NDLI: Tin( II) fluoride vs. tin( II) chloride – a comparison of their coordination chemistry with neutral ligands

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Tin( II) fluoride vs. tin( II) chloride – a comparison of their coordination chemistry with neutral ligands

Content Provider	World Health Organization (WHO)-Global Index Medicus
Author	Reid, Gillian Hector, Andrew L. Jager, Edward Gurnani, Chitra Levason, William Pugh, David
Description	Author Affiliation: Gurnani C ( School of Chemistry, University of Southampton, Southampton SO17 1BJ, UK.)
Abstract	Reaction of $SnF_{2}$ in MeOH with the appropriate neutral N- or O-donor ligands produces $[SnF(2,2′-bipy)]_{2}SnF_{6},$ $[SnF(1,10-phen)]_{2}SnF_{4}$ and $[SnF_{2}(L)]$ L = $Me_{3}PO,$ dmso or pyNO). The X-ray structures of $[SnF(2,2′-bipy)]_{2}SnF_{6},$ $[SnF(1,10-phen)]_{2}SnF_{4}$ and $[SnF_{2}(dmso)],$ reveal trigonal pyramidal Sn(II) cores with longer fluorine bridges completing distorted 5- or 6-coordination. Attempts to prepare $SnF_{2}$ adducts with various phosphine or diphosphine ligands in MeCN failed, whilst in $CH_{2}Cl_{2}$ solution complex reactions involving the solvent occurred. The NHC, 1,3-(2,6-di-isopropylphenyl)imidazol-2-ylidene (IDiPP) and $SnF_{2}$ produced the imidazolium salt, $[IDiPPH]SnF_{3},$ the crystal structure of which revealed the first example of a discrete trifluorostannate(II) ion. In contrast, diphosphine complexes of tin( II) chloride formed readily, including $[SnCl_{2}\{Me_{2}P(CH_{2})_{2}PMe_{2}\}],$ $[SnCl_{2}\{o-C_{6}H_{4}(PMe_{2})_{2}\}],$ $[SnCl_{2}\{o-C_{6}H_{4}(PPh_{2})_{2}\}]$ and $[(SnCl_{2})_{2}(μ-Ph_{2}P(CH_{2})_{2}PPh_{2})],$ which were characterised by X-ray crystallography . The structures of $[SnCl_{2}\{Me_{2}P(CH_{2})_{2}PMe_{2}\}]$ and $[SnCl_{2}\{o-C_{6}H_{4}(PMe_{2})_{2}\}]$ reveal chloride-bridged dimers, but $[SnCl_{2}\{o-C_{6}H_{4}(PPh_{2})_{2}\}],$ although also dimeric, has very asymmetric diphosphine coordination best described as $κ^{1}.$ The structures of $[(SnCl_{2})_{2}(μ-Ph_{2}P(CH_{2})_{2}PPh_{2})]$ and of $[SnCl\{o-C_{6}H_{4}(AsMe_{2})_{2}\}]SnCl_{3}$ reveal trigonal pyramidal cores, but with longer Sn⋯Cl bridges affording polymeric structures. The synthesis of $[SnCl_{2}(R_{3}EO)_{2}]$ (R = Ph, E = P or As; and R = Me, E = P) are also reported, along with the structure of $[SnCl_{2}(Me_{3}PO)_{2}],$ which contains distorted tetragonal pyramidal Sn(II) coordination. X-ray structures are also reported for $[(PMe_{3})_{2}CH_{2}][SnCl_{3}]_{2}$ and $[Ph_{2}P(H)(CH_{2})_{2}P(H)Ph_{2}][SnCl_{3}]_{2},$ obtained as by-products from the attempts to synthesise phosphine complexes, as well as $[(o-C_{6}H_{4}(PMe_{2})_{2}CH_{2}]I_{2}.$ All complexes were characterised by microanalysis, IR and multinuclear NMR spectroscopy $(^{1}H,$ $^{19}F\{^{1}H\},$ $^{31}P\{^{1}H$ } and, where solubility allowed, $^{119}Sn).$ Comparisons are drawn with corresponding Sn(IV) and Ge(II) complexes.
ISSN	14779226
Issue Number	23
Volume Number	42
e-ISSN	13645447
Journal	Dalton Trans.
Language	English
Publisher	Royal Society of Chemistry
Publisher Date	2013-06-21
Publisher Place	Great Britain (UK)
Access Restriction	Subscribed
Subject Keyword	Tin Compounds Chemistry Tin Fluorides Crystallography, X-Ray Ligands Molecular Structure Metabolism Comparative Study Journal Article Research Support, Non-U.S. Gov't
Content Type	Text
Resource Type	Article
Subject	Inorganic Chemistry

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