Studies Of Phosphazenes. Part 34. Group 6 Metal Carbonyl Complexes Of Bis(pyrazolyl)cyclotriphosphazenes

Content Provider	Indian Institute of Science (IISc)
Author	Chandrasekaran, Annamalai Krishnamurthy, Setharampattu S. Nethaj, Munirathinam
Copyright Year	1994
Abstract	Reactions of the bis(3,5-dimethylpyrazol-1-yl)cyclotriphosphazenes gem-N3P3Ph4(C3HN2Me2)2 (L1) and N3P3(MeNCH2CH2O)2(C3HN2Me2)2 (L2) with [M(CO)6] (M = Mo or W) afford complexes of the type [M(CO)3L] (L = L1 or L2), which have been characterised by IR and NMR spectroscopic data. The structures of [Mo(CO)3L1], [W(CO)3L2] and the ligand L2 have been determined by single-crystal X-ray diffraction. The phosphazenes act as novel tridentate NNN-donor ligands with two pyrazolyl nitrogen atoms and one phosphazene ring nitrogen atom bonded to the metal atom
File Format	PDF
Journal	PeerReviewed
Language	English
Publisher	Royal society of chemistry
Publisher Date	1994-01-07
Access Restriction	Authorized
Subject Keyword	Inorganic & Physical Chemistry
Content Type	Text
Resource Type	Article