NDLI: Polymer-Supported Ionic-Liquid-Like Phases (SILLPs): Transferring Ionic Liquid Properties to Polymeric Matrices

Content Provider	World Health Organization (WHO)-Global Index Medicus
Author	Pawlak, Milena Sans, Victor Compañ, Vicente Luis, Santiago V. García-verdugo, Eduardo Burguete, M. Isabel Karbass, Naima
Description	Author Affiliation: Sans V ( Dpto. Química Inorgánica y Orgánica Department, Universidad Jaume I, Avda. Sos Baynat s/n, 12071 Castellon, Spain.)
Abstract	The physico-chemical properties of polymers with ionic-liquid-like moieties covalently bound to their surfaces (SILLPs) have been studied by thermal and spectroscopic techniques, as well as by direct impedance and dielectric measurements, and compared to those of the corresponding bulk ionic liquids. The effective transfer of properties from ionic liquids in solution to the supported species has thereby been demonstrated. The effects of the chemical nature of these tunable “solid solvents” on their macroscopic swelling and microwave heating, as well as the stabilities and activities of different catalytic moieties immobilized on the SILLPs, have been studied. Finally, the experimental effect observed in microwave heating can be directly correlated with the values of tan δ derived from dielectric measurements.
ISSN	09476539
e-ISSN	15213765
Journal	Chemistry - A European Journal
Issue Number	6
Volume Number	17
Language	English
Publisher	Wiley-VCH;ChemPubSoc Europe
Publisher Date	2011-02-07
Publisher Place	Germany
Access Restriction	Open
Subject Keyword	Chemistry
Content Type	Text
Resource Type	Article
Subject	Organic Chemistry Catalysis

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Polymer-Supported Ionic-Liquid-Like Phases (SILLPs): Transferring Ionic Liquid Properties to Polymeric Matrices