NDLI: Clean Synthesis of an Economical 3D Nanochain Network of PdCu Alloy with Enhanced Electrocatalytic Performance towards Ethanol Oxidation

Please wait, while we are loading the content...

Year: 2017 Volume: 23

Year: 2016 Volume: 22

Year: 2015 Volume: 21

Year: 2015 Volume: 21 Issue: 52

Year: 2015 Volume: 21 Issue: 51

Year: 2015 Volume: 21 Issue: 50

Year: 2015 Volume: 21 Issue: 49

Lewis Acid Coupled Electron Transfer of Metal–Oxygen Intermediates

To Transfer or Not to Transfer? Development of a Dinitrosyl Iron Complex as a Nitroxyl Donor for the Nitroxylation of an $Fe^{III}–Porphyrin$ Center

Direct Catalytic Asymmetric Mannich-Type Reaction of $α-N_{3}$ Amide

Self-Relay Gold(I)-Catalyzed Pictet–Spengler/Cyclization Cascade Reaction for the Rapid Elaboration of Pentacyclic Indole Derivatives

Construction of Bridged Polycyclic Systems by Polyene Cyclization

Efficient Biomimetic Hydroxylation Catalysis with a Bis(pyrazolyl)imidazolylmethane Copper Peroxide Complex

Metalated Hexaphyrins: From Understanding to Rational Design

Red/NIR G-Quadruplex Sensing, Harvesting Blue Light by a Coumarin–Naphthalene Diimide Dyad

Clean Synthesis of an Economical 3D Nanochain Network of PdCu Alloy with Enhanced Electrocatalytic Performance towards Ethanol Oxidation

An Approach to Preparing Ni–P with Different Phases for Use as Supercapacitor Electrode Materials

Cross-linked Polymer-Blend Gate Dielectrics through Thermal Click Chemistry

Fibril Film Formation of Pseudoenantiomeric Oxymethylenehelicene Oligomers at the Liquid–Solid Interface: Structural Changes, Aggregation, and Discontinuous Heterogeneous Nucleation

Normal-to-Abnormal NHC Rearrangement of $Al^{III},$ $Ga^{III},$ and $In^{III}$ Trialkyl Complexes: Scope, Mechanism, Reactivity Studies, and $H_{2}$ Activation

Ring Expansions of Boroles with Diazo Compounds: Steric Control of C or N Insertion and Aromatic/Nonaromatic Products

Hydrothermal Formation of Calcium Copper Tetrasilicate

Facile Synthesis of Size-Tunable Functional Polyimidazolium Macrocycles through a Photochemical Closing Strategy

Catalytic Asymmetric Reactions of 4‐Substituted Indoles with Nitroethene: A Direct Entry to Ergot Alkaloid Structures

A Convenient Palladium-Catalyzed Carbonylative Suzuki Coupling of Aryl Halides with Formic Acid as the Carbon Monoxide Source

Formation of Highly Strained N-Heterocycles via Decomposition of Iron N-Heterocyclic Carbene Complexes: The Value of Labile FeC Bonds

Lewis Acid Catalyzed Asymmetric Three-Component Coupling Reaction: Facile Synthesis of α-Fluoromethylated Tertiary Alcohols

Carbon-Dot-Sensitized, Nitrogen-Doped $TiO_{2}$ in Mesoporous Silica for Water Decontamination through Nonhydrophobic Enrichment–Degradation Mode

Secondary Binding Interactions in a Synthetic Receptor for Trimethyllysine

Azobenzene C-Nucleosides for Photocontrolled Hybridization of DNA at Room Temperature

Expedient Mechanosynthesis of N,N-Dialkyl Imidazoliums and Silver(I)–Carbene Complexes in a Ball-Mill

Highly Lewis Acidic Arylboronate Esters Capable of Colorimetric Turn-On Response

Extending the Scope of the $B(C_{6}F_{5})_{3}-Catalyzed$ CN Bond Reduction: Hydrogenation of Oxime Ethers and Hydrazones

Unexpected Efficiency of a Luminescent Samarium(III) Complex for Combined Visible and Near-Infrared Biphotonic Microscopy

