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catena-Poly[[[diaqua-(1,10-phenanthroline-κ(2)N,N')zinc]-μ-4,4'-bipyridine-κ(2)N:N'] dinitrate 4,4'-bipyridine hemisolvate monohydrate].
| Content Provider | Europe PMC |
|---|---|
| Author | Xu, Shan Dai, Yong-Cheng Qiu, Qi-Ming Jin, Qiong-Hua Zhang, Cun-Lin |
| Copyright Year | 2012 |
| Abstract | In the title compound, [Zn(C10H8N2)(C12H8N2)(H2O)2](NO3)2·0.5C10H8N2·H2O, the ZnII atom is coordinated in a distorted octahedral geometry by two N atoms from two 4,4′-bipyridine (4,4′-bipy) ligands, two N atoms from a chelating 1,10-phenanthroline ligand and two O atoms from two mutually cis water molecules. The 4,4′-bipy ligands bridge the ZnII atoms into a chain structure along [100]. The uncoordinated 4,4′-bipy molecule lies on an inversion center. O—H⋯O and O—H⋯N hydrogen bonds connect the cationic chains, the nitrate anions, the uncoordinated 4,4′-bipy molecules and the water molecules into tow-dimensional networks. |
| Journal | Acta crystallographica. Section E, Structure Reports Online |
| Volume Number | 68 |
| PubMed Central reference number | PMC3435629 |
| Issue Number | Pt 9 |
| Issue Number | pt 9 |
| PubMed reference number | 22969502 |
| e-ISSN | 16005368 |
| DOI | 10.1107/s1600536812036318 |
| Language | English |
| Publisher | International Union of Crystallography |
| Publisher Date | 2012-08-31 |
| Access Restriction | Open |
| Rights License | This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. © Xu et al. 2012 |
| Content Type | Text |
| Resource Type | Article |
| Subject | Chemistry Condensed Matter Physics Materials Science |
