NDLI: Investigation of surface wetting of a mercury-film electrode in potassium chloride solution after electrochemical treatment

Content Provider	IEEE Xplore Digital Library
Author	Perevezentseva, D.O. Chernyshova, N.N. Karbainov, Ju.A. Kondratuk, A.A.
Copyright Year	2005
Description	Author affiliation: Tomsk Polytech. Univ., Russia (Perevezentseva, D.O.; Chernyshova, N.N.; Karbainov, Ju.A.; Kondratuk, A.A.)
Abstract	The electrochemical activation (EChA) of the aqueous solutions is employed in many technologies, for example, in agriculture, in oil production, in medicine. The EChA of the solutions are also employed for the intensification of the sample pretreatment in an analytical chemistry, for example, the method of the electrochemical sample pretreatment of aqueous solutions for the determination of the toxic metals in the natural water and sewage by stripping voltammetry (SVA). The reasons of the influence of the electrochemical treatment (ECht) on the analytical signals of Cd, Cu has not been investigated yet. There is the investigation of the reasons of the influence of the ECht on the analytical signals of Cd, Cu and the improvement of their reproducibility by SVA in the given work. It was supposed that the changes of shape of analytical signals of Cd, Cu and the improvement of their reproducibility by SVA may be connected with the improvement of the wettability of the surface of the indicator mercury-film electrode. The change of their wettability is connected with the change of the composition and the structure of the solution KCl after the ECht.
Starting Page	261
Ending Page	263
File Size	921851
Page Count	3
File Format	PDF
ISBN	0780389433
DOI	10.1109/KORUS.2005.1507704
Language	English
Publisher	Institute of Electrical and Electronics Engineers, Inc. (IEEE)
Publisher Date	2005-06-26
Publisher Place	Russia
Access Restriction	Subscribed
Rights Holder	Institute of Electrical and Electronics Engineers, Inc. (IEEE)
Subject Keyword	Surface treatment Signal analysis Reproducibility of results Biomedical electrodes Chemical technology Agriculture Petroleum Production Chemistry Shape
Content Type	Text
Resource Type	Article

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