Highly Luminescent, Water-Soluble Lanthanide Fluorobenzoates: Syntheses, Structures and Photophysics, Part I: Lanthanide Pentafluorobenzoates

Boosting Proton Conductivity in Highly Robust 3D Inorganic Cationic Extended Frameworks through Ion Exchange with Dihydrogen Phosphate Anions

Design of Lead(II) Metal–Organic Frameworks Based on Covalent and Tetrel Bonding

Biofunctionalization of Polyoxometalates with DNA Primers, Their Use in the Polymerase Chain Reaction (PCR) and Electrochemical Detection of PCR Products

Synthesis of Long, Palladium End-Capped Polyynes through the Use of Asymmetric 1-Iodopolyynes

Ultrathin $g-C_{3}N_{4}$ Nanosheets Coupled with $AgIO_{3}$ as Highly Efficient Heterostructured Photocatalysts for Enhanced Visible-Light Photocatalytic Activity

Naphthalene Imide Conjugates: Formation of Supramolecular Assemblies, and the Encapsulation and Release of Dyes through DNA-Mediated Disassembly

Efficient Rhodium-Catalyzed Multicomponent Reaction for the Synthesis of Novel Propargylamines

CH Bond Activation by Early Transition Metal Carbide Cluster Anion $MoC_{3}^{−}$

A Luminescent Nitrogen-Containing Polycyclic Aromatic Hydrocarbon Synthesized by Photocyclodehydrogenation with Unprecedented Regioselectivity

Rapid and Efficient Conversion of $^{11}CO_{2}$ to $^{11}CO$ through Silacarboxylic Acids: Applications in Pd-Mediated Carbonylations

Mesoporous Foam $TiO_{2}$ Nanomaterials for Effective Hydrogen Production

Analogues of Cis- and Transplatin with a Rich Solution Chemistry: $cis-[PtCl_{2}(NH_{3})(1-MeC-N3)]$ and $trans-[PtI_{2}(NH_{3})(1-MeC-N3)]^{†}$

Dioxygen-Mediated Decarbonylative CH Alkylation of Heteroaromatic Bases with Aldehydes

A $\{Nb_{6}P_{2}W_{12}\}-Based$ Hexameric Manganese Cluster with Single-Molecule Magnet Properties

Oxidation and β-Alkylation of Alcohols Catalysed by Iridium(I) Complexes with Functionalised N-Heterocyclic Carbene Ligands

Substituting $CF_{2}$ for O4′ in Components of Nucleic Acids: Towards Systems with Reduced Propensity to Form Abasic Lesions

Insight into the Mechanism of the Initial Reaction of an OH Radical with DNA/RNA Nucleobases: A Computational Investigation of Radiation Damage

Chiral Lithiated Allylic α-Sulfonyl Carbanions: Experimental and Computational Study of Their Structure, Configurational Stability, and Enantioselective Synthesis

Mesomeric Effects of Graphene Modified with Diazonium Salts: Substituent Type and Position Influence its Properties

Intramolecular OH⋅⋅⋅Fluorine Hydrogen Bonding in Saturated, Acyclic Fluorohydrins: The γ-Fluoropropanol Motif

Controlled Redox Chemistry at Cerium within a Tripodal Nitroxide Ligand Framework

Core Halogenation as a Construction Principle in Tuning the Material Properties of Tetraazaperopyrenes

Chloride-Anion-Templated Synthesis of a Strapped-Porphyrin-Containing Catenane Host System

Ab Initio Molecular Dynamics with Explicit Solvent Reveals a Two-Step Pathway in the Frustrated Lewis Pair Reaction

The Synthesis and Characterization of Aromatic Hybrid Anderson–Evans POMs and their Serum Albumin Interactions: The Shift from Polar to Hydrophobic Interactions

A Mononuclear Uranium(IV) Single-Molecule Magnet with an Azobenzene Radical Ligand

Corrigendum: Kekulé versus Lewis: When Aromaticity Prevents Electron Pairing and Imposes Polyradical Character

