NDLI: Recent progress in solid polymer electrolyte technologies

Content Provider	IEEE Xplore Digital Library
Author	Fauteux, D. Barnett, B.
Copyright Year	1992
Description	Author affiliation: Arthur D. Little Inc., Cambridge, MA, USA (Fauteux, D.; Barnett, B.)
Abstract	The use of plasticizers in polyether-based solid polymer electrolytes (SPEs) has become a viable approach to increasing room-temperature ionic conductivity. A review of SPE technologies indicates that the selection of an appropriate plasticizer can yield major performance improvements otherwise unlikely to be achieved. However, some of the plasticizers proposed may have detrimental effects on the interfacial impedance and cycle life of SPE-based rechargeable lithium batteries. Recent results obtained from a new group of compounds suitable for use as plasticizers for low- and high-temperature applications are reported. These compounds have been selected and designed for their compatibility with polyether, their low mobility, and their good solvating properties of lithium salts. The plasticizers have low vapor pressure and are thermally stable up to >150 degrees C. Electrolyte solutions made of the plasticizer and lithium salt showed high ionic conductivity at room temperature.
Starting Page	190
Ending Page	191
File Size	171514
Page Count	2
File Format	PDF
ISBN	0780305523
DOI	10.1109/IPSS.1992.282046
Language	English
Publisher	Institute of Electrical and Electronics Engineers, Inc. (IEEE)
Publisher Date	1992-06-22
Publisher Place	USA
Access Restriction	Subscribed
Rights Holder	Institute of Electrical and Electronics Engineers, Inc. (IEEE)
Subject Keyword	Solids Polymers Temperature Batteries Conductivity Lithium Stability Solvents Impedance Research and development
Content Type	Text
Resource Type	Article

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