NDLI: 2,2′-Biquinolines as test pilots for tuning the colour emission of luminescent mesomorphic silver(I) complexes

Please wait, while we are loading the content...

Year: 2017 Volume: 46

Year: 2016 Volume: 45

Year: 2015 Volume: 44

Year: 2014 Volume: 43

Year: 2013 Volume: 42

Year: 2012 Volume: 41

Year: 2011 Volume: 40

Year: 2011 Volume: 40 Issue: 48

Year: 2011 Volume: 40 Issue: 47

Year: 2011 Volume: 40 Issue: 46

Year: 2011 Volume: 40 Issue: 45

Year: 2011 Volume: 40 Issue: 44

Year: 2011 Volume: 40 Issue: 43

Year: 2011 Volume: 40 Issue: 42

Year: 2011 Volume: 40 Issue: 41

Year: 2011 Volume: 40 Issue: 40

Year: 2011 Volume: 40 Issue: 39

Year: 2011 Volume: 40 Issue: 38

Year: 2011 Volume: 40 Issue: 37

Year: 2011 Volume: 40 Issue: 36

Year: 2011 Volume: 40 Issue: 35

Year: 2011 Volume: 40 Issue: 34

Year: 2011 Volume: 40 Issue: 33

Year: 2011 Volume: 40 Issue: 32

Year: 2011 Volume: 40 Issue: 31

Year: 2011 Volume: 40 Issue: 30

Year: 2011 Volume: 40 Issue: 29

Year: 2011 Volume: 40 Issue: 28

Year: 2011 Volume: 40 Issue: 27

Year: 2011 Volume: 40 Issue: 26

Year: 2011 Volume: 40 Issue: 25

Year: 2011 Volume: 40 Issue: 24

Year: 2011 Volume: 40 Issue: 23

Year: 2011 Volume: 40 Issue: 22

Year: 2011 Volume: 40 Issue: 21

Year: 2011 Volume: 40 Issue: 20

Year: 2011 Volume: 40 Issue: 19

Year: 2011 Volume: 40 Issue: 18

Year: 2011 Volume: 40 Issue: 17

Controlling the growth of low dimension nanostructures of an iridium complex

$[(Me)_{2}NH_{2}]_{0.75}[Ag_{1.25}SnSe_{3}]:$ A three-dimensionally microporous chalcogenide exhibiting framework flexibility upon ion-exchange

Structural considerations and reactivity of peroxocomplexes of V(V), Mo(VI) and W(VI)

Supramolecular ligand–ligand and ligand–substrate interactions for highly selective transition metal catalysis

Heteroscorpionate rare-earth initiators for the controlled ring-opening polymerization of cyclic esters

Structure and spectroscopic characterization of free base and metal complexes of 5,5-dimethyl-10,15-bis(pentafluorophenyl)isocorrole

Oxidative properties of iodine-adducts of propylthiouracil and methimazole : Direct synthesis of mercury(II) complexes from the reaction with liquid mercury

Syntheses, crystal structures, photophysical and theoretical studies of 1,3,2-benzodiazaborolyl-functionalized diphenylacetylenes

Interaction with DNA and different effect on the nucleus of cancer cells for copper( II) complexes of N-benzyl di(pyridylmethyl)amine

Infinite terbium(III) chains formed from a tetra-phosphorylated resorcinarene cavitand

A new familiy of heteroleptic ruthenium(II) polypyridyl complexes for sensitization of nanocrystalline $TiO_{2}$ films

Speciation of organic-soluble europium( III) α1-Wells–Dawson complexes

N-heterocyclic carbene Pt(II) complexes from caffeine : synthesis, structures and photoluminescent properties

$Na[Li(NH_{2}BH_{3})_{2}]$ – the first mixed- cation amidoborane with unusual crystal structure

Transition metal complexes bearing a 2,2-bis(3,5-dimethylpyrazol-1-yl)propionate ligand : one methyl more matters

Forward molecular design for highly efficient OLED emitters: A theoretical analysis of photophysical properties of platinum(II) complexes with N-heterocyclic carbene ligands

trans-Methylpyridine cyclen versus cross-bridged trans-methylpyridine cyclen. Synthesis, acid–base and metal complexation studies (metal = $Co^{2+},$ $Cu^{2+},$ and $Zn^{2+})$