Corrigendum: Palladium-Catalyzed Carbonylative Reactions of 1-Bromo-2-fluorobenzenes with Various Nucleophiles: Effective Combination of Carbonylation and Nucleophilic Substitution

Corrigendum: A Well-Defined Aluminum-Based Lewis Acid as an Effective Catalyst for Diels–Alder Transformations

Year: 2015 Volume: 21 Issue: 48

Year: 2015 Volume: 21 Issue: 47

Year: 2015 Volume: 21 Issue: 46

Year: 2015 Volume: 21 Issue: 45

Year: 2015 Volume: 21 Issue: 44

Year: 2015 Volume: 21 Issue: 43

Year: 2015 Volume: 21 Issue: 42

Year: 2015 Volume: 21 Issue: 41

Year: 2015 Volume: 21 Issue: 40

Year: 2015 Volume: 21 Issue: 39

Year: 2015 Volume: 21 Issue: 38

Year: 2015 Volume: 21 Issue: 37

Year: 2015 Volume: 21 Issue: 36

Year: 2015 Volume: 21 Issue: 35

Year: 2015 Volume: 21 Issue: 34

Year: 2015 Volume: 21 Issue: 33

Year: 2015 Volume: 21 Issue: 32

Year: 2015 Volume: 21 Issue: 31

Year: 2015 Volume: 21 Issue: 30

Year: 2015 Volume: 21 Issue: 29

Year: 2015 Volume: 21 Issue: 28

Year: 2015 Volume: 21 Issue: 27

Year: 2015 Volume: 21 Issue: 26

Year: 2015 Volume: 21 Issue: 25

Year: 2015 Volume: 21 Issue: 24

Year: 2015 Volume: 21 Issue: 23

Year: 2015 Volume: 21 Issue: 22

Year: 2015 Volume: 21 Issue: 21

Year: 2015 Volume: 21 Issue: 20

Year: 2015 Volume: 21 Issue: 19

Year: 2015 Volume: 21 Issue: 18

Year: 2015 Volume: 21 Issue: 17

Year: 2015 Volume: 21 Issue: 16

Year: 2015 Volume: 21 Issue: 15

Year: 2015 Volume: 21 Issue: 14

Year: 2015 Volume: 21 Issue: 13

Year: 2015 Volume: 21 Issue: 12

Year: 2015 Volume: 21 Issue: 11

Year: 2015 Volume: 21 Issue: 10

Year: 2015 Volume: 21 Issue: 9

Year: 2015 Volume: 21 Issue: 8

Year: 2015 Volume: 21 Issue: 7

Year: 2015 Volume: 21 Issue: 6

Year: 2015 Volume: 21 Issue: 5

Year: 2015 Volume: 21 Issue: 4

Year: 2015 Volume: 21 Issue: 3

Year: 2015 Volume: 21 Issue: 2

Year: 2015 Volume: 21 Issue: 1

Year: 2014 Volume: 20

Year: 2013 Volume: 19

Year: 2012 Volume: 18

Year: 2011 Volume: 17

Year: 2010 Volume: 16

Year: 2009 Volume: 15

Year: 2008 Volume: 14

Year: 2007 Volume: 13

Year: 2006 Volume: 12

Year: 2005 Volume: 11

Year: 1997 Volume: 3

Clean Synthesis of an Economical 3D Nanochain Network of PdCu Alloy with Enhanced Electrocatalytic Performance towards Ethanol Oxidation

