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Oxo-carboxylato-molybdenum(VI) complexes possessing dithiolene ligands related to the active site of type II DMSOR family molybdoenzymes.
| Content Provider | Semantic Scholar |
|---|---|
| Author | Sugimoto, Hideki Sato, Masanori Giles, Logan J. Asano, Kaori Suzuki, Takeyuki Kirk, Martin L. Itoh, Shinobu |
| Copyright Year | 2013 |
| Abstract | Spectroscopic and kinetic studies indicate that oxo-carboxylato-molybdenum(VI) bis-dithiolene complexes, (Mo(VI)O(p-X-OBz)L2), have been generated at low temperature as active site structural models for the type II class of pyranopterin molybdenum DMSOR family enzymes. A DFT analysis of low energy charge transfer bands shows that these complexes possess a Mo-S(dithiolene) π-bonding interaction between the Mo(d(xy)) redox active molecular orbital and a cis S(p(z)) donor orbital located on one of the dithiolene ligands. |
| File Format | PDF HTM / HTML |
| DOI | 10.1039/c3dt51485d |
| PubMed reference number | 24029827 |
| Journal | Medline |
| Volume Number | 42 |
| Issue Number | 45 |
| Alternate Webpage(s) | http://pubs.rsc.org/en/content/articlepdf/2013/dt/c3dt51485d |
| Alternate Webpage(s) | https://pubs.rsc.org/en/content/articlepdf/2013/dt/c3dt51485d?page=search |
| Alternate Webpage(s) | https://pubs.rsc.org/en/content/articlepdf/2013/dt/c3dt51485d |
| Alternate Webpage(s) | https://doi.org/10.1039/c3dt51485d |
| Journal | Dalton transactions |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |
