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Oxo-carboxylato-molybdenum(VI) complexes possessing dithiolene ligand related to the active site of type II class of DMSOR family of molybdoenzymes
| Content Provider | PubMed Central |
|---|---|
| Author | Sugimoto, Hideki Sato, Masanori Giles, Logan J. Asano, Kaori Suzuki, Takeyuki Kirk, Martin L. Itoh, Shinobu |
| Abstract | Spectroscopic and kinetic studies indicate that oxo-carboxylato-molybdenum(VI) bis-dithiolene complexes, (MoVIO(p-X-OBz)L2), have been generated at low temperature as active site structural models for the type II class of pyranopterin molybdenum DMSOR family enzymes. A DFT analysis of low energy charge transfer bands shows that these complexes possess a Mo-Sdithiolene π bonding interaction between the Mo(dxy) redox active molecular orbital and a cis S(pz) donor orbital located on one of the dithiolene ligands. |
| Related Links | http://dx.doi.org/10.1039/c3dt51485d |
| File Format | |
| ISSN | 14779234 |
| e-ISSN | 14779234 |
| Journal | Dalton transactions (Cambridge, England : 2003) |
| Issue Number | 45 |
| Volume Number | 42 |
| Language | English |
| Publisher Date | 2013-12-07 |
| Access Restriction | Open |
| Subject Keyword | Research in Higher Education |
| Content Type | Text |
| Resource Type | Article |
| Subject | Inorganic Chemistry |