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| Content Provider | PubMed Central |
|---|---|
| Author | Daniela, Schönauer-kamin Fleischer, Maximilian Moos, Ralf |
| Copyright Year | 2013 |
| Abstract | Half-cell potentials of the electrochemical cell Au, VWT | YSZ | Au are analyzed in dependence on oxygen and ammonia concentration at 550 °C. One of the gold electrodes is covered with a porous SCR catalyst, vanadia-tungstenia-titania (VWT). The cell is utilized as a potentiometric ammonia gas sensor and provides a semi-logarithmic characteristic curve with a high NH3 sensitivity and selectivity. The analyses of the Au | YSZ and Au, VWT | YSZ half-cells are conducted to describe the non-equilibrium behavior of the sensor device in light of mixed potential theory. Both electrode potentials provide a dependency on the NH3 concentration, whereby VWT, Au | YSZ shows a stronger effect which increases with increasing VWT coverage. The potential shifts in the anodic direction confirm the formation of mixed potentials at both electrodes resulting from electrochemical reactions of O2 and NH3 at the three-phase boundary. Polarization curves indicate Butler-Volmer-type kinetics. Modified polarization curves of the VWT covered electrode show an enhanced anodic reaction and an almost unaltered cathodic reaction. The NH3 dependency is dominated by the VWT coverage and it turns out that the catalytic properties of the VWT thick film are responsible for the electrode potential shift. |
| Related Links | http://dx.doi.org/10.3390/s130404760 |
| Ending Page | 4780 |
| Page Count | 21 |
| Starting Page | 4760 |
| File Format | |
| ISSN | 14248220 |
| e-ISSN | 14248220 |
| Journal | Sensors (Basel, Switzerland) |
| Issue Number | 4 |
| Volume Number | 13 |
| Language | English |
| Publisher | Molecular Diversity Preservation International (MDPI) |
| Publisher Date | 2013-04-01 |
| Access Restriction | Open |
| Rights Holder | Molecular Diversity Preservation International (MDPI) |
| Subject Keyword | Electrical and Electronic Engineering Analytical Chemistry Atomic and Molecular Physics, and Optics Biochemistry Research in Higher Education |
| Content Type | Text |
| Resource Type | Article |
| Subject | Medicine Atomic and Molecular Physics, and Optics Instrumentation Analytical Chemistry Biochemistry Information Systems Electrical and Electronic Engineering |
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