NDLI: Highly fluorescent complexes with 3-isocyanoperylene and N-(2,5-di-tert-butylphenyl)-9-isocyano-perylene-3,4-dicarboximide

Please wait, while we are loading the content...

Year: 2017 Volume: 46

Year: 2016 Volume: 45

Year: 2015 Volume: 44

Year: 2014 Volume: 43

Year: 2014 Volume: 43 Issue: 48

Year: 2014 Volume: 43 Issue: 47

Year: 2014 Volume: 43 Issue: 46

Year: 2014 Volume: 43 Issue: 45

Year: 2014 Volume: 43 Issue: 43

Year: 2014 Volume: 43 Issue: 41

Year: 2014 Volume: 43 Issue: 40

Year: 2014 Volume: 43 Issue: 39

Year: 2014 Volume: 43 Issue: 38

Year: 2014 Volume: 43 Issue: 37

Year: 2014 Volume: 43 Issue: 36

Year: 2014 Volume: 43 Issue: 35

Year: 2014 Volume: 43 Issue: 34

Year: 2014 Volume: 43 Issue: 33

Year: 2014 Volume: 43 Issue: 32

Year: 2014 Volume: 43 Issue: 31

Year: 2014 Volume: 43 Issue: 30

Year: 2014 Volume: 43 Issue: 29

Year: 2014 Volume: 43 Issue: 28

$Carbonate–H_{2}O_{2}$ leaching for sequestering uranium from seawater

The first indoleamine-2,3-dioxygenase-1 (IDO1) inhibitors containing carborane

Tuning coordination modes of pyridine/thioether Schiff base (NNS) ligands to mononuclear manganese carbonyls

Differences in the cyclometalation reactivity of bisphosphinimine-supported organo-rare earth complexes

Hysteretic behaviour in a vacuum deposited submonolayer of single ion magnets

The reductive supercritical hydrothermal process, a novel synthesis method for cobalt nanoparticles: synthesis and investigation on the reaction mechanism

Structure-direction in the crystallization of ITW zeolites using 2-ethyl-1,3,4-trimethylimidazolium

Isoquinoline-derivatized tris(2-pyridylmethyl)amines as fluorescent zinc sensors with strict $Zn^{2+}/Cd^{2+}$ selectivity

Nanocasted synthesis of ordered mesoporous cerium iron mixed oxide and its excellent performances for As(V) and Cr(VI) removal from aqueous solutions

Multicolor tunable luminescence and paramagnetic properties of $NaGdF_{4}:Tb^{3+}/Sm^{3+}$ multifunctional nanomaterials

Synthesis and electrochemistry of β-pyrrole nitro-substituted cobalt(II) porphyrins. The effect of the $NO_{2}$ group on redox potentials, the electron transfer mechanism and catalytic reduction of molecular oxygen in acidic media

Formation of a dihydroborole by catalytic isomerization of a divinylborane

Preparation of Pt–Tl clusters showing new geometries. X-ray, NMR and luminescence studies

Uranyl-oxo coordination directed by non-covalent interactions

Si–H bond activation at $\{(NHC)_{2}Ni^{0}\}$ leading to hydrido silyl and bis(silyl) complexes: a versatile tool for catalytic Si–H/D exchange, acceptorless dehydrogenative coupling of hydrosilanes, and hydrogenation of disilanes to hydrosilanes

Preparation and characterisation of high-density ionic liquids incorporating halobismuthate anions

Nanostructured manganese oxide/carbon nanotubes, graphene and graphene oxide as water-oxidizing composites in artificial photosynthesis

Highly fluorescent complexes with 3-isocyanoperylene and N-(2,5-di-tert-butylphenyl)-9-isocyano-perylene-3,4-dicarboximide

Di-, tri- and tetranuclear molecular vanadium phosphonates: a chloride encapsulated tetranuclear bowl

Adsorption dominant catalytic activity of a carbon dots stabilized gold nanoparticles system

Tunable white-light emission from mixed lanthanide $(Eu^{3+},$ $Gd^{3+},$ $Tb^{3+})$ coordination polymers derived from 4-(dipyridin-2-yl)aminobenzoate

