NDLI: Three 3D silver-bis(triazole) metal–organic frameworks stabilized by high-connected Wells–Dawson polyoxometallates

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Three 3D silver-bis(triazole) metal–organic frameworks stabilized by high-connected Wells–Dawson polyoxometallates

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Three 3D silver-bis(triazole) metal–organic frameworks stabilized by high-connected Wells–Dawson polyoxometallates

Content Provider	World Health Organization (WHO)-Global Index Medicus
Author	Zhao, Dan Tian, Aixiang Ying, Jun Wang, Xiuli
Description	Author Affiliation: Wang X ( Department of Chemistry, Bohai University, Jinzhou, 121000, P. R. China. wangxiuli@bhu.edu.cn.)
Abstract	Three silver-bis(triazole) three-dimensional (3D) metal–organic frameworks (MOFs) with Wells–Dawson type polyoxometalates (POMs) as high-connected inorganic ligands have been isolated: $[Ag_{7}(bte)_{4}(H_{2}O)(HP_{2}W^{VI}_{16}W^{V}_{2}O_{62})]·2H_{2}O$ (1), $[Ag_{7}(btp)_{5}(HP_{2}W^{VI}_{16}W^{V}_{2}O_{62})]·H_{2}O$ (2) and $[Ag_{4}(btb)_{3.5}(P_{2}W_{18}O_{62})](H_{2}btb)·2H_{2}O$ (3) (bte = 1,2-bis(1,2,4-triazol-1-yl)ethane, btp = 1,3-bis(1,2,4-triazol-1-y1)propane, btb = 1,4-bis(1,2,4-triazol-1-y1)butane). Compound 1 contains a 3D metal–organic subunit, which is constructed from 1D Ag/bte chains and 2D layers based on hexanuclear $[Ag_{6}(bte)_{2}]^{6+}$ circuits. The $[P_{2}W_{18}O_{62}]^{8−}$ $(P_{2}W_{18})$ anions act as 10-dentate inorganic ligands incorporated into the channels of the 3D framework. In compound 2, the metal–organic subunits are a 2D layer constructed from the $[Ag_{5}(btp)_{2}]^{5+}$ circuits and flexible Ag/btp helical chains. The $P_{2}W_{18}$ anions also act as 10-dentate inorganic ligands linking adjacent 2D layers to construct a 3D framework. Both 1 and 2 contain Ag–Ag bonds, which further stabilize the structures. Compared with 1 and 2, the metal–organic subunit of 3 is a 3D cage-like host architecture. Without the assistance of Ag–Ag bonds, two sets of these 3D MOFs interpenetrate each other to generate a 2-fold interpenetrating structure for stability, which are united by the 5-dentate $P_{2}W_{18}$ anions to construct an integrated 3D structure. The roles of coordination modes of silver centers and POMs, as well as the effects of organic ligand lengths on the metal–organic subunit and final structures, have been reported. In addition, the electrochemical properties, photochemical catalysis and antibacterial properties of title compounds have also been investigated.
ISSN	14779226
Issue Number	13
Journal	Dalton Trans.
Volume Number	43
e-ISSN	13645447
Language	English
Publisher	Royal Society of Chemistry
Publisher Date	2014-04-07
Publisher Place	Great Britain (UK)
Access Restriction	Subscribed
Subject Keyword	Chemistry
Content Type	Text
Resource Type	Article
Subject	Inorganic Chemistry

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