NDLI: Poly[[diaqua-(μ-4,4'-bipyridine N,N'-di-oxide-κ(2)O:O')(μ-terephthalato-κ(2)O(1):O(4))cobalt(II)] 4,4'-bipyridine N,N'-dioxide monosolvate].

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Poly[[diaqua-(μ-4,4'-bipyridine N,N'-di-oxide-κ(2)O:O')(μ-terephthalato-κ(2)O(1):O(4))cobalt(II)] 4,4'-bipyridine N,N'-dioxide monosolvate].

Content Provider	Europe PMC
Author	Ge, Xin Song, Shu-Yan
Copyright Year	2012
Abstract	In the title compound, {[Co(C8H4O4)(C10H8N2O2)(H2O)2]·C10H8N2O2}n, the CoII atom, lying on an inversion center, is hexacoordinated in a distorted octahedral geometry defined by two O atoms from two terephthalate (tp) ligands, two O atoms from two 4,4′-bipyridine N,N′-dioxide (bpydo) ligands and two water molecules. The coordinated tp and bpydo ligands and uncoordinated bpydo molecule all have an inversion center. The CoII atoms are connected by the tp and bpydo ligands into a layer parallel to (111). In the crystal, O—H⋯O hydrogen bonds link the uncoordinated bpydo molecules and the layers into a three-dimensional supramolecular structure. Intralayer O—H⋯O hydrogen bonds and π–π interactions [centroid-to-centroid distances = 3.6643 (13) and 3.8048 (13) Å] are also observed.
Journal	Acta crystallographica. Section E, Structure Reports Online
Volume Number	68
PubMed Central reference number	PMC3470175
Issue Number	Pt 10
Issue Number	pt 10
PubMed reference number	23125619
e-ISSN	16005368
DOI	10.1107/s1600536812040056
Language	English
Publisher	International Union of Crystallography
Publisher Date	2012-09-26
Access Restriction	Open
Rights License	This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. © Ge and Song 2012
Content Type	Text
Resource Type	Article
Subject	Chemistry Condensed Matter Physics Materials Science

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Poly[[diaqua(μ-4,4′-bipyridine N,N′-dioxide-κ2 O:O′)(μ-terephthalato-κ2 O 1:O 4)cobalt(II)] 4,4′-bipyridine N,N′-dioxide monosolvate]

Poly[[diaqua(μ-4,4′-bipyridine N,N′-dioxide-κ2 O:O′)(μ-terephthalato-κ2 O 1:O 4)cobalt(II)] 4,4′-bipyridine N,N′-dioxide monosolvate]

Poly[diaqua-bis-(μ-4,4'-bipyridine-κ(2) N:N')bis-(ethane-1,2-diol-κO)bis(μ-sulfato-κ(2) O:O')dicobalt(II)].

$catena-Poly[[(1,10-phenanthroline-κ^{2}$ $N,N′)praseodymium(III)]-di-μ-phenoxyacetato-κ^{4}$ $O:O′-[(1,10-phenanthroline-κ^{2}$ $N,N′)praseodymium(III)]-di-μ-phenoxyacetato-κ^{4}$ $O:O′-di-μ-phenoxyacetato-κ^{3}$ $O,O′:O;κ^{3}$ O:O,O′]

catena-Poly[[[diaqua-(1,10-phenanthroline-κ(2)N,N')zinc]-μ-4,4'-bipyridine-κ(2)N:N'] dinitrate 4,4'-bipyridine hemisolvate monohydrate].

$catena-Poly[[[triaquamanganese(II)]-μ-4,4′-bipyridine-κ^{2}$ $N:N′-[triaquamanganese(II)]-μ-pyrimidine-4,6-dicarboxylato-κ^{4}$ N $^{1},O$ $^{6}:N$ $^{3},O$ $^{4}]$ sulfate trihydrate]

catena-Poly[[[diaqua-(1,10-phenanthroline-κ(2)N,N')cobalt(II)]-μ-4-hy-droxy-3-sulfonato-benzoato-κ(2)O(3):O(1)] sesquihydrate].