Manganese-mefenamic acid complexes exhibit high lipoxygenase inhibitory activity

Synthesis, structure, and peculiar green emission of $NaBaBO_{3}:Ce^{3+}$ phosphors

Metal ions and solvents ratio co-regulate four new magnetic coordination polymers based upon an unsymmetric tricarboxylate acid ligand

A monomer–dimer nanoswitch that mimics the working principle of the SARS-CoV 3CLpro enzyme controls copper-catalysed cyclopropanation

Synthesis, structural and photo-physical studies of bismuth(III) complexes with Janus scorpionate and co-ligands

Magnetic relaxation versus 3D long-range ordering in $\{Dy_{2}Ba(α-fur)_{8}\}_{n}$ furoate polymers

Phase transitions and interface phenomena in the cryogenic temperature domain of a niobate nanostructured ceramic

Investigation of composition dependent structural and optical properties of the $Zn_{1−x}Cd_{x}S,$ coaxial $Zn_{0.99−x}Cd_{x}Cu_{0.01}S/ZnS,$ $Zn_{0.99−x}Cd_{x}Mn_{0.01}S$ nanorods generated by a one-step hydrothermal process

Bismuth induced enhanced green emission from terbium ions and their complex in thin films

Cu(I) and Ag(I) complexes of 7,10-bis-N-heterocycle-diazafluoranthenes: programmed molecular grids?

A highly reactive and enhanced thermal stability nanocomposite catalyst based on Au nanoparticles assembled in the inner surface of $SiO_{2}$ hollow nanotubes

Gold(III) compounds containing a chelating, dicarbanionic ligand derived from 4,4′-di-tert-butylbiphenyl

The role of hydroxo-bridged dinuclear species and the influence of “innocent” buffers in the reactivity of $cis-[Co^{III}(cyclen)(H_{2}O)_{2}]^{3+}$ and $[Co^{III}(tren)(H_{2}O)_{2}]^{3+}$ complexes with biologically relevant ligands at physiological pH

Luminescent metal–organic frameworks as explosive sensors

α $MnMoO_{4}/graphene$ hybrid composite: high energy density supercapacitor electrode material

Self-assembly of an all-thiol-stabilized $\{Ag_{28}S_{23}\}$ high-nuclearity luminescent nanocluster with a “crab-like” shape

Electrochemical reduction of dioxygen by copper complexes with pyridylalkylamine ligands dissolved in aqueous buffer solution: the relationship between activity and redox potential

Facile base-free in situ generation and palladation of mesoionic and normal N-heterocyclic carbenes at ambient conditions

Year: 2014 Volume: 43 Issue: 27

Year: 2014 Volume: 43 Issue: 26

Year: 2014 Volume: 43 Issue: 25

Year: 2014 Volume: 43 Issue: 24

Year: 2014 Volume: 43 Issue: 23

Year: 2014 Volume: 43 Issue: 22

Year: 2014 Volume: 43 Issue: 21

Year: 2014 Volume: 43 Issue: 20

Year: 2014 Volume: 43 Issue: 19

Year: 2014 Volume: 43 Issue: 18

Year: 2014 Volume: 43 Issue: 17

Year: 2014 Volume: 43 Issue: 16

Year: 2014 Volume: 43 Issue: 15

Year: 2014 Volume: 43 Issue: 14

Year: 2014 Volume: 43 Issue: 13

Year: 2014 Volume: 43 Issue: 12

Year: 2014 Volume: 43 Issue: 11

Year: 2014 Volume: 43 Issue: 10

Year: 2014 Volume: 43 Issue: 9

Year: 2014 Volume: 43 Issue: 8

Year: 2014 Volume: 43 Issue: 7

Year: 2014 Volume: 43 Issue: 6

Year: 2014 Volume: 43 Issue: 5

Year: 2014 Volume: 43 Issue: 4

Year: 2014 Volume: 43 Issue: 3

Year: 2014 Volume: 43 Issue: 2

Year: 2014 Volume: 43 Issue: 1

Year: 2013 Volume: 42

Year: 2012 Volume: 41

Year: 2011 Volume: 40

Year: 2010 Volume: 39

Highly fluorescent complexes with 3-isocyanoperylene and N-(2,5-di-tert-butylphenyl)-9-isocyano-perylene-3,4-dicarboximide