Content Provider	World Health Organization (WHO)-Global Index Medicus
Author	Zhang, Huan Li, Tingting Han, Heyou Zuo, Yunpeng Liu, Jiawei Cai, Kai Lu, Zhicheng Huang, Zhao
Description	Author Affiliation: Liu J ( State Key Laboratory of Agriculture Microbiology, College of Science, College of Food Science and Technology, Huazhong Agricultural University, Wuhan 430070 (P.R. China).); Huang Z ( State Key Laboratory of Agriculture Microbiology, College of Science, College of Food Science and Technology, Huazhong Agricultural University, Wuhan 430070 (P.R. China).); Cai K ( State Key Laboratory of Agriculture Microbiology, College of Science, College of Food Science and Technology, Huazhong Agricultural University, Wuhan 430070 (P.R. China).); Zhang H ( State Key Laboratory of Agriculture Microbiology, College of Science, College of Food Science and Technology, Huazhong Agricultural University, Wuhan 430070 (P.R. China).); Lu Z ( State Key Laboratory of Agriculture Microbiology, College of Science, College of Food Science and Technology, Huazhong Agricultural University, Wuhan 430070 (P.R. China).); Li T ( State Key Laboratory of Agriculture Microbiology, College of Science, College of Food Science and Technology, Huazhong Agricultural University, Wuhan 430070 (P.R. China).); Zuo Y ( State Key Laboratory of Agriculture Microbiology, College of Science, College of Food Science and Technology, Huazhong Agricultural University, Wuhan 430070 (P.R. China).); Han H ( State Key Laboratory of Agriculture Microbiology, College of Science, College of Food Science and Technology, Huazhong Agricultural University, Wuhan 430070 (P.R. China). hyhan@mail.hzau.edu.cn.)
Abstract	A one-pot method for the fast synthesis of a 3D nanochain network (NNC) of PdCu alloy without any surfactants is described. The composition of the as-prepared PdCu alloy catalysts can be precisely controlled by changing the precursor ratio of Pd to Cu. First, the Cu content changes the electronic structure of Pd in the 3D NNC of PdCu alloy. Second, the 3D network structure offers large open pores, high surface areas, and self-supported properties. Third, the surfactant-free strategy results in a relatively clean surface. These factors all contribute to better electrocatalytic activity and durability towards ethanol oxidation. Moreover, the use of copper in the alloy lowers the price of the catalyst by replacing the noble metal palladium with non-noble metal copper. The composition-optimized $Pd_{80}Cu_{20}$ alloy in the 3D NNC catalyst shows an increased electrochemically active surface area $(80.95 m^{2} g^{−1})$ and a 3.62-fold enhancement of mass activity $(6.16 A mg^{−1})$ over a commercial Pd/C catalyst.
ISSN	09476539
e-ISSN	15213765
Journal	Chemistry - A European Journal
Issue Number	49
Volume Number	21
Language	English
Publisher	Wiley-VCH;ChemPubSoc Europe
Publisher Date	2015-12-01
Publisher Place	Germany
Access Restriction	Open
Subject Keyword	Chemistry
Content Type	Text
Resource Type	Article
Subject	Organic Chemistry Catalysis

Central Library (ISO-9001:2015 Certified)
Indian Institute of Technology Kharagpur
Kharagpur, West Bengal, India | PIN - 721302

See location in the Map
03222 282435
Mail: support@ndl.gov.in

Sl.	Authority	Responsibilities	Communication Details
1	Ministry of Education (GoI), Department of Higher Education	Sanctioning Authority	https://www.education.gov.in/ict-initiatives
2	Indian Institute of Technology Kharagpur	Host Institute of the Project: The host institute of the project is responsible for providing infrastructure support and hosting the project	https://www.iitkgp.ac.in
3	National Digital Library of India Office, Indian Institute of Technology Kharagpur	The administrative and infrastructural headquarters of the project	Dr. B. Sutradhar bsutra@ndl.gov.in
4	Project PI / Joint PI	Principal Investigator and Joint Principal Investigators of the project	Dr. B. Sutradhar bsutra@ndl.gov.in Prof. Saswat Chakrabarti will be added soon
5	Website/Portal (Helpdesk)	Queries regarding NDLI and its services	support@ndl.gov.in
6	Contents and Copyright Issues	Queries related to content curation and copyright issues	content@ndl.gov.in
7	National Digital Library of India Club (NDLI Club)	Queries related to NDLI Club formation, support, user awareness program, seminar/symposium, collaboration, social media, promotion, and outreach	clubsupport@ndl.gov.in
8	Digital Preservation Centre (DPC)	Assistance with digitizing and archiving copyright-free printed books	dpc@ndl.gov.in
9	IDR Setup or Support	Queries related to establishment and support of Institutional Digital Repository (IDR) and IDR workshops	idr@ndl.gov.in