NDLI: Low valent and hydride complexes of NHC coordinated gallium and indium

Please wait, while we are loading the content...

Year: 2017 Volume: 46

Year: 2016 Volume: 45

Year: 2015 Volume: 44

Year: 2014 Volume: 43

Year: 2013 Volume: 42

Year: 2012 Volume: 41

Year: 2012 Volume: 41 Issue: 48

Year: 2012 Volume: 41 Issue: 47

Year: 2012 Volume: 41 Issue: 46

Year: 2012 Volume: 41 Issue: 45

Year: 2012 Volume: 41 Issue: 44

Year: 2012 Volume: 41 Issue: 43

Year: 2012 Volume: 41 Issue: 42

Year: 2012 Volume: 41 Issue: 41

Year: 2012 Volume: 41 Issue: 39

Year: 2012 Volume: 41 Issue: 38

Year: 2012 Volume: 41 Issue: 37

Year: 2012 Volume: 41 Issue: 36

Year: 2012 Volume: 41 Issue: 35

Year: 2012 Volume: 41 Issue: 34

Year: 2012 Volume: 41 Issue: 33

Year: 2012 Volume: 41 Issue: 32

Year: 2012 Volume: 41 Issue: 31

Year: 2012 Volume: 41 Issue: 30

Year: 2012 Volume: 41 Issue: 29

Year: 2012 Volume: 41 Issue: 28

Year: 2012 Volume: 41 Issue: 27

Year: 2012 Volume: 41 Issue: 26

Year: 2012 Volume: 41 Issue: 25

Year: 2012 Volume: 41 Issue: 24

Year: 2012 Volume: 41 Issue: 23

Year: 2012 Volume: 41 Issue: 22

Year: 2012 Volume: 41 Issue: 21

Year: 2012 Volume: 41 Issue: 20

Year: 2012 Volume: 41 Issue: 19

Year: 2012 Volume: 41 Issue: 18

Year: 2012 Volume: 41 Issue: 17

Year: 2012 Volume: 41 Issue: 16

Year: 2012 Volume: 41 Issue: 15

Year: 2012 Volume: 41 Issue: 14

Year: 2012 Volume: 41 Issue: 13

Year: 2012 Volume: 41 Issue: 12

Year: 2012 Volume: 41 Issue: 11

Year: 2012 Volume: 41 Issue: 10

Year: 2012 Volume: 41 Issue: 9

Year: 2012 Volume: 41 Issue: 8

Year: 2012 Volume: 41 Issue: 7

Year: 2012 Volume: 41 Issue: 6

Year: 2012 Volume: 41 Issue: 5

Year: 2012 Volume: 41 Issue: 4

Year: 2012 Volume: 41 Issue: 3

A 3D $α-Fe_{2}O_{3}$ nanoflake urchin-like structure for electromagnetic wave absorption

Can a meso-type dinuclear complex be chiral?: dinuclear β-diketonato Ru(III) complexes

Formation of the second superhydrophobic shell around an encapsulated metal ion: synthesis, X-ray structure and electrochemical study of the clathrochelate and bis-clathrochelate iron(II) and cobalt(II, III) dioximates with ribbed perfluoroarylsulfide substituents

New methods for functionalizing biologically important molecules using triosmium metal clusters

The role of three-center/four-electron bonds in superelectrophilic dirhodium carbene and nitrene catalytic intermediates

A systematic study on the synthesis, reactivity and structure of ortho-palladated aryloximes, including the first cyclopalladated aryloximato and iminoaryloxime complexes

Synthesis, crystal structure and properties of a new candidate for nonlinear optical material in the IR region: $Hg_{2}BrI_{3}$

Substitution behaviour of novel dinuclear Pt(II) complexes with bio-relevant nucleophiles

One-step synthesis of cubic $FeS_{2}$ and flower-like $FeSe_{2}$ particles by a solvothermal reduction process

Exhaustive oxidation of a nickel dithiolate complex: some mechanistic insights en route to sulfate formation

Distorted cubic tetranuclear vanadium( IV) phosphonate cages: double-four-ring (D4R) containing transition metal ion phosphonate cages

Molecular and ionic complexes of pyrrolidinofullerene bearing chelating 3-pyridyl units

Insight into the structural characteristics of core-links and flat-aluminum tridecamers: A density functional theory study