Content Provider	World Health Organization (WHO)-Global Index Medicus
Author	Expósito, J. E. Lentijo, S. Aullón, G. Miguel, J. A. Espinet, P.
Description	Author Affiliation: Lentijo S ( IU CINQUIMA/Química Inorgánica, Facultad de Ciencias, Universidad de Valladolid, 47071 Valladolid, Spain. Jamiguel@qi.uva.es espinet@qi.uva.es.)
Abstract	The perylene derivatives 3-isocyanoperylene (Per–N≡C) (4a) and N-(2,5-di-tert-butylphenyl)-9-isocyano-perylene-3,4-dicarboximide (PMI–N≡C) (4b) were prepared and used to synthesize gold complexes [AuX(CNR)] (X = $C_{6}F_{5}$ (5a,b), $C_{6}F_{4}-O^{n}Bu-p$ (6b)). The reaction of 5b and 6b with $HNEt_{2}$ led to the carbene complexes $[AuX\{C(NEt_{2})(NHR)\}]$ (7b, 8b), respectively. The molecular structure of complexes 7b and 8b have been determined by X-ray diffraction analysis showing intermolecular π-stacking of the perylene groups and $C_{6}F_{5}$ rings and no Au⋯Au interactions. The derivative compounds $[M(CO)_{5}(CNR)]$ (M = Cr (9a,b), Mo (10a,b) or W (11a,b)) and $trans-[Pd(CNR)_{2}(C_{6}F_{3}Cl_{2})_{2}]$ (12a,b) were also prepared. All complexes exhibit fluorescence associated with the perylene fragment with emission quantum yields, in solution at room temperature, in the range 0.05–0.93 and emission lifetimes ∼ 4 ns. DFT calculations were performed of the absorption spectra of the ligands Per–N≡C and PMI–N≡C and representative complexes $[Au(C_{6}F_{5})(CNR)],$ $[Cr(CO)_{5}(CNR)],$ showing a perylene-dominated intraligand π–π* emissive state, from the HOMO and LUMO orbitals of the perylene chromophore, but with significantly different absorption maxima by the influence of the metal fragment, particularly significant in the Per–N≡C derivatives.
ISSN	14779226
Issue Number	28
Journal	Dalton Trans.
Volume Number	43
e-ISSN	13645447
Language	English
Publisher	Royal Society of Chemistry
Publisher Date	2014-07-28
Publisher Place	Great Britain (UK)
Access Restriction	Subscribed
Subject Keyword	Chemistry
Content Type	Text
Resource Type	Article
Subject	Inorganic Chemistry

Central Library (ISO-9001:2015 Certified)
Indian Institute of Technology Kharagpur
Kharagpur, West Bengal, India | PIN - 721302

See location in the Map
03222 282435
Mail: support@ndl.gov.in

Sl.	Authority	Responsibilities	Communication Details
1	Ministry of Education (GoI), Department of Higher Education	Sanctioning Authority	https://www.education.gov.in/ict-initiatives
2	Indian Institute of Technology Kharagpur	Host Institute of the Project: The host institute of the project is responsible for providing infrastructure support and hosting the project	https://www.iitkgp.ac.in
3	National Digital Library of India Office, Indian Institute of Technology Kharagpur	The administrative and infrastructural headquarters of the project	Dr. B. Sutradhar bsutra@ndl.gov.in
4	Project PI / Joint PI	Principal Investigator and Joint Principal Investigators of the project	Dr. B. Sutradhar bsutra@ndl.gov.in Prof. Saswat Chakrabarti will be added soon
5	Website/Portal (Helpdesk)	Queries regarding NDLI and its services	support@ndl.gov.in
6	Contents and Copyright Issues	Queries related to content curation and copyright issues	content@ndl.gov.in
7	National Digital Library of India Club (NDLI Club)	Queries related to NDLI Club formation, support, user awareness program, seminar/symposium, collaboration, social media, promotion, and outreach	clubsupport@ndl.gov.in
8	Digital Preservation Centre (DPC)	Assistance with digitizing and archiving copyright-free printed books	dpc@ndl.gov.in
9	IDR Setup or Support	Queries related to establishment and support of Institutional Digital Repository (IDR) and IDR workshops	idr@ndl.gov.in