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| Content Provider | World Health Organization (WHO)-Global Index Medicus |
|---|---|
| Author | Prasanna, Dakshinamoorthy Selvaraj, Vaithilingam |
| Description | Country affiliation: India Author Affiliation: Prasanna D ( Nanotech Research Lab, Department of Chemistry, University College of Engineering Villupuram (A Constituent College of Anna University, Chennai), Kakuppam, Villupuram 605 103, Tamil Nadu, India.); Selvaraj V ( Nanotech Research Lab, Department of Chemistry, University College of Engineering Villupuram (A Constituent College of Anna University, Chennai), Kakuppam, Villupuram 605 103, Tamil Nadu, India. Electronic address: vaithilingamselvaraj@gmail.com.) |
| Abstract | This present study reports the development of novel catalyst support of amine terminated cyclophosphazene/cyclophosphazene/hexafluoroisopropylidenedianiline-carbon nanotube (ATCP/CP/HFPA-CNT) composite. The ATCP/CP/HFPA-CNT composite has been used as a catalyst support for platinum (Pt) and platinum-gold (Pt-Au) nanoparticles towards electrooxidation of methanol in alkaline medium. The obtained anode materials were characterized by X-ray diffraction, transmission electron microscope and energy dispersive X-ray analysis. Electrocatalytic performances of Pt/ATCP/CP/HFPA-CNT and Pt-Au/ATCP/CP/HFPA-CNT catalysts were investigated by cyclic voltammetry, CO stripping and chronoamperometric techniques. The electrooxidation of methanol and CO stripping results conclude that the metal nanocatalyst embedded with ATCP/CP/HFPA-CNT composite shows significantly higher anodic oxidation current, more CO tolerance and lower onset potential when compared to that of the Pt/CNT and Pt/C (Vulcan carbon) catalysts. |
| ISSN | 00219797 |
| Journal | Journal of Colloid and Interface Science |
| Volume Number | 472 |
| e-ISSN | 10957103 |
| Language | English |
| Publisher | Elsevier |
| Publisher Date | 2016-06-15 |
| Publisher Place | United States |
| Access Restriction | One Nation One Subscription (ONOS) |
| Subject Keyword | Discipline Colloid & Interface Science |
| Content Type | Text |
| Resource Type | Article |
| Subject | Surfaces, Coatings and Films Colloid and Surface Chemistry Biomaterials Electronic, Optical and Magnetic Materials |
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