Preparation and formation mechanism of a $n-butylammonium/MnO_{2}$ layered hybrid via a one-pot synthesis under moderate conditions

Ni(II) and Pd(II) pyridinyloxazolidine-compounds: synthesis, X-ray characterisation and catalytic activities in the aza-Michael reaction

Syntheses of highly unsaturated isocyanidesvia organometallic pathways

A novel $Zn_{4}O-based$ triazolyl benzoate MOF: synthesis, crystal structure, adsorption properties and solid state $^{13}C$ NMR investigations

Evidence for acyl – iron ligation in the active site of [Fe]-hydrogenase provided by mass spectrometry and infrared spectroscopy

Low valent and hydride complexes of NHC coordinated gallium and indium

Synthesis, characterization and photophysical properties of $PPh_{2}–C_{2}–(C_{6}H_{4})_{n}–C_{2}–PPh_{2}$ based bimetallic Au(I) complexes

Promoted hydrogen release from ammonia borane with mannitolvia a solid-state reaction route

In situ controlled growth of well-dispersed gold nanoparticles in $TiO_{2}$ nanotube arrays as recyclable substrates for surface-enhanced Raman scattering

Controlled synthesis and size-dependent thermal conductivity of $Fe_{3}O_{4}$ magnetic nanofluids

Synthesis and structure of the first clathrochelate iron(II) tris-dioximates with inherent nitrile substituent(s) and new dehalogenation – reduction reaction at a quasi-aromatic macrobicyclic framework

Photo-induced DNA cleavage activity and remarkable photocytotoxicity of lanthanide( III) complexes of a polypyridyl ligand

Highly luminescent bis-diketone lanthanide complexes with triple-stranded dinuclear structure

Synthesis, structures, and properties of ruthenium(II) complexes of N-(1,10-phenanthrolin-2-yl)imidazolylidenes

Control over the oxidative reactivity of metalloporphyrins . Efficient electrosynthesis of meso,meso-linked zinc porphyrin dimer

Isolation and characterization of main group and late transition metal complexes using orthometallated imine ligands

Development of a borondipyrromethene-based $Zn^{2+}$ fluorescent probe : solvent effects on modulation sensing ability

$Ru_{x}Pt_{y}Sn_{z}cluster-derived$ nanoparticle catalysts : spectroscopic investigation into the nature of active multinuclear single sites

Protonolysis of $[(^{i}PrO)TiMo_{5}O_{18}]^{3−}:$ access to a family of $TiMo_{5}$ Lindqvist type polyoxometalates

Dipyridylketone as a versatile ligand precursor for new cationic heteroleptic cyclometalated iridium complexes

A kinetics and mechanistic study on the role of the structural rigidity of the linker on the substitution reactions of chelated dinuclear Pt(II) complexes

Structure, electronic configuration, and Mössbauer spectral parameters of an antiferromagnetic Fe $_{2}-peroxo$ intermediate of methane monooxygenase

Potassium ion-mediated non-covalent bonded coordination polymers

Ionothermal synthesis process for aluminophosphate molecular sieves in the mixed water/ ionic liquid system

(α-Diimine)tricarbonylhalorhenium complexes: the oxidation side

Structural motifs in phenylbismuth heterocyclic carboxylates – secondary interactions leading to oligomers

A series of pillar-layer metal–organic frameworks based on 5-aminoisophthalic acid and 4,4′-bipyridine

Mechanistic investigation of cyclohexane oxidation by a non-heme iron complex: evidence of product inhibition by UV/vis stopped-flow studies

Structure and magnetic exchange in heterometallic 3d–3d transition metal triethanolamine clusters

Zinc and magnesium complexes incorporated by bis(amine) benzotriazole phenoxide ligand : Synthesis, characterization, photoluminescent properties and catalysis for ring-opening polymerization of lactide

Characterization of HDEHP-lanthanide complexes formed in a non-polar organic phase using $^{31}P$ NMR and ESI-MS

Synthesis and optoelectronic properties of a carbazole -modified platinum(II) complex in polymer light-emitting devices

A novel genetically encoded fluorescent protein as a Cu(I) indicator

Construction of graphdiyne nanowires with high-conductivity and mobility

Synthesis and structure of QD-6: A novel aluminoborate constructed from unprecedented $[B@Al_{6}O_{24}]$ and polyborate clusters

