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| Content Provider | IET Digital Library |
|---|---|
| Author | Feng, Guangwei Feng, Jian |
| Abstract | Low toxic, non-stoichiometric colloidal copper–indium–sulphur [Cu–In–S (CIS)] ternary quantum dots with different Cu:In molar ratios by a hot-injection method in octadecene was synthesised. The Cu:In precursor molar ratios were 1/10, 1/20 and 1/40. Varying the fraction of cationic and capping agents, the compositions of CIS nanocrystals were precisely controlled. The photoluminescence (PL) results reveal that, reducing the Cu:In ratio in the CIS is the feasible strategy for bandgap engineering. Tunable PL emissions have been observed. X-ray powder diffraction and high-resolution transmission electron microscopy results indicate that as-prepared CIS nanocrystals are compositional homogeneity. The single-crystal nature of CIS nanocrystals improves the relative PL quantum yield up to 12%, which exhibits substantial enhancement comparing with the stoichiometric CuInS2 and CIS-based semiconductor core QDs. The PL decay curve of CIS has a triexponential feature. The value of τ1, τ2 and τ3 of CIS sample agree well with CuInS2 core QDs. The average PL lifetime of CIS is reduced to 146.9 ns, which can be attributed to the reduction of surface-related trap states. |
| Starting Page | 550 |
| Ending Page | 553 |
| Page Count | 4 |
| Volume Number | 11 |
| e-ISSN | 17500443 |
| Issue Number | Issue 9, Sep (2016) |
| Alternate Webpage(s) | https://digital-library.theiet.org/content/journals/mnl/11/9 |
| Alternate Webpage(s) | https://digital-library.theiet.org/content/journals/10.1049/mnl.2016.0211 |
| Journal | Micro & Nano Letters |
| Publisher Date | 2016-09-01 |
| Access Restriction | Open |
| Rights Holder | © The Institution of Engineering and Technology |
| Subject Keyword | Average Photoluminescence Lifetime Bandgap Engineering Capping Agent Cationic Agent Colloidal Crystals Colloids Compositional Homogeneity Copper Compounds Cu-In Precursor Molar Ratios CuInS2 Energy Gap High-resolution Transmission Electron Microscopy Hot-injection Method HRTEM Indium Compound Inorganic SemiConductor And Insulator Low Toxic Nonstoichiometric Colloidal Copper-indium-sulphur Ternary Quantum Dots Low-Dimensional Structure: Growth, Structure And Nonelectronic Property Nanofabrication Nanometre-Scale Semiconductor Fabrication Technology NanoParticle Nanostructured Material Nanotube And Nanostructured Material Octadecene Optical Property Photoluminescence Photoluminescence Decay Curve Photoluminescence in Other Inorganic Material Quantum Wells And Related Structure Radiative Lifetimes Relative Photoluminescence Quantum Yield Semiconductor Growth Semiconductor Material Semiconductor Quantum Dots Semiconductor Superlattices Single-crystal Nature Stoichiometry Structure of Solid Clusters Surface-related Trap State Ternary Nonstoichiometric Cu-In-S Nanocrystal Emitters Ternary SemiConductor Time 146.9 Ns Transmission Electron Microscopy Tunable Optical Property Tunable Photoluminescence Emission X-Ray Diffraction X-Ray Powder Diffraction XRD |
| Content Type | Text |
| Resource Type | Article |
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