| Content Provider |
World Health Organization (WHO)-Global Index Medicus |
| Author |
Bandowe, Benjamin A. Musa Huang, Rujin Ho, Kinfai Cao, Junji Meusel, Hannah Hoffmann, Thorsten |
| Description |
Country affiliation: Switzerland Author Affiliation: Bandowe BA ( Institute of Geography, University of Bern, Hallerstrasse 12, 3012, Bern, Switzerland. benjamin.bandowe@giub.unibe.ch.); Meusel H ( Oeschger Centre for Climate Change Research, University of Bern, Falkenplatz 16, 3012, Bern, Switzerland. benjamin.bandowe@giub.unibe.ch.); Huang R ( Multiphase Chemistry Department, Max Planck Institute for Chemistry, Hahn-Meitner-Weg 1, 55128, Mainz, Germany.); Hoffmann T ( Key Laboratory of Aerosol Chemistry & Physics, Institute of Earth Environment, Chinese Academy of Sciences, 10 Fenghui South Road, 710075, Xi'an, China.); Cao J ( Centre for Atmospheric and Marine Sciences, Xiamen Huaxia University, Xiamen, 361024, China.); Ho K ( Laboratory of Atmospheric Chemistry, Paul Scherrer Institute, 5232, Villigen, Switzerland.) |
| Abstract |
Azaarenes (AZAs) are toxicologically relevant organic compounds with physicochemical properties that are significantly different from the well-studied polycyclic aromatic hydrocarbons (PAHs). However, little is known about their concentrations, seasonal variations, fate, and relationship with PAHs in air. This paper reports the temporal variations in the concentrations and composition patterns of AZAs in PM2.5 that was sampled once per 6 days from outdoor air of Xi'an, China from July 2008 to August 2009. The concentrations of the ∑AZAs, quinoline (QUI), benzo[h]quinoline (BQI), and acridine (ACR) in PM2.5 were 213-6441, 185-520, 69-2483, and 10-3544 pg m(-3), respectively. These concentrations were higher than those measured in urban areas of Western Europe. AZA compositional patterns were dominated by BQI and ACR. The high concentration of AZAs, high AZA/related PAH ratio, and the dominance of three-ring AZAs (BQI and ACR) in PM2.5 of Xi'an are all in contrast to observations from Western European and North American cities. This contrast likely reflects differences in coal type and the more intense use of coal in China. The PM2.5-bound concentration of AZA in winter season (W) was higher than during the summer season (S) with W/S ratios of 5.7, 1.4, 4.1, and 13, for ∑AZAs, QUI, BQI, and ACR, respectively. Despite their significantly different physicochemical properties, AZAs were significantly (p < 0.05) positively correlated with their related PAHs and pyrogenic elemental carbon. The changes in AZA concentrations were positively correlated with ambient pressure but negatively correlated with ambient temperature, wind speed, and relative humidity. This trend is similar to that observed for the related PAHs. We conclude that Xi'an and possibly other Chinese cities have higher emission of AZAs into their atmosphere because of the more pronounced use of coal. We also conclude that in spite of differences in physicochemical properties between AZAs and related PAHs, the atmospheric dynamics and relationships with meteorological factors of both compound groups are similar. |
| ISSN |
09441344 |
| Issue Number |
16 |
| Journal |
Environmental Science and Pollution Research |
| Volume Number |
23 |
| e-ISSN |
16147499 |
| Language |
English |
| Publisher |
Springer |
| Publisher Date |
2016-08-01 |
| Publisher Place |
Germany |
| Access Restriction |
One Nation One Subscription (ONOS) |
| Subject Keyword |
Discipline Environmental Science Discipline Environmental Chemistry |
| Content Type |
Text |
| Resource Type |
Article |
| Subject |
Environmental Chemistry Health, Toxicology and Mutagenesis Pollution Medicine |