catena-Poly[[[triaqua[3-(4-carboxyphenoxy)phthalato-κO $^{2}]manganese(II)]-μ-4,4′-bipyridine-κ^{2}$ N:N′] 4,4′-bipyridine monosolvate dihydrate]

$catena-Poly[[(1,10-phenanthroline-5,6-dione-κ^{2}$ $N,N′)lead(II)]-μ-terephthalato-κ^{2}$ O $^{1}:O$ $^{4}]$

Poly[[diaqua-(μ-4,4'-bipyridine N,N'-di-oxide-κ(2)O:O')(μ-terephthalato-κ(2)O(1):O(4))cobalt(II)] 4,4'-bipyridine N,N'-dioxide monosolvate].

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Poly[[diaqua(μ-4,4′-bipyridine N,N′-dioxide-κ2 O:O′)(μ-terephthalato-κ2 O 1:O 4)cobalt(II)] 4,4′-bipyridine N,N′-dioxide monosolvate]

Poly[[diaqua­(μ-4,4′-bipyridine N,N′-di­oxide-κ2 O:O′)(μ-terephthalato-κ2 O 1:O 4)cobalt(II)] 4,4′-bipyridine N,N′-dioxide monosolvate]

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$catena-Poly[[(1,10-phenanthroline-κ^{2}$ $N,N′)praseodymium(III)]-di-μ-phenoxy­acetato-κ^{4}$ $O:O′-[(1,10-phenanthroline-κ^{2}$ $N,N′)praseodymium(III)]-di-μ-phenoxy­acetato-κ^{4}$ $O:O′-di-μ-phenoxy­acetato-κ^{3}$ $O,O′:O;κ^{3}$ O:O,O′]

catena-Poly[[[diaqua-(1,10-phenanthroline-κ(2)N,N')zinc]-μ-4,4'-bipyridine-κ(2)N:N'] dinitrate 4,4'-bipyridine hemisolvate monohydrate].

$catena-Poly[[[triaqua­manganese(II)]-μ-4,4′-bipyridine-κ^{2}$ $N:N′-[triaqua­manganese(II)]-μ-pyrimidine-4,6-dicarboxyl­ato-κ^{4}$ N $^{1},O$ $^{6}:N$ $^{3},O$ $^{4}]$ sulfate trihydrate]

catena-Poly[[[diaqua-(1,10-phenanthroline-κ(2)N,N')cobalt(II)]-μ-4-hy-droxy-3-sulfonato-benzoato-κ(2)O(3):O(1)] sesquihydrate].

catena-Poly[[[triaqua­[3-(4-carb­oxy­phen­oxy)phthalato-κO $^{2}]manganese(II)]-μ-4,4′-bipyridine-κ^{2}$ N:N′] 4,4′-bipyridine monosolvate dihydrate]

$catena-Poly[[(1,10-phenanthroline-5,6-dione-κ^{2}$ $N,N′)lead(II)]-μ-terephthalato-κ^{2}$ O $^{1}:O$ $^{4}]$

Poly[[diaqua-(μ-4,4'-bipyridine N,N'-di-oxide-κ(2)O:O')(μ-terephthalato-κ(2)O(1):O(4))cobalt(II)] 4,4'-bipyridine N,N'-dioxide monosolvate].

Poly[[diaqua(μ-4,4′-bipyridine N,N′-dioxide-κ2 O:O′)(μ-terephthalato-κ2 O 1:O 4)cobalt(II)] 4,4′-bipyridine N,N′-dioxide monosolvate]

$catena-Poly[[(1,10-phenanthroline-κ^{2}$ $N,N′)praseodymium(III)]-di-μ-phenoxyacetato-κ^{4}$ $O:O′-[(1,10-phenanthroline-κ^{2}$ $N,N′)praseodymium(III)]-di-μ-phenoxyacetato-κ^{4}$ $O:O′-di-μ-phenoxyacetato-κ^{3}$ $O,O′:O;κ^{3}$ O:O,O′]

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catena-Poly[[[triaqua[3-(4-carboxyphenoxy)phthalato-κO $^{2}]manganese(II)]-μ-4,4′-bipyridine-κ^{2}$ N:N′] 4,4′-bipyridine monosolvate dihydrate]