Year: 2012 Volume: 41 Issue: 2

Year: 2012 Volume: 41 Issue: 1

Year: 2011 Volume: 40

Year: 2010 Volume: 39

Low valent and hydride complexes of NHC coordinated gallium and indium

Content Provider	World Health Organization (WHO)-Global Index Medicus
Author	Ball, Graham E. Cole, Marcus L. Mckay, Alasdair I.
Description	Author Affiliation: Ball GE ( School of Chemistry, University of New South Wales, Sydney, NSW 2052, Australia.)
Abstract	The reactions of the N-heterocyclic carbene 1,3-dimesitylimidazol-2-ylidene (IMes) with Ga[GaCl $_{4}]$ , “ GaI ”, InCl $_{2}$ and GaBr $_{3}$ have been examined. All reactions using a low valent gallium or indium starting material led to species of the form [{MX $_{2}(IMes)\}$ $_{2}]$ , where M = Ga, X = Cl (1), I (2); M = In, X = Cl (3), with disproportionation and loss of gallium metal in the case of 2. Reaction of IMes with gallium tribromide yields the air and moisture stable complex $[GaBr_{3}(IMes)]$ (4), which has been used as a precursor to the mixed bromohydrides $[GaBrH_{2}(IMes)]$ (5) and $[GaBr_{2}H(IMes)]$ (6) by (i) ligand redistribution with $[GaH_{3}(IMes)],$ (ii) hydride – bromide exchange with triethylsilane , and (iii) alkylation with $^{n}butyllithium$ followed by β-hydride elimination (6 only). Attempts to prepare 1, or monovalent analogues such as [ {GaCl(IMes)} $_{n}$ ], by thermally induced reductive elimination of dihydrogen from the chlorohydride congeners of 5 and 6 resulted in isolation of the known compounds [IMesCl][Cl] ( IMesCl = 1,3-dimesityl-2-chloroimidazolium ), and/or 1,3-dimesityl-2-dihydroimidazole , and gallium metal. Preliminary photochemical NMR spectroscopy and catalytic studies of 5 and 6 aimed at reductive dehydrogenation under milder conditions are reported. Compounds 1 and 4 have been characterised by single crystal X-ray structure determination .
ISSN	14779226
Issue Number	3
Journal	Dalton Trans.
Volume Number	41
e-ISSN	13645447
Language	English
Publisher	Royal Society of Chemistry
Publisher Date	2012-01-21
Publisher Place	Great Britain (UK)
Access Restriction	Subscribed
Subject Keyword	Chemistry
Content Type	Text
Resource Type	Article
Subject	Inorganic Chemistry

Central Library (ISO-9001:2015 Certified)
Indian Institute of Technology Kharagpur
Kharagpur, West Bengal, India | PIN - 721302

See location in the Map
03222 282435
Mail: support@ndl.gov.in

Sl.	Authority	Responsibilities	Communication Details
1	Ministry of Education (GoI), Department of Higher Education	Sanctioning Authority	https://www.education.gov.in/ict-initiatives
2	Indian Institute of Technology Kharagpur	Host Institute of the Project: The host institute of the project is responsible for providing infrastructure support and hosting the project	https://www.iitkgp.ac.in
3	National Digital Library of India Office, Indian Institute of Technology Kharagpur	The administrative and infrastructural headquarters of the project	Dr. B. Sutradhar bsutra@ndl.gov.in
4	Project PI / Joint PI	Principal Investigator and Joint Principal Investigators of the project	Dr. B. Sutradhar bsutra@ndl.gov.in Prof. Saswat Chakrabarti will be added soon
5	Website/Portal (Helpdesk)	Queries regarding NDLI and its services	support@ndl.gov.in
6	Contents and Copyright Issues	Queries related to content curation and copyright issues	content@ndl.gov.in
7	National Digital Library of India Club (NDLI Club)	Queries related to NDLI Club formation, support, user awareness program, seminar/symposium, collaboration, social media, promotion, and outreach	clubsupport@ndl.gov.in
8	Digital Preservation Centre (DPC)	Assistance with digitizing and archiving copyright-free printed books	dpc@ndl.gov.in
9	IDR Setup or Support	Queries related to establishment and support of Institutional Digital Repository (IDR) and IDR workshops	idr@ndl.gov.in