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| Content Provider | World Health Organization (WHO)-Global Index Medicus |
|---|---|
| Author | Sohrabi, Beheshteh Moallemi, Maryam Fazeli, Sara |
| Description | Country affiliation: Iran Author Affiliation: Moallemi M ( Department of Chemistry, Iran University of Science and Technology, Tehran, Iran.) |
| Abstract | The effect of salt concentration on intermicellar interactions and aggregate structures of anionic and cationic-rich mixtures of CTAB (cetyltrimethylammonium bromide) and SDS (sodium dodecyl sulfate) were investigated with conductometry, surface tension, zeta potential, cyclic voltammetry measurements and by determining the surfactant NMR self-diffusion coefficients. The critical aggregate concentration (CAC), surface excess (Γ(max)), and mean molecular surface area (A(min)) were determined from plots of the surface tension (γ) as a function of the log of total surfactant concentration. The electrochemical behavior of cationic-anionic (catanionic) mixed surfactant and self-assembled surfactant monomers at Pt wire electrode were studied by cyclic voltammetry (CV). A variation in the peak current versus the total concentration of surfactant allow us to evaluate the CAC and related parameters from regular solution theory along with the diffusion coefficient of the electroactive species. It was observed that, for both the planar air/aqueous interface and micellar systems, the nonideality decreased as the amount of electrolyte in the aqueous medium was increased. Finally, we investigated the variations of electrostatic, transfer and steric free energy in phase transition between mixed micelle and vesicle in the presence of electrolyte using the presented model by our groups. |
| ISSN | 00219797 |
| Issue Number | 1 |
| Journal | Journal of Colloid and Interface Science |
| Volume Number | 361 |
| e-ISSN | 10957103 |
| Language | English |
| Publisher | Elsevier |
| Publisher Date | 2011-09-01 |
| Publisher Place | United States |
| Access Restriction | One Nation One Subscription (ONOS) |
| Subject Keyword | Discipline Colloid & Interface Science |
| Content Type | Text |
| Resource Type | Article |
| Subject | Surfaces, Coatings and Films Colloid and Surface Chemistry Biomaterials Electronic, Optical and Magnetic Materials |
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