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| Content Provider | World Health Organization (WHO)-Global Index Medicus |
|---|---|
| Author | de la Piscina, Pilar Ramírez Pereira, Evandro Brum Homs, Narcís |
| Description | Country affiliation: Spain Author Affiliation: Pereira EB ( Departament de Química Inorgànica, Universitat de Barcelona, Barcelona, Spain. epereira@uerj.br) |
| Abstract | The aim of this study was to investigate biohydrogen production from biofuel-reforming processes using new multi-component bulk-type cobalt-based catalysts. The addition of different components to improve the catalytic performance was studied. Monometallic cobalt catalyst and catalysts containing Ru (ca. 1%) and/or Na (ca. 0.5%) were characterized and tested in the 623-673 K temperature range in ethanol steam reforming (ESR) with a steam/carbon ratio (S/C) of 3. The catalysts showed a high performance for hydrogen production and, except for H(2) and CO(2), only small amounts of by-products were obtained, depending on the temperature and the catalyst used. The catalyst containing both Ru and Na (Co-Ru(Na)) showed the best catalytic behavior in ESR. It operated stably for at least 12 days under cycles of oxidative steam reforming of glycerol/ethanol mixtures (S/C=2) and activation under O(2). |
| ISSN | 09608524 |
| Issue Number | 3 |
| Volume Number | 102 |
| e-ISSN | 18732976 |
| Journal | Bioresource Technology |
| Language | English |
| Publisher | Elsevier |
| Publisher Date | 2011-02-01 |
| Publisher Place | Great Britain (UK) |
| Access Restriction | One Nation One Subscription (ONOS) |
| Subject Keyword | Biofuels Analysis Cobalt Chemistry Ethanol Glycerol Hydrogen Catalysis Gases Isolation & Purification Journal Article Research Support, Non-u.s. Gov't Discipline Bioresource |
| Content Type | Text |
| Resource Type | Article |
| Subject | Waste Management and Disposal Medicine Environmental Engineering Renewable Energy, Sustainability and the Environment Bioengineering |
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