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Copper-Catalyzed Diastereo- and Enantioselective Borylative Cyclization
| Content Provider | MDPI |
|---|---|
| Author | Manna, Srimanta |
| Copyright Year | 2022 |
| Description | Copper-catalyzed enantioselective borylative cyclization with various electrophiles via difunctionalization of unsaturated hydrocarbons is a powerful tool for the generation of interesting boron-containing carbocycles and heterocycles processes involving a chiral organocopper intermediate. Alkenes, allenes, and alkynes are versatile and easily accessible substrates that can be subjected to a wide range of reactions to produce densely functionalized, enantioenriched products. In this chapter, I discuss copper-catalyzed alkenes, allenes, and alkynes borofunctionalization and enantioselective cyclization via chiral organocopper intermediate. Copper-catalyzed enantioselective borylative cyclization and regiodivergent functionalization of alkenes, allenes, and alkynes, as well as the current mechanistic understanding of such processes, are given special attention in this review. |
| Starting Page | 734 |
| e-ISSN | 20734344 |
| DOI | 10.3390/catal12070734 |
| Journal | Catalysts |
| Issue Number | 7 |
| Volume Number | 12 |
| Language | English |
| Publisher | MDPI |
| Publisher Date | 2022-07-02 |
| Access Restriction | Open |
| Subject Keyword | Catalysts Copper Catalysis Enantioselective Borylation Cyclization |
| Content Type | Text |
| Resource Type | Article |
