NDLI: Modular solid-phase synthesis, catalytic application and efficient recycling of supported phosphine–phosphite ligand libraries

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P–S bond cleavage in reactions of thiophosphinidene-bridged dimolybdenum complexes with $[Co_{2}(CO)_{8}]$ to give phosphinidene-bridged heterometallic derivatives

Formation of the spirocyclic, Si-centered cage cations $[ClP(NSiMe_{3})_{2}Si(NSiMe_{3})_{2}P_{5}]^{+}$ and $[P_{5}(NSiMe_{3})_{2}Si(NSiMe_{3})_{2}P_{5}]^{2+}$

Synthesis and characterization of manganese triple-decker complexes

Dehydrogenative coupling involving P(O)–H bonds: a powerful way for the preparation of phosphoryl compounds

Synthesis and reactivity of α-cationic phosphines: the effect of imidazolinium and amidinium substituents

Heptaphosphide cluster anions bearing group 14 element amide functionalities

Activation of A–H bonds (A = B, C, N, O, Si) by using monovalent phosphorus complexes [RP→M]

P-chiral 1-phosphanorbornenes: from asymmetric phospha-Diels–Alder reactions towards ligand design and functionalisation

Stimuli-responsive chromism in organophosphorus chemistry

Palladium(II) complexes with chelating N-phosphanyl acyclic diaminocarbenes: synthesis, characterization and catalytic performance in Suzuki couplings

Iron-catalyzed cross coupling of P–H/C–O bonds: efficient synthesis of α-alkoxyphosphorus compounds

Spontaneous dehydrocoupling in peri-substituted phosphine–borane adducts

Synthetic strategies to bicyclic tetraphosphanes using $P_{1},$ $P_{2}$ and $P_{4}$ building blocks

On the energetics of P–P bond dissociation of sterically strained tetraamino-diphosphanes

Synthesis of P-stereogenic diarylphosphinic amides by directed lithiation: transformation into tertiary phosphine oxides via methanolysis, aryne chemistry and complexation behaviour toward zinc(II)

Phosphole formation by 1,1-carboboration – reactions of bis-alkynyl phosphanes with a frustrated P/B Lewis pair

Hydroalumination of alkynyl-aminophosphines as a promising tool for the synthesis of unusual phosphines: P–N bond activation, a transient phosphaallene, a zwitterionic $AlP_{2}C_{2}$ heterocycle and a masked Al/P-based frustrated Lewis pair

From the parent phosphinidene–carbene adduct NHC=PH to cationic $P_{4}-rings$ and $P_{2}-cycloaddition$ products

Mechanism of intramolecular transformations of nickel phosphanido hydride complexes

The mechanism of a phosphazene–phosphazane rearrangement

Palladium(II) complexes featuring a mixed phosphine–pyridine–iminophosphorane pincer ligand: synthesis and reactivity

Synthesis and self-assembly of carbamoylmethylphosphonate acrylamide-based diblock copolymers: new valuable thermosensitive materials

Reactions of [Cu(X)(BPEP-Ph)] (X = $PF_{6},$ $SbF_{6})$ with silyl compounds. Cooperative bond activation involving non-coordinating anions

N-heterocyclic phosphenium and phosphido nickel complexes supported by a pincer ligand framework

Rearrangement and deoxygenation of 3,3-bis(2-pyridyl)oxaphosphirane complexes

Computational and carbon-13 NMR studies of Pt–C bonds in P–C–P pincer complexes

Metal carbonyl complexes of phosphaamidines. Coordinative integrity detected in $C-amino(λ^{3},σ^{2})-phosphaalkene$ isomers coordinated through n(P) HOMO−1 donor orbitals

Modular solid-phase synthesis, catalytic application and efficient recycling of supported phosphine–phosphite ligand libraries

2-Phosphino-1,3-diphosphonium ions

Assembly and stabilization of $\{E(cyclo-P_{3})_{2}\}$ (E = Sn, Pb) as a bridging ligand spanning two triaryloxyniobium units

The specific functionalization of cyclotriphosphazene for the synthesis of smart dendrimers

Phosphidoboratabenzene–rhodium(I) complexes as precatalysts for the hydrogenation of alkenes at room temperature and atmospheric pressure

Zirconium-catalyzed intermolecular hydrophosphination using a chiral, air-stable primary phosphine

