NDLI: Valorization of CO<sub>2</sub> through the Synthesis of Cyclic Carbonates Catalyzed by ZIFs.

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Valorization of CO₂ through the Synthesis of Cyclic Carbonates Catalyzed by ZIFs.

Content Provider	Europe PMC
Author	Delgado-Marín, José J. Martín-García, Iris Villalgordo-Hernández, David Alonso, Francisco Ramos-Fernández, Enrique V. Narciso, Javier
Editor	Samanidou, Victoria Deliyanni, Eleni
Copyright Year	2022
Abstract	One way to exploit CO2 is to use it as a feedstock for the production of cyclic carbonates via its reaction with organic epoxides. As far as we know, there is still no heterogeneous catalyst that accelerates the reaction in a selective, efficient and industrially usable way. Cobalt and zinc-based zeolitic imidazole frameworks (ZIFs) have been explored as heterogeneous catalysts for this reaction. In particular, we have prepared ZIF-8 and ZIF-67 catalysts, which have been modified by partial replacement of 2-methylimidazole by 1,2,4-triazole, in order to introduce uncoordinated nitrogen groups with the metal. The catalysts have shown very good catalytic performance, within the best of the heterogeneous catalysts tested in the cycloaddition of CO2 with epichlorohydrin. The catalytic activity is due ultimately to defects on the outer surface of the crystal, and varies in the order of ZIF-67-m > ZIF-67 > ZiF-8-m = ZIF-8. Notably, reactions take place under mild reaction conditions and without the use of co-catalysts.
Journal	Molecules
Volume Number	27
DOI	10.3390/molecules27227791
PubMed Central reference number	PMC9699457
Issue Number	22
PubMed reference number	36431891
e-ISSN	14203049
Language	English
Publisher	Molecular Diversity Preservation International (MDPI)
Publisher Date	2022-11-12
Access Restriction	Open
Subject Keyword	carbon dioxide cyclic carbonates epichlorohydrin epoxides heterogeneous catalysis ZIFs
Content Type	Text
Resource Type	Article
Subject	Physical and Theoretical Chemistry Medicine Chemistry Drug Discovery Pharmaceutical Science Analytical Chemistry Molecular Medicine Organic Chemistry

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