NDLI: Synthesis and engineering porosity of a mixed metal $Fe_{2}Ni$ MIL-88B metal–organic framework

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Synthesis and engineering porosity of a mixed metal $Fe_{2}Ni$ MIL-88B metal–organic framework

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Synthesis and engineering porosity of a mixed metal $Fe_{2}Ni$ MIL-88B metal–organic framework

Content Provider	World Health Organization (WHO)-Global Index Medicus
Author	Vuong, Gia-thanh Do, Trong-on Pham, Minh-hao
Description	Author Affiliation: Vuong GT ( Department of Chemical Engineering, Centre de Recherche sur les Interfaces et la Catalyse (CERPIC), Laval University, Quebec, G1V 0A6, Canada.)
Abstract	A new rational approach has been developed for the synthesis of a mixed metal MIL-88B metal–organic framework based on a neutral mixed metal cluster, such as $Fe_{2}Ni(μ_{3}-O).$ Unlike the conventional negative charged single metal cluster, the use of the neutral mixed metal cluster as nodes in the framework avoids the need of a compensating anion inside the porous MIL-88B system; thus the mixed metal MIL-88B becomes porous. The flexibility of the mixed metal MIL-88B can be controlled by terminal ligands with different steric hindrance. This allows us to reversibly customize the porosity of the MIL-88B structure at three levels of specific surface area as well as the pore volume.
ISSN	14779226
Issue Number	2
Journal	Dalton Trans.
Volume Number	42
e-ISSN	13645447
Language	English
Publisher	Royal Society of Chemistry
Publisher Date	2013-01-14
Publisher Place	Great Britain (UK)
Access Restriction	Subscribed
Subject Keyword	Chemistry
Content Type	Text
Resource Type	Article
Subject	Inorganic Chemistry

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