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Organometallics Of Diphosphazanes. Part 10. Dinuclear Group 6 Metal Carbonyl Complexes Bridged By A Cyclodiphosphazane In Its Cis Or Trans Form
| Content Provider | Indian Institute of Science (IISc) |
|---|---|
| Author | Reddy, Venkata S. Krishnamurthy, Setharampattu S. Nethaji, Munirathinam |
| Copyright Year | 1994 |
| Abstract | Mononuclear Group 6 metal tetracarbonyl complexes containing a cyclodiphosphazane ligand, [PhNP(OC(6)H(4)Me-p)](2) (L), have been used as synthons to prepare homo- and hetero-bimetallic complexes in which the cyclodiphosphazane bridges the two metal centres in its cis or trans isomeric forms. The dimolybdenum complex [Mo-2(eta(5)-C5H5)(2)(CO)(4)(mu-L)] has also been synthesized. The trends in P-31 NMR chemical shifts and the structural features as revealed by X-ray crystallography are discussed. |
| File Format | |
| Journal | PeerReviewed |
| Language | English |
| Publisher | Royal society of chemistry |
| Publisher Date | 1994-09-21 |
| Access Restriction | Authorized |
| Subject Keyword | Inorganic & Physical Chemistry |
| Content Type | Text |
| Resource Type | Article |