effluent, and total Cr in the extract was carried out using ICP-OES. The recovery of the total Cr from the original samples was 96–99% and that of Cr(III) and Cr(VI) spiked was 97–102% with an RSD in the range of 5–6%. A developed methodology has been applied for the speciation of Cr in a certified reference material stream sediment (GBW-07312) and also four real world samples: two sediments collected from the Hussain Sagar lake, Hyderabad, India and two soils collected near the Uranium Corporation of India Limited (UCIL), Tummalapalli, Kadapa, India. The total concentration of Cr in the extract was in good agreement with the certified value of the stream sediment and with the complete dissolution method in case of the real world samples. The limit of detection of Cr(VI) was 0.02 mg L−1, which corresponding to a detection limit of 5.0 mg kg−1 for this method.
Starting Page	9653
Ending Page	9657
Page Count	5
File Format	HTM / HTML PDF
ISSN	17599660
Volume Number	6
Issue Number	24
Journal	Analytical Methods
DOI	10.1039/c4ay01914h
Language	English
Publisher	Royal Society of Chemistry
Access Restriction	Open
Subject Keyword	Ammonium Sediment Kadapa TBAB Inductively coupled plasma atomic emission spectroscopy Certified reference materials Tummalapalli Hyderabad Nitric acid India Bromide Ethylenediaminetetraacetic acid Microwave oven Hussain Sagar Hydrofluoric acid PH Sulfate Uranium Corporation of India Limited Speciation
Content Type	Text
Resource Type	Article
Subject	Analytical Chemistry Engineering Chemical Engineering

Sl.	Authority	Responsibilities	Communication Details
1	Ministry of Education (GoI), Department of Higher Education	Sanctioning Authority	https://www.education.gov.in/ict-initiatives
2	Indian Institute of Technology Kharagpur	Host Institute of the Project: The host institute of the project is responsible for providing infrastructure support and hosting the project	https://www.iitkgp.ac.in
3	National Digital Library of India Office, Indian Institute of Technology Kharagpur	The administrative and infrastructural headquarters of the project	Dr. B. Sutradhar bsutra@ndl.gov.in
4	Project PI / Joint PI	Principal Investigator and Joint Principal Investigators of the project	Dr. B. Sutradhar bsutra@ndl.gov.in Prof. Saswat Chakrabarti will be added soon
5	Website/Portal (Helpdesk)	Queries regarding NDLI and its services	support@ndl.gov.in
6	Contents and Copyright Issues	Queries related to content curation and copyright issues	content@ndl.gov.in
7	National Digital Library of India Club (NDLI Club)	Queries related to NDLI Club formation, support, user awareness program, seminar/symposium, collaboration, social media, promotion, and outreach	clubsupport@ndl.gov.in
8	Digital Preservation Centre (DPC)	Assistance with digitizing and archiving copyright-free printed books	dpc@ndl.gov.in
9	IDR Setup or Support	Queries related to establishment and support of Institutional Digital Repository (IDR) and IDR workshops	idr@ndl.gov.in

Dispersive liquid–liquid micro extraction of uranium(vi) from groundwater and seawater samples and determination by inductively coupled plasma–optical emission spectrometry and flow injection–inductively coupled plasma mass spectrometry

Boron speciation in acid digests of metallurgical grade silicon reveals problem for accurate boron quantification by inductively coupled plasma – optical emission spectroscopy

Speciation of Cr (III) and Cr (VI) via Reversed Phase HPLC with Inductively Coupled Plasma Emission Spectroscopic Detection (HPLC-ICP)24

Simultaneous speciation and determination of arsenic, chromium and cadmium in water samples by high performance liquid chromatography with inductively coupled plasma mass spectrometry

Interfacing a microfluidic electrophoresis chip with inductively coupled plasma mass spectrometry for rapid elemental speciation

Oxidative pyrolysis combined with the microwave-assisted extraction method for the multi-elemental analysis of boron carbide powders by inductively coupled plasma optical emission spectrometry (ICP-OES)

Analysis of glass in product tampering investigations by inductively coupled plasma atomic emission spectrometry with a hydrofluoric acid resistant torch

Synthesis of Cross-Linked Chitosan and Application to Adsorption and Speciation of Se (VI) and Se (IV) in Environmental Water Samples by Inductively Coupled Plasma Optical Emission Spectrometry

Determination of minor and trace elements in ferrochromium and ferromanganese by inductively coupled plasma atomic emission spectrometry

Microwave assisted extraction of Cr(iii) and Cr(vi) from soil/sediments combined with ion exchange separation and inductively coupled plasma optical emission spectrometry detection

Similar Documents

Dispersive liquid–liquid micro extraction of uranium(vi) from groundwater and seawater samples and determination by inductively coupled plasma–optical emission spectrometry and flow injection–inductively coupled plasma mass spectrometry

Boron speciation in acid digests of metallurgical grade silicon reveals problem for accurate boron quantification by inductively coupled plasma – optical emission spectroscopy

Speciation of Cr (III) and Cr (VI) via Reversed Phase HPLC with Inductively Coupled Plasma Emission Spectroscopic Detection (HPLC-ICP)24

Simultaneous speciation and determination of arsenic, chromium and cadmium in water samples by high performance liquid chromatography with inductively coupled plasma mass spectrometry

Interfacing a microfluidic electrophoresis chip with inductively coupled plasma mass spectrometry for rapid elemental speciation

Oxidative pyrolysis combined with the microwave-assisted extraction method for the multi-elemental analysis of boron carbide powders by inductively coupled plasma optical emission spectrometry (ICP-OES)

Analysis of glass in product tampering investigations by inductively coupled plasma atomic emission spectrometry with a hydrofluoric acid resistant torch

Synthesis of Cross-Linked Chitosan and Application to Adsorption and Speciation of Se (VI) and Se (IV) in Environmental Water Samples by Inductively Coupled Plasma Optical Emission Spectrometry

Determination of minor and trace elements in ferrochromium and ferromanganese by inductively coupled plasma atomic emission spectrometry

Microwave assisted extraction of Cr(iii) and Cr(vi) from soil/sediments combined with ion exchange separation and inductively coupled plasma optical emission spectrometry detection