A simple route to phosphamethine cyanines from S,N-heterocyclic carbenes

Synthesis of 3-stannyl and 3-silyl propargyl phosphanes and the formation of a phosphinoallene

Polynuclear platinum phosphanido/phosphinito complexes: formation of P–O and P–O–P bonds through reductive coupling processes

An investigation on the chemistry of the $R_{2}P=P$ ligand: reactions of a phosphanylphosphinidene complex of tungsten(VI) with electrophilic reagents

[3]Ferrocenophanes with the bisphosphanotetryl bridge: inorganic rings on the way to tetrylenes

Resolution of P-stereogenic P-heterocycles via the formation of diastereomeric molecular and coordination complexes (a review)

Effects of boryl, phosphino, and phosphonio substituents on optical, electrochemical, and photophysical properties of 2,5-dithienylphospholes and 2-phenyl-5-thienylphospholes

Synthesis of the first metal-free phosphanylphosphonate and its use in the “phospha–Wittig–Horner” reaction

The expanding field of polyphosphazene high polymers

Hydrophosphination reactions with transition metal ferrocenylphosphine complexes

Polyphosphazenes for the Stille reaction: a new type of recyclable stannyl reagent

2,4,6-Triphenylphosphinine and 2,4,6-triphenylposphabarrelene revisited: synthesis, reactivity and coordination chemistry

Tris(pyrazolyl)phosphines with copper(I): from monomers to polymers

The design of second generation MOP-phosphonites: efficient chiral hydrosilylation of functionalised styrenes

Synthesis of novel pyridyl containing phospholanes and their polynuclear luminescent copper(I) complexes

Reactivity of aminophosphonic acids. Oxidative dephosphonylation of 1-aminoalkylphosphonic acids by aqueous halogens

Synthesis and electronic properties of polycyclic aromatic hydrocarbons doped with phosphorus and sulfur

Synthesis and structure of the extended phosphazane ligand $[(1,4-C_{6}H_{4})\{N(μ-PN^{t}Bu)_{2}N^{t}Bu\}_{2}]^{4−}$

3H-1,3-Azaphospholo[4,5-b]pyridines – novel heterocyclic P,N-bridging or hybrid ligands: synthesis and first $d^{8}-transition$ metal complexes

Molecular, 1D and 2D assemblies from hexakis(3-pyridyloxy)cyclophosphazene containing 20-membered metallamacrocyclic motifs

A straightforward access to ruthenium-coordinated fluorophosphines from phosphorous oxyacids

Phosphorus chemistry: discoveries and advances.

Aminophobanes: hydrolytic stability, tautomerism and application in Cr-catalysed ethene oligomerisation

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Modular solid-phase synthesis, catalytic application and efficient recycling of supported phosphine–phosphite ligand libraries

Content Provider	World Health Organization (WHO)-Global Index Medicus
Author	Heutz, Frank J. L. Kamer, Paul C. J.
Description	Author Affiliation: Heutz FJ ( EaStCHEM, School of Chemistry, University of St Andrews, North Haugh, St Andrews KY16 9ST, UK. pcjk@st-andrews.ac.uk.)
Abstract	In spite of decades of research in the field of homogeneous asymmetric catalysis the discovery of new high performance catalysts still relies heavily on trial-and-error. There is still a lack of efficient combinatorial methods which enable the synthesis and screening of vast ligand libraries, especially for bidentate phosphorus ligands. Here we present a highly modular solid-phase synthetic approach which provides facile access to libraries of phosphine–phosphite ligands in quantitative yield requiring only minimal work-up. The obtained library of supported phosphine–phosphites was successfully applied in rhodium catalyzed asymmetric hydrogenation obtaining high enantioselectivities up to 98%. Also, these polymer supported ligands could be successfully recycled under batch conditions exhibiting only a small decline of activity and no loss of selectivity.
ISSN	14779226
Issue Number	5
Journal	Dalton Trans.
Volume Number	45
e-ISSN	13645447
Language	English
Publisher	Royal Society of Chemistry
Publisher Date	2016-02-07
Publisher Place	Great Britain (UK)
Access Restriction	Subscribed
Subject Keyword	Chemistry
Content Type	Text
Resource Type	Article
Subject	Inorganic Chemistry

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