NDLI: A comparison of heat outputs attributed to lithium film formation and repair in Li/SOCl/sub 2/ and Li/MnO/sub 2/ cells

Content Provider	IEEE Xplore Digital Library
Author	Kronenberg, M.L. Baker, J.W. Rissmiller, P. Bytella, J.
Copyright Year	1992
Description	Author affiliation: Catalyst Res., Sparks, MD, USA (Kronenberg, M.L.)
Abstract	Heat output measurements were taken following partial discharges or short circuit tests on Li/SOCl/sub 2/ and on Li/MnO/sub 2/ cells. The magnitude and change in heat output with time is contrasted using examples from these two basically different systems. The magnitude and duration of the heat output is related to the nature of the film that is undergoing repair and rebuilding on the lithium anode. In the case of Li/SOCl/sub 2/, the film forming reaction is the same as the normal discharge reaction, so heat output information can be used to estimate losses in lithium anode capacity attributed to film formation and repair during storage or following intermittent discharges. However, the solvent reaction with lithium is quite different from the normal discharge reaction in lithium cells using solid cathodes and organic solvent based electrolytes. The data show that heat outputs following partial discharge or short circuit are much higher for Li/SOCl/sub 2/ than for Li/MnO/sub 2/ cells. However, for both of these cell types, formation and repair data are mostly related to the secondary film layer rather than the thin, compact primary layer.
Starting Page	60
Ending Page	63
File Size	466314
Page Count	4
File Format	PDF
ISBN	0780305523
DOI	10.1109/IPSS.1992.282054
Language	English
Publisher	Institute of Electrical and Electronics Engineers, Inc. (IEEE)
Publisher Date	1992-06-22
Publisher Place	USA
Access Restriction	Subscribed
Rights Holder	Institute of Electrical and Electronics Engineers, Inc. (IEEE)
Subject Keyword	Solvents Polymer films Anodes Solids Partial discharges Circuit testing Cathodes Life estimation Lithium compounds Equations
Content Type	Text
Resource Type	Article

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