NDLI: Expanded Organic Building Units for the Construction of Highly Porous Metal–Organic Frameworks

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Expanded Organic Building Units for the Construction of Highly Porous Metal–Organic Frameworks

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Expanded Organic Building Units for the Construction of Highly Porous Metal–Organic Frameworks

Content Provider	World Health Organization (WHO)-Global Index Medicus
Author	Chen, Banglin Kong, Guo-qiang Krishna, Rajamani Zou, Chao Wu, Chuan-de Zhou, Wei Yildirim, Taner Ou, Sha He, Yabing Han, Zhi-da
Description	Author Affiliation: Kong GQ ( Center for Chemistry of High-Performance and Novel Materials, Department of Chemistry, Zhejiang University, Hangzhou, 310027 (P.R. China), Fax: (+86) 571-87951895.)
Abstract	Two new organic building units that contain dicarboxylate sites for their self-assembly with paddlewheel $[Cu_{2}(CO_{2})_{4}]$ units have been successfully developed to construct two isoreticular porous metal–organic frameworks (MOFs), ZJU-35 and ZJU-36, which have the same tbo topologies (Reticular Chemistry Structure Resource (RCSR) symbol) as HKUST-1. Because the organic linkers in ZJU-35 and ZJU-36 are systematically enlarged, the pores in these two new porous MOFs vary from 10.8 Å in HKUST-1 to 14.4 Å in ZJU-35 and 16.5 Å in ZJU-36, thus leading to their higher porosities with Brunauer–Emmett–Teller (BET) surface areas of 2899 and $4014 m^{2} g^{−1}$ for ZJU-35 and ZJU-36, respectively. High-pressure gas-sorption isotherms indicate that both ZJU-35 and ZJU-36 can take up large amounts of $CH_{4}$ and $CO_{2},$ and are among the few porous MOFs with the highest volumetric storage of $CH_{4}$ under 60 bar and $CO_{2}$ under 30 bar at room temperature. Their potential for high-pressure swing adsorption (PSA) hydrogen purification was also preliminarily examined and compared with several reported MOFs, thus indicating the potential of ZJU-35 and ZJU-36 for this important application. Studies show that most of the highly porous MOFs that can volumetrically take up the greatest amount of $CH_{4}$ under 60 bar and $CO_{2}$ under 30 bar at room temperature are those self-assembled from organic tetra- and hexacarboxylates that contain m-benzenedicarboxylate units with the $[Cu_{2}(CO_{2})_{4}]$ units, because this series of MOFs can have balanced porosities, suitable pores, and framework densities to optimize their volumetric gas storage. The realization of the two new organic building units for their construction of highly porous MOFs through their self-assembly with $[Cu_{2}(CO_{2})_{4}]$ units has provided great promise for the exploration of a large number of new tetra- and hexacarboxylate organic linkers based on these new organic building units in which different aromatic backbones can be readily incorporated into the frameworks to tune their porosities, pore structures, and framework densities, thus targeting some even better performing MOFs for very high gas storage and efficient gas separation under high pressure and at room temperature in the near future.
ISSN	09476539
e-ISSN	15213765
Journal	Chemistry - A European Journal
Issue Number	44
Volume Number	19
Language	English
Publisher	Wiley-VCH;ChemPubSoc Europe
Publisher Date	2013-10-25
Publisher Place	Germany
Access Restriction	Open
Subject Keyword	Chemistry
Content Type	Text
Resource Type	Article
Subject	Organic Chemistry Catalysis

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