Dimethylaluminium iminophosphoranylenamides and iminophosphoranylanilides: Synthesis, characterisation, and their controlled ring-opening polymerisation of ε-caprolactone

Intramolecularly coordinated azobenzene selenium derivatives: Effect of strength of the Se⋯N intramolecular interaction on luminescence

Irreversible transformation of chiral to achiral polymorph of $K[Co(HCOO)_{3}]:$ synthesis, structures, and magnetic properties

Influence of amines on the size control of in situ synthesized ruthenium nanoparticles in imidazolium ionic liquids

The low spin $Co^{II}$ fragment with homoleptic 1,10-phenanthroline ligands : synthesis, structures, DFT investigations, and magnetic properties

Structure and properties of ionic fullerene complex $Co^{+}(dppe)_{2}·(C_{60}˙^{−})·(C_{6}H_{4}Cl_{2})_{2}:$ distortion of the ordered fullerene cage of $C_{60}˙^{−}radical$ anions

Potassium $S_{2}N-heteroscorpionates:$ structure and iridaboratrane formation

Half-zirconocene anilide complexes: synthesis, characterization and catalytic properties for ethylene polymerization and copolymerization with 1-hexene

π–π Interaction intercalation of layered carbon materials with metallocene

Effect of terminal N-substitution in 2-oxo-1,2-dihydroquinoline-3-carbaldehyde thiosemicarbazones on the mode of coordination, structure, interaction with protein , radical scavenging and cytotoxic activity of copper(II) complexes

High-spin Ni(II) clusters: triangles and planar tetranuclear complexes

The coordination behaviour of ferrocene -based pyridylphosphine ligands towards $Zn^{II},$ $Cd^{II}$ and $Hg^{II}$

Comparative spectroscopic and mechanistic study of chelation properties of fisetin with iron in aqueous buffered solutions. Implications on in vitroantioxidant activity

Controlled synthesis of nickel(II) dihalides bearing two different or identical N-heterocyclic carbene ligands and the influence of carbene ligands on their structures and catalysis

Addition of boranes to N-aryl-salicylaldimines: Intramolecular hydrogenation of imines

Complexes of functionally modified hydrazone ligands —square, rectangular $(M_{4}),$ trigonal bipyramidal $(M_{5})$ and pin-wheel $(M_{6})$ motifs

Ag(I) and Zn(II) coordination polymers with a bulky naphthalene -based dicarboxyl tecton and different 4,4′-bipyridyl -like bridging co- ligands : structural regulation and properties

The preparation of HfC/C ceramics via molecular design

Syntheses, crystal structures and characterizations of two new quaternary thioborates: $PbMBS_{4}$ (M = Sb, Bi)

Probing the structural and magnetic properties of transition metal- benzene anion complexes

High-pressure synthesis and neutron diffraction investigation of the crystallographic and magnetic structure of $TeNiO_{3}$ perovskite

First single-crystal synthesis and low-temperature structural determination of the quasi-2D quantum spin compound $(CuCl)LaNb_{2}O_{7}$

Atomic layer deposition of organic–inorganic hybrid materials based on saturated linear carboxylic acids

Novel pincer complexes of Ag(I), coordination of toluene and their comparison with indium analogues

2,2′-Biquinolines as test pilots for tuning the colour emission of luminescent mesomorphic silver(I) complexes

Pressure-induced first-order phase transition in $(NH_{4})_{2}V_{3}O_{8}$ fresnoite: a double coordination change for $V^{4+}$ and $V^{5+}$

Nickel( II) hydride and fluoride pincer complexes and their reactivity with Lewis acids $BX_{3}·L$ (X = H, L = thf; X = F, L = $Et_{2}O)$

Year: 2011 Volume: 40 Issue: 16

Year: 2011 Volume: 40 Issue: 15

Year: 2011 Volume: 40 Issue: 14

Year: 2011 Volume: 40 Issue: 13

Year: 2011 Volume: 40 Issue: 12

Year: 2011 Volume: 40 Issue: 11

Year: 2011 Volume: 40 Issue: 10

Year: 2011 Volume: 40 Issue: 9

Year: 2011 Volume: 40 Issue: 8

Year: 2011 Volume: 40 Issue: 7

Year: 2011 Volume: 40 Issue: 6

Year: 2011 Volume: 40 Issue: 5

Year: 2011 Volume: 40 Issue: 4

Year: 2011 Volume: 40 Issue: 3

Year: 2011 Volume: 40 Issue: 2

Year: 2011 Volume: 40 Issue: 1

Year: 2010 Volume: 39

2,2′-Biquinolines as test pilots for tuning the colour emission of luminescent mesomorphic silver(I) complexes

Content Provider	World Health Organization (WHO)-Global Index Medicus
Author	Pucci, Daniela Crispini, Alessandra Ghedini, Mauro La Deda, Massimo Szerb, Elisabeta I.
Description	Author Affiliation: Pucci D ( Centro di Eccellenza CEMIF.CAL-LASCAMM, CR-INSTM Unità della Calabria, Dipartimento di Chimica, Università della Calabria, Via P. Bucci Cubo 14C, Italy. d.pucci@unical.it)
Abstract	The synthesis and characterization of a series of 2,2′-biquinolines differently substituted in the 4,4′-position and their corresponding silver(I) derivatives obtained through reaction with silver triflate in a 1:1 stoichiometric ratio are reported. In order to perform a systematic investigation on the role played by the substituents on the coordination to the silver(I) centre, structural studies through single crystal X-ray diffraction have been performed on two Ag(I) model complexes. Unlike their analogous 2,2′-bipyridine ligands , the biquinolines have been found to behave only as chelated ligands towards the silver(I) ion, irrespective of the substituents. The coordination sphere of the Ag(I) is filled by a solvent molecule and, depending on the presence and nature of the substituents on the organic ligand , by an oxygen atom coming from a coordinated triflate or from a carboxylic group of a symmetrically related molecule, giving rise to neutral or ionic species. For the highest Ag(I) triflate homologues the presence of long and flexible peripheral tails makes it possible to achieve liquid crystalline properties with columnar organization whose high order is due to the large and rigid core. Moreover, the metal coordination induces in all the Ag(I) species interesting emission properties both in solution and condensed states, giving rise to blue or green emitters, depending on the nature of the substituents on the biquinoline units.
ISSN	14779226
Issue Number	17
Volume Number	40
e-ISSN	13645447
Journal	Dalton Trans.
Language	English
Publisher	Royal Society of Chemistry
Publisher Date	2011-05-07
Publisher Place	Great Britain (UK)
Access Restriction	Subscribed
Subject Keyword	Coordination Complexes Chemistry Quinolines Silver Color Chemical Synthesis Crystallography, X-Ray Molecular Conformation Phase Transition Spectrophotometry, Ultraviolet Temperature Journal Article Research Support, Non-U.S. Gov't
Content Type	Text
Resource Type	Article
Subject	Inorganic Chemistry

Central Library (ISO-9001:2015 Certified)
Indian Institute of Technology Kharagpur
Kharagpur, West Bengal, India | PIN - 721302

See location in the Map
03222 282435
Mail: support@ndl.gov.in

Sl.	Authority	Responsibilities	Communication Details
1	Ministry of Education (GoI), Department of Higher Education	Sanctioning Authority	https://www.education.gov.in/ict-initiatives
2	Indian Institute of Technology Kharagpur	Host Institute of the Project: The host institute of the project is responsible for providing infrastructure support and hosting the project	https://www.iitkgp.ac.in
3	National Digital Library of India Office, Indian Institute of Technology Kharagpur	The administrative and infrastructural headquarters of the project	Dr. B. Sutradhar bsutra@ndl.gov.in
4	Project PI / Joint PI	Principal Investigator and Joint Principal Investigators of the project	Dr. B. Sutradhar bsutra@ndl.gov.in Prof. Saswat Chakrabarti will be added soon
5	Website/Portal (Helpdesk)	Queries regarding NDLI and its services	support@ndl.gov.in
6	Contents and Copyright Issues	Queries related to content curation and copyright issues	content@ndl.gov.in
7	National Digital Library of India Club (NDLI Club)	Queries related to NDLI Club formation, support, user awareness program, seminar/symposium, collaboration, social media, promotion, and outreach	clubsupport@ndl.gov.in
8	Digital Preservation Centre (DPC)	Assistance with digitizing and archiving copyright-free printed books	dpc@ndl.gov.in
9	IDR Setup or Support	Queries related to establishment and support of Institutional Digital Repository (IDR) and IDR workshops	idr@ndl